Citation: Feng Cuilan, Hei Liying, Li Zhen, Liu Lantao. Magnetic Microporous Organic Polymer of 1, 1'-Bi-2-naphtholSupported Palladium for Suzuki Coupling Reactions[J]. Chinese Journal of Organic Chemistry, ;2015, 36(1): 179-184. doi: 10.6023/cjoc201507028 shu

Magnetic Microporous Organic Polymer of 1, 1'-Bi-2-naphtholSupported Palladium for Suzuki Coupling Reactions

1.
College of Chemistry and Chemical Engineering, Shangqiu Normal University, Shangqiu 476000

Corresponding author: Feng Cuilan, Liu Lantao, liult05@iccas.ac.cn
Received Date: 23 July 2015
Revised Date: 22 August 2015

Fund Project: the National Natural Science Foundation of China 21102087the National Natural Science Foundation of China 21202095

Figures(5)

A recyclable palladium catalyst supported on magnetic microporous organic polymer (MOP) of 1, 1'-bi-2-naphthol (Fe₃O₄@MOPB-Pd) was synthesized by two steps. After being charactered by transmission electron microscope (TEM), X-ray photoelectron spectroscopy (XPS), thermogravimetric analysis (TG) and vibrating sample magnetometer (VSM), the palladium catalyst was applied in Suzuki coupling reaction in air atmosphere. With 0.01 g of Fe₃O₄@MOPB-Pd (0.12 mol% Pd based on bromobenzene) as catalyst, 1.0 mmol of bromobenzene reacted with 1.1 equiv. phenylboronic acid at 60 ℃ for 3 h can give the product with 98% yield. In addition, Fe₃O₄@MOPB-Pd can be easily separated from reaction system in the presence of magnetic field and the 92% yield was achieved even being used at 7th time for the Suzuki coupling reaction of iodobenzene and phenylboronic acid.
- magnetic nanoparticles,
- supported Pd catalyst,
- suzuki coupling reaction,
- BINOL,
- MOPs
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通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Magnetic Microporous Organic Polymer of 1, 1'-Bi-2-naphtholSupported Palladium for Suzuki Coupling Reactions

南开大学师唯/华北电力大学（保定）刘景维：二维配位聚合物中有序的亲锂冠醚位点用于无枝晶锂沉积

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通讯作者: 陈斌, bchen63@163.com