Citation: Zhang Yu, Wang Shixing, Yang Rui, Dai Tengyuan, Zhang Nan, Xi Pinxian, Yan Chun-Hua. Construction of Co₉S₈/MoS₂ Heterostructures for Enhancing Electrocatalytic Hydrogen Evolution Reaction[J]. Acta Chimica Sinica, ;2020, 78(12): 1455-1460. doi: 10.6023/A20070332 shu

Construction of Co₉S₈/MoS₂ Heterostructures for Enhancing Electrocatalytic Hydrogen Evolution Reaction

College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000, China

Corresponding author: Xi Pinxian, xipx@lzu.edu.cn
Received Date: 29 July 2020
Available Online: 13 October 2020
Fund Project: the National Natural Science Foundation of China 21931001the lnnovation Platform of Rare-earth Funcional Maeri.als of Gansu Province 2019ZX-04the National Natural Science Foundation of China 21922105Project supported by the National Natural Science Foundation of China(Nos.21931001, 21922105), the lnnovation Platform of Rare-earth Funcional Maeri.als of Gansu Province (No.2019ZX-04) and the 111 Project (No.B20027)the 111 Project B20027

Figures(5)

The large-scale use of coal, oil, and natural gas will cause environmental pollution and resource shortages, which is incompatible with the sustainable development. Therefore, it is essential to the development of renewable energy. H₂ has a high heat of combustion, and it's combustion products do not include greenhouse gases, so it is considered as an ideal clean energy carrier. Industrial hydrogen production methods will bring CO₂ inevitably. As an emerging energy conversion device, hydrogen produced by water splitting has simple equipment and little pollution, making it the first choice for clean energy in the future. Generally, the adsorption energy of hydrogen on the surface of precious metal catalysts is close to zero, and its hydrogen evolution reaction (HER) performance is the most prominent. Pt is an excellent HER catalyst. Commercial Pt/C has high alkaline HER performance, but its higher cost, material instability and resource scarcity limit its widespread applications. Therefore, this research is devoted to the development of high-activity, low-cost transition metal catalysts for HER by water splitting. Firstly, CoMoO₄ nanorods were synthesized by hydrothermal method. Then, using the precursor morphology oriented strategy method, the activated Co₉S₈/MoS₂ heterostructure catalyst was successfully prepared by sulfurating CoMoO₄ into CoS₂/MoS₂ and further, calcining CoS₂/MoS₂ nanorod in hydrogen atmosphere. X-rays diffraction (XRD), transmission electron microscopy (TEM), electron spin resonance (ESR), Raman spectra, X-ray photoelectron spectra (XPS) and synchrotron-based X-ray absorption fine structure (XAFS) characterizations exhibit that the Co coordination mode change from octahedron in CoS₂ to tetrahedron in Co₉S₈, leading to the activation of inert basal plane in MoS₂. Owing to this activation, the interlayer spacing of MoS₂ is reduced and thus generate abundant defects. Meanwhile, the increased electrochemical surface area (ECSA) and roughness of the catalysts are more conducive to the adsorption of H^*. The test of the contact angle data show that the electrode has good hydrophilicity, which can facilitate the penetration of electrolyte and diffusion of gas molecules quickly. When the current density is at 10 mA·cm^-2 in 1 mol·L^-1 KOH solution, an overpotential of 84 mV and a Tafel slope of 93 mV·dec^-1 can be achieved. Due to the strong interaction between different components of the heterostructures, the nanorods possess good structural stability in alkaline solutions. This work highlights the vital role of the sulfides heterostructure construction in HER, opening a new way to advanced alkaline HER catalysts.
- morphology oriented strategy,
- Co₉S₈/MoS₂,
- heterostructure,
- hydrophilicity,
- hydrogen evolution reaction
1. [1]
  Wang, Y.; Zhang, L. M.; Hu, T. J. Acta Chim. Sinica 2015, 73, 316(in Chinese).
2. [2]
  Li, Y.; Wei, X. F.; Chen, L. S.; Shi, J. L.; He, M. Y. Nat. Commun. 2019, 10, 5335.
3. [3]
  Chen, F.; Chen, H.; Wu, Q.; Luo, S. Chin. J. Org. Chem 2020, 40, 339(in Chinese).
4. [4]
  Huang, G.; Chen, Y. Z.; Jiang, H. L. Acta Chim. Sinica 2016, 74, 113(in Chinese).
5. [5]
  Song, F. Y.; Ding, Y.; Zhao, C. C. Acta Chim. Sinica 2014, 72, 133(in Chinese).
6. [6]
  Staszak-Jirkovský, J.; Malliakas, C. D.; Lopes, P. P.; Danilovic. N.; Kota, S. S.; Chang, K.-C.; Genorio, B.; Strmcnik, D.; Stamenkovic, V. R.; Kanatzidis, M. G.; Markovic, N. M. Nat. Mater. 2016, 15, 197.
7. [7]
  Liu, W.-Q.; Yang, X.-L.; Tung, C.-H.; Wu, L.-Z. Acta Chim. Sinica 2019, 77, 861(in Chinese).
8. [8]
  Dong, K.; Liu, Q.; Wu, L.-Z. Acta Chim. Sinica 2020, 78, 299(in Chinese).
9. [9]
  Zhang, X.-L.; Hu, S.-J.; Zheng, Y.-R.; Wu, R.; Gao, F.-Y.; Yang, P.-P.; Niu, Z.-Z.; Gu, C.; Yu, X. X.; Zheng, X.-S.; Ma, C.; Zheng, X.; Zhu, J.-F.; Gao, M.-R.; Yu, S.-H. Nat. Commun. 2019, 10, 5338.
10. [10]
  Podjaski, F.; Weber, D.; Zhang, S. Y.; Diehl, L.; Eger, R.; Duppel, V.; Alarcón-Lladó, E.; Richter, G.; Haase, F.; Morral, A. F. i.; Scheu, C.; Lotsch, B. V. Nat. Catal. 2019, 3, 55.
11. [11]
  Men, Y. N.; Li, P.; Zhou, J. H.; Cheng, G. Z.; Chen, S. L.; Luo, W. ACS Catal. 2019, 9, 3744.
12. [12]
  Qi, K.; Cui, X. Q.; Gu, L.; Yu, S. S.; Fan, X. F.; Luo, M. C.; Xu, S.; Li, N. B.; Zheng, L. R.; Zhang, Q. H.; Ma, J. Y.; Gong, Y.; Lv, F.; Wang, K.; Huang, H. H.; Zhang, W.; Guo, S. J.; Zheng, W. T.; Liu, P. Nat. Commun. 2019, 10, 5231.
13. [13]
  Li, H.; Tsai, C.; Koh, A. L.; Cai, L. L.; Contryman, A. W.; Fragapane, A. H.; Zhao, J. H.; Han, H. S.; Manoharan, H. C.; Abild-Pedersen, F.; Nørskov, J. K.; Zheng, X. L. Nat. Mater. 2016, 15, 48.
14. [14]
  Li, G. Q.; Chen, Z. H.; Li, Y. F.; Zhang, D.; Yang, W. T.; Liu, Y. Y.; Cao, L. Y. ACS Nano 2020, 14, 1707.
15. [15]
  Lu, Q.; Yu, J.; Zou, X. H.; Liao, K. M.; Tan, P.; Zhou, W.; Ni, M.; Shao, Z. P. Adv. Funct. Mater. 2019, 29, 1904481.
16. [16]
  Wu, H. B.; Xia, B. Y.; Yu, L.; Yu, X.-Y.; Lou, X. W. Nat. Commun. 2015, 6, 6512.
17. [17]
  Mak, K. F.; Lee, C.; Hone, J.; Shan, J.; Heinz, T. F. Phys. Rev. Lett. 2010, 105, 136805.
18. [18]
  Smith, R. J.; King, P. J.; Lotya, M.; Wirtz, C.; Khan, U.; De, S.; O'Neill, A.; Duesberg, G. S.; Grunlan, J. C.; Moriarty, G.; Chen, J.; Wang, J. Z.; Minett, A. I.; Nicolosi, V.; Coleman, J. N. Adv. Mater. 2011, 23, 3944.
19. [19]
  Xiong, Q. Z.; Wang, Y.; Liu, P.-F.; Zheng, L.-R.; Wang, G. Z.; Yang, H.-G.; Wong, P.-K.; Zhang, H. M.; Zhao, H. J. Adv. Mater. 2018, 30, 1801450.
20. [20]
  Shi, Y.; Zhou, Y.; Yang, D.-R.; Xu, W.-X.; Wang, C.; Wang, F.-B.; Xu, J.-J.; Xia, X.-H.; Chen, H.-Y. J. Am. Chem. Soc. 2017, 139, 15479.
21. [21]
  Xie, J. F.; Zhang, H.; Li, S.; Wang, R. X.; Sun, X.; Zhou, M.; Zhou, J. F.; Lou, X. W.; Xie, Y. Adv. Mater. 2013, 25, 5807.
22. [22]
  Cai, L.; He, J. F.; Liu, Q. H.; Yao, T.; Chen, L.; Yan, W. S.; Hu, F. C.; Jiang, Y.; Zhao, Y. D.; Hu, T. D.; Sun, Z. H.; Wei, S. Q. J. Am. Chem. Soc. 2015, 137, 2622.
23. [23]
  Toh, R. J.; Sofer, Z.; Luxa, J.; Sedmidubsky, D.; Pumera, M. Chem. Commun. 2017, 53, 3054.
24. [24]
  Wang, S.; Zhang, D.; Li, B.; Zhang, C.; Du, Z. G.; Yin, H. M.; Bi, X. F.; Yang, S. B. Adv. Energy Mater. 2018, 8, 1801345.
25. [25]
  Chen, Y. P.; Wang, X. Y.; Lao, M. M.; Rui, K.; Zheng, X. B.; Yu, H. B.; Ma, J.; Dou, S. X.; Sun, W. P. Nano Energy 2019, 64, 103918.
26. [26]
  Li, Y. G.; Wang, H. L.; Xie, L. M.; Liang, Y. Y.; Hong, G. S.; Dai, H. J. J. Am. Chem. Soc. 2011, 133, 7296.
27. [27]
  Uddin, N.; Zhang, H. Y.; Du, Y. P.; Jia, G. H.; Wang, S. B.; Yin, Z. Y. Adv. Mater. 2020, 32, 1905739.
28. [28]
  Hinnemann, B.; Moses, P. G.; Bonde, J.; Jørgensen, K. P.; Nielsen, J. H.; Horch, S.; Chorkendorff, I.; Nørskov, J. K. J. Am. Chem. Soc. 2005, 127, 5308.
29. [29]
  Jaramillo, T. F.; Jørgensen, K. P.; Bonde, J.; Nielsen, J. H.; Horch, S.; Chorkendorff, I. Science 2007, 317, 100.
30. [30]
  Yin, J.; Li, Y. X.; Lv, F.; Lu, M.; Sun, K.; Wang, W.; Wang, L.; Cheng, F. Y.; Li, Y. F.; Xi, P. X.; Guo, S. J. Adv. Mater. 2017, 29, 1704681.
31. [31]
  An, L.; Li, Y. X.; Luo, M. C.; Yin, J.; Zhao, Y.-Q.; Xu, C. L.; Cheng, F. Y.; Yang, Y.; Xi, P. X.; Guo, S. J. Adv. Funct. Mater. 2017, 27, 1703779.
32. [32]
  Yin, J.; Li, Y. X.; Lv, F.; Fan, Q. H.; Zhao, Y.-Q.; Zhang, Q. L.; Wang, W.; Cheng, F. Y.; Xi, P. X.; Guo, S. J. ACS Nano 2017, 11, 2275.
33. [33]
  Zhang, H. B.; Yu, L.; Chen, T.; Zhou, W.; Lou, X. W. Adv. Funct. Mater. 2018, 28, 1807086.
34. [34]
  Deng, J.; Li, H. B.; Wang, S. H.; Ding, D.; Chen, M. S.; Liu, C.; Tian, Z. Q.; Novoselov, K. S.; Ma, C.; Deng, D. H.; Bao, X. H. Nat. Commun. 2017, 8, 14430.
35. [35]
  Yang, R.; An, L.; Zhang, Y.; Zhang, N.; Dai, T. Y.; Xi, P. X. ChemCatChem 2019, 11, 6002.
36. [36]
  Cai, Z.; Li, L. D.; Zhang, Y. W.; Zhao, Y.; Yang, J.; Guo. Y. J.; Guo, L. Angew. Chem. Int. Ed. 2019, 58, 4189.
37. [37]
  Bai, J. M.; Meng, T.; Guo, D. L.; Wang, S. G.; Mao, B. G.; Cao, M. H. ACS Appl. Mater. Interfaces 2018, 10, 1678.
1. [1]
  Zhengyu Zhou , Huiqin Yao , Youlin Wu , Teng Li , Noritatsu Tsubaki , Zhiliang Jin . Synergistic Effect of Cu-Graphdiyne/Transition Bimetallic Tungstate Formed S-Scheme Heterojunction for Enhanced Photocatalytic Hydrogen Evolution. Acta Physico-Chimica Sinica, 2024, 40(10): 2312010-. doi: 10.3866/PKU.WHXB202312010
2. [2]
  Kai CHEN , Fengshun WU , Shun XIAO , Jinbao ZHANG , Lihua ZHU . PtRu/nitrogen-doped carbon for electrocatalytic methanol oxidation and hydrogen evolution by water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1357-1367. doi: 10.11862/CJIC.20230350
3. [3]
  Qiangqiang SUN , Pengcheng ZHAO , Ruoyu WU , Baoyue CAO . Multistage microporous bifunctional catalyst constructed by P-doped nickel-based sulfide ultra-thin nanosheets for energy-efficient hydrogen production from water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1151-1161. doi: 10.11862/CJIC.20230454
4. [4]
  Pingping HAO , Fangfang LI , Yawen WANG , Houfen LI , Xiao ZHANG , Rui LI , Lei WANG , Jianxin LIU . Hydrogen production performance of the non-platinum-based MoS₂/CuS cathode in microbial electrolytic cells. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1811-1824. doi: 10.11862/CJIC.20240054
5. [5]
  Asif Hassan Raza , Shumail Farhan , Zhixian Yu , Yan Wu . 用于高效制氢的双S型ZnS/ZnO/CdS异质结构光催化剂. Acta Physico-Chimica Sinica, 2024, 40(11): 2406020-. doi: 10.3866/PKU.WHXB202406020
6. [6]
  Wenjiang LI , Pingli GUAN , Rui YU , Yuansheng CHENG , Xianwen WEI . C₆₀-MoP-C nanoflowers van der Waals heterojunctions and its electrocatalytic hydrogen evolution performance. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 771-781. doi: 10.11862/CJIC.20230289
7. [7]
  Jianyin He , Liuyun Chen , Xinling Xie , Zuzeng Qin , Hongbing Ji , Tongming Su . ZnCoP/CdLa₂S₄肖特基异质结的构建促进光催化产氢. Acta Physico-Chimica Sinica, 2024, 40(11): 2404030-. doi: 10.3866/PKU.WHXB202404030
8. [8]
  Qin Hu , Liuyun Chen , Xinling Xie , Zuzeng Qin , Hongbing Ji , Tongming Su . Ni掺杂构建电子桥及激活MoS₂惰性基面增强光催化分解水产氢. Acta Physico-Chimica Sinica, 2024, 40(11): 2406024-. doi: 10.3866/PKU.WHXB202406024
9. [9]
  Endong YANG , Haoze TIAN , Ke ZHANG , Yongbing LOU . Efficient oxygen evolution reaction of CuCo₂O₄/NiFe-layered bimetallic hydroxide core-shell nanoflower sphere arrays. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 930-940. doi: 10.11862/CJIC.20230369
10. [10]
  Chenye An , Abiduweili Sikandaier , Xue Guo , Yukun Zhu , Hua Tang , Dongjiang Yang . 红磷纳米颗粒嵌入花状CeO₂分级S型异质结高效光催化产氢. Acta Physico-Chimica Sinica, 2024, 40(11): 2405019-. doi: 10.3866/PKU.WHXB202405019
11. [11]
  Shuqi Yu , Yu Yang , Keisuke Kuroda , Jian Pu , Rui Guo , Li-An Hou . Selective removal of Cr(Ⅵ) using polyvinylpyrrolidone and polyacrylamide co-modified MoS₂ composites by adsorption combined with reduction. Chinese Chemical Letters, 2024, 35(6): 109130-. doi: 10.1016/j.cclet.2023.109130
12. [12]
  Yuejiao An , Wenxuan Liu , Yanfeng Zhang , Jianjun Zhang , Zhansheng Lu . Revealing Photoinduced Charge Transfer Mechanism of SnO₂/BiOBr S-Scheme Heterostructure for CO₂ Photoreduction. Acta Physico-Chimica Sinica, 2024, 40(12): 2407021-. doi: 10.3866/PKU.WHXB202407021
13. [13]
  Kaihui Huang , Dejun Chen , Xin Zhang , Rongchen Shen , Peng Zhang , Difa Xu , Xin Li . Constructing Covalent Triazine Frameworks/N-Doped Carbon-Coated Cu₂O S-Scheme Heterojunctions for Boosting Photocatalytic Hydrogen Production. Acta Physico-Chimica Sinica, 2024, 40(12): 2407020-. doi: 10.3866/PKU.WHXB202407020
14. [14]
  Xiutao Xu , Chunfeng Shao , Jinfeng Zhang , Zhongliao Wang , Kai Dai . Rational Design of S-Scheme CeO₂/Bi₂MoO₆ Microsphere Heterojunction for Efficient Photocatalytic CO₂ Reduction. Acta Physico-Chimica Sinica, 2024, 40(10): 2309031-. doi: 10.3866/PKU.WHXB202309031
15. [15]
  Yingchun ZHANG , Yiwei SHI , Ruijie YANG , Xin WANG , Zhiguo SONG , Min WANG . Dual ligands manganese complexes based on benzene sulfonic acid and 2, 2′-bipyridine: Structure and catalytic properties and mechanism in Mannich reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1501-1510. doi: 10.11862/CJIC.20240078
16. [16]
  Wenxiu Yang , Jinfeng Zhang , Quanlong Xu , Yun Yang , Lijie Zhang . Bimetallic AuCu Alloy Decorated Covalent Organic Frameworks for Efficient Photocatalytic Hydrogen Production. Acta Physico-Chimica Sinica, 2024, 40(10): 2312014-. doi: 10.3866/PKU.WHXB202312014
17. [17]
  Bingliang Li , Yuying Han , Dianyang Li , Dandan Liu , Wenbin Shang . One-Step Synthesis of Benorilate Guided by Green Chemistry Principles and in vivo Dynamic Evaluation. University Chemistry, 2024, 39(6): 342-349. doi: 10.3866/PKU.DXHX202311070
18. [18]
  Jianyu Qin , Yuejiao An , Yanfeng Zhang . In Situ Assembled ZnWO₄/g-C₃N₄ S-Scheme Heterojunction with Nitrogen Defect for CO₂ Photoreduction. Acta Physico-Chimica Sinica, 2024, 40(12): 2408002-. doi: 10.3866/PKU.WHXB202408002
19. [19]
  Jiaxing Cai , Wendi Xu , Haoqiang Chi , Qian Liu , Wa Gao , Li Shi , Jingxiang Low , Zhigang Zou , Yong Zhou . 具有0D/2D界面的InOOH/ZnIn₂S₄空心球S型异质结用于增强光催化CO₂转化性能. Acta Physico-Chimica Sinica, 2024, 40(11): 2407002-. doi: 10.3866/PKU.WHXB202407002
20. [20]
  Yuqiao Zhou , Weidi Cao , Shunxi Dong , Lili Lin , Xiaohua Liu . Study on the Teaching Reformation of Practical X-ray Crystallography. University Chemistry, 2024, 39(3): 23-28. doi: 10.3866/PKU.DXHX202303003

Get Citation

PDF

XML

Metrics

PDF Downloads(59)
Abstract views(3678)
HTML views(836)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Construction of Co9S8/MoS2 Heterostructures for Enhancing Electrocatalytic Hydrogen Evolution Reaction

Metrics

通讯作者: 陈斌, bchen63@163.com

Construction of Co₉S₈/MoS₂ Heterostructures for Enhancing Electrocatalytic Hydrogen Evolution Reaction