Citation: Sun Hongshun, Wang Jianqiang, Tan Wenwen, Yang Haidong, Li Yulong, Shen Linjiang, Guo Cheng. Synthesis and Crystal Structure of a Novel 1,3,4-Oxadiazin-one Compound[J]. Chinese Journal of Organic Chemistry, ;2016, 36(3): 622-625. doi: 10.6023/cjoc201509033 shu

Synthesis and Crystal Structure of a Novel 1,3,4-Oxadiazin-one Compound

1.
a College of Chemistry and Molecular Engineering, Nanjing Tech University, Nanjing 211816;
2.
b Department of Chemical Engineering, Nanjing Polytechnic Institute, Nanjing 210048

Corresponding author: Shen Linjiang,
Received Date: 25 September 2015
Available Online: 27 October 2015
Fund Project: 国家自然科学青年基金(No. 21106069) (No. 21106069)南京科技职业学院院级重点(No. NHKY-2015-1)资助项目. (No. NHKY-2015-1)

Using benzothiophene-2-carboxylic acid as a raw material, 2-(1-benzothiophen-2-yl)-4H-1,3,4-oxadiazin-5(6H)-one (4) was synthesized by esterification and hydrazinolysis, followed by the acylation and cyclization reactions. The novel compound 4 was characterized by ¹H NMR, ¹³C NMR, ESI-MS, FT-IR, elemental analysis and X-ray single crystal diffraction.
- benzothiophen,
- oxadiazin,
- synthesis,
- crystal structure
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