Citation: Sun Jingfu, Qian Ying. A Novel Naphthalimide-Rhodamine Fluorescence Sensor: Synthesis, Aggregation-Induced Emission Enhancement and Its Dual-Channel Detection Property[J]. Chinese Journal of Organic Chemistry, ;2015, 36(1): 151-157. doi: 10.6023/cjoc201506022 shu

A Novel Naphthalimide-Rhodamine Fluorescence Sensor: Synthesis, Aggregation-Induced Emission Enhancement and Its Dual-Channel Detection Property

Sun Jingfu ,
Qian Ying ^*,,

1.
School of Chemistry and Chemical Engineering, Southeast University, Nanjing 211189

Corresponding author: Qian Ying, yingqian@seu.edu.cn
Received Date: 17 June 2015
Revised Date: 6 September 2015

Fund Project: the National Natural Science Foundation of China 61178057

Figures(8)

A novel fluorescence probe based on naphthalimide-rhodamine N, N'-rhodamine acyl ethylamino-4-pyridine vinyl-1, 8-naphathlimide (PNRh) was synthesized and characterized by ¹H NMR, ¹³C NMR and HRMS techniques. Fluorescence spectra of PNRh in solid, ethanol/water mixed solution were measured. The results demonstrated that PNRh performed luminous yellow fluorescence in the solid state and the maximum emission wavelength was 592 nm. With the increasing of water content, the fluorescence intensity was enhanced in the ethanol/water mixed solution. When the water content reached 100%, the fluorescence intensity got the highest, and the color of the solution turned from slight blue fluorescence to kermesinus fluorescence. In addition, metal ion probe behavior of PNRh was detected. In a word, PNRh, possessed the characteristic of aggregation-induced emission enhancement (AIEE), was a dual-channel fluorescence sensor for detection Hg²⁺ and Cr³⁺ ions.
- naphthalimide-rhodamine,
- aggregation-induced emission enhancement,
- dual-channel fluorescence probe,
- mercury ion fluorescence probe,
- pH fluorescence probe
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