Citation: Xu Xing, Guan Yaohui, Xu Dongcheng, Li Xinsheng. Copper(I)-Catalyzed Oxidation of Disubstituted Aromatic Alkenes to Ketones[J]. Chinese Journal of Organic Chemistry, ;2016, 36(4): 850-854. doi: 10.6023/cjoc201509035 shu

Copper(I)-Catalyzed Oxidation of Disubstituted Aromatic Alkenes to Ketones

1.
College of Chemistry and Life Science, Zhejiang Normal University, Jinhua. 321004

Corresponding author: Li Xinsheng,
Received Date: 26 September 2015
Available Online: 11 December 2015
Fund Project:

Oxidation of 1,1-disubstituted alkenes to ketones in pyridine with CuBr as catalyst in high yields (31%~95%) was discovered. The reaction, simple operation, low catalyst loading, excellent selectivity and yields provided a good choice for the oxidative cleavage of aromatic terminal olefins to ketones.
- CuBr,
- disubstituted alkene,
- oxidation
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沈阳化工大学材料科学与工程学院沈阳 110142