Citation: Yuan Qianjia, Zhang Wanbin. Applications of Phosphoramidite Ligands in Ir-Catalyzed Asymmetric Hydrogenation Reactions[J]. Chinese Journal of Organic Chemistry, ;2016, 36(2): 274-282. doi: 10.6023/cjoc201509016 shu

Applications of Phosphoramidite Ligands in Ir-Catalyzed Asymmetric Hydrogenation Reactions

Yuan Qianjia ,
Zhang Wanbin ^,

1.
School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University, Shanghai 200240

Corresponding author: Zhang Wanbin,
Received Date: 13 September 2015
Available Online: 13 October 2015
Fund Project: 国家自然科学基金(No. 21232004) (No. 21232004)上海市优秀学科带头人(No. 14XD1402300)资助项目. (No. 14XD1402300)

Phosphoramidites, as a class of privileged chiral ligands, are suitable for different types of reactions, such as catalytic asymmetric hydrogenation, catalytic asymmetric allylic substitution, catalytic asymmetric Diels-Alder reaction and so on. Catalytic asymmetric hydrogenation reactions are some of the most important reactions in industry. In this review recent advances and applications of phosphoramidite ligands in Ir-catalyzed asymmetric hydrogenation of enamides and their derivatives, unfunctionalized enamines, imines and heteroaromatic compounds are discussed.
- phosphoramidites,
- iridium,
- catalytic asymmetric hydrogenation
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