Citation: Sun Jingjing, Wu Qiurong, Weng Wenqiang, Liu Xiaoqin, Tan Peng, Sun Linbing. Smart Light-responsive CO₂ Adsorbents for Regulating Strong Active Sites[J]. Acta Chimica Sinica, ;2020, 78(10): 1082-1088. doi: 10.6023/A20070316 shu

Smart Light-responsive CO₂ Adsorbents for Regulating Strong Active Sites

State Key Laboratory of Materials-Oriented Chemical Engineering, College of Chemical Engineering, Nanjing Tech University, Nanjing 211816, China

Corresponding author: Sun Linbing, lbsun@njtech.edu.cn
Received Date: 16 July 2020
Available Online: 10 August 2020
Fund Project: The National Natural Science Foundation of China 21676138The National Natural Science Foundation of China 21878149Project supported by the National Science Foundation for Excellent Young Scholars (No. 21722606), the National Natural Science Foundation of China (Nos. 21676138, 21878149, 21808110), and China Postdoctoral Science Foundation (No. 2019T120419)China Postdoctoral Science Foundation 2019T120419The National Science Foundation for Excellent Young Scholars 21722606The National Natural Science Foundation of China 21808110

Figures(5)

Light-responsive CO₂ adsorbents can effectively adjust their ability to capture CO₂ through external light irradiation, and have the advantages of good controllability and high energy efficiency during the adsorption process. However, the currently reported light-responsive CO₂ adsorbents can only realize the regulation of weak adsorption sites, and the regulation of strong adsorption sites is still a challenging task. In this work, a light-responsive smart adsorbent was constructed by in situ synthesis, and the light-responsive control of strong adsorption sites for CO₂ was realized. The construction of adsorbent was achieved by introducing the azobenzene derivative with cis and trans isomers and silane coupling agent containing primary amines into mesoporous silica. The characterization results show that the adsorbents have uniform pore channels, and primary amine and light-responsive groups are dispersed on the pore walls. The strong interaction between primary amine and CO₂ can lead to the selective adsorption of CO₂, while azobenzene as a molecular switch can regulate the adsorption performance of primary amine. Before light irradiation, azobenzene is in trans configuration, which decreases the electrostatic potential of the primary amine, and exposes the active site, thus CO₂ can be freely adsorbed; after light irradiation, azobenzene is converted to the cis configuration, which increases the electrostatic potential of the primary amine and shields the active sites. The change amount of adsorption capacity can reach 43%, and this process is reversible. Both the light-responsive properties of azobenzene groups and the adsorptive performances of adsorbents can be well maintained after 5 cycles. Azobenzene in different configuration has distinctive influences on the electrostatic potential of primary amine, thereby achieving the regulation of adsorption ability. This work utilizes the specific interaction between stimuli-responsive groups and target-specific adsorption sites, realizing the regulation of strong active cites for CO₂, which gives clues to the development of new smart adsorbents.
- CO₂ adsorption,
- light-responsive switch,
- strong adsorption site,
- selective adsorption,
- smart adsorbent
1. [1]
  Alvarez, R. A.; Zavala-Araiza, D.; Lyon, D. R.; Allen, D. T.; Barkley, Z. R.; Brandt, A. R.; Davis, K. J.; Herndon, S. C.; Jacob, D. J.; Karion, A.; Kort, E. A.; Lamb, B. K.; Lauvaux, T.; Maasakkers, J. D.; Marchese, A. J.; Omara, M.; Pacala, S. W.; Peischl, J.; Robinson, A. L.; Shepson, P. B.; Sweeney, C.; Townsend-Small, A.; Wofsy, S. C.; Hamburg, S. P. Science 2018, 361, 186.
2. [2]
  Yan, T. T.; Xing, G. L.; Ben, T. Acta Chim. Sinica 2018, 76, 366.
3. [3]
  Ding, M. L.; Flaig, R. W.; Jiang, H. L.; Yaghi, O. M. Chem. Soc. Rev. 2019, 48, 2783. doi: 10.1039/C8CS00829A
4. [4]
  Liu, Z. L.; Li, W.; Liu, H.; Zhuang, X. D.; Li, S. Acta Chim. Sinica 2019, 77, 323.
5. [5]
  Feng, K. S.; Davis, S. J.; Sun, L. X.; Hubacek, K. Nat. Commun. 2016, 7, 10693. doi: 10.1038/ncomms10693
6. [6]
  Chen, Z. Y.; Liu, J. W.; Cui, H.; Zhang, L.; Su, C. Y. Acta Chim. Sinica 2019, 77, 242.
7. [7]
  Nguyen, T. D.; Liu, Y.; Saha, S.; Leung, K. C. F.; Stoddart, J. F.; Zink, J. I. J. Am. Chem. Soc. 2007, 129, 626. doi: 10.1021/ja065485r
8. [8]
  Feng, A. H.; Yu, Y.; Yu, Y.; Song, L. X. Acta Chim. Sinica 2018, 76, 757.
9. [9]
  Jia, J. T.; Wang, L.; Zhao, Q.; Sun, F. X.; Zhu, G. S. Acta Chim. Sinica 2013, 71, 1492.
10. [10]
  Liu, B; Lian, Y. H.; Li, Z.; Chen, G. J. Acta Chim. Sinica 2014, 72, 942.
11. [11]
  Qiao, W. Z.; Song, T. Q.; Zhao, B. Chin. J. Chem. 2019, 37, 474. doi: 10.1002/cjoc.201800587
12. [12]
  Qi, S. C.; Zhu, R. R.; Liu, X.; Xue, D. M.; Liu, X. Q.; Sun, L. B. CIESC J. 2020, 71, 1666.
13. [13]
  Tan, P.; Jiang, Y.; Qi, S. C.; Gao, X. J.; Liu, X. Q.; Sun, L. B. Engineering 2020, 6, 569. doi: 10.1016/j.eng.2020.03.005
14. [14]
  Stuart, M. A. C.; Huck, W. T. S.; Genzer, J.; Muller, M.; Ober, C.; Stamm, M.; Sukhorukov, G. B.; Szleifer, I.; Tsukruk, V. V.; Urban, M.; Winnik, F.; Zauscher, S.; Luzinov, I.; Minko, S. Nat. Mater. 2010, 9, 101. doi: 10.1038/nmat2614
15. [15]
  Bian, L.; Li, W.; Wei, Z. Z.; Liu, X. W.; Li, S. Acta Chim. Sinica 2018, 76, 303.
16. [16]
  Xing, Z. M.; Gao, Y. X.; Shi, L. Y.; Liu, X. Q.; Jiang, Y.; Sun, L. B. Chem. Eng. Sci. 2017, 158, 216. doi: 10.1016/j.ces.2016.10.029
17. [17]
  Aznar, E.; Oroval, M.; Pascual, L.; Murguia, J. R.; Martinez-Manez, R.; Sancenon, F. Chem. Rev. 2016, 116, 561. doi: 10.1021/acs.chemrev.5b00456
18. [18]
  Lee, C. H.; Cheng, S. H.; Huang, I. P.; Souris, J. S.; Yang, C. S.; Mou, C. Y.; Lo, L. W. Angew. Chem. Int. Ed. 2010, 49, 8214. doi: 10.1002/anie.201002639
19. [19]
  Li, P.; Xie, G. H.; Kong, X. Y.; Zhang, Z.; Xiao, K.; Wen, L. P.; Jiang, L. Angew. Chem. Int. Ed. 2016, 55, 15637. doi: 10.1002/anie.201609161
20. [20]
  Jewell, J.; McCollum, D.; Emmerling, J.; Bertram, C.; Gernaat, D. E. H. J.; Krey, V.; Paroussos, L.; Berger, L.; Fragkiadakis, K.; Keppo, I.; Saadi, N.; Tavoni, M.; van Vuuren, D.; Vinichenko, V.; Riahi, K. Nature 2018, 554, 229. doi: 10.1038/nature25467
21. [21]
  Huang, Z. X.; Sednek, C.; Urynowicz, M. A.; Guo, H. G.; Wang, Q. R.; Fallgren, P.; Jin, S.; Jin, Y.; Igwe, U.; Li, S. P. Nat. Commun. 2017, 8, 1329. doi: 10.1038/s41467-017-01331-8
22. [22]
  Wriedt, M.; Sculley, J. P.; Yakovenko, A. A.; Ma, Y. G.; Halder, G. J.; Balbuena, P. B.; Zhou, H. C. Angew. Chem. Int. Ed. 2012, 51, 9804. doi: 10.1002/anie.201202992
23. [23]
  Cheng, L.; Jiang, Y.; Qi, S. C.; Liu, W.; Shan, S. F.; Tan, P.; Liu, X. Q.; Sun, L. B. Chem. Mater. 2018, 30, 3429. doi: 10.1021/acs.chemmater.8b01005
24. [24]
  Wang, M. F.; Yan, M.; Hu, F. L.; Zheng, N.; Yin, X. H.; Huang, Q.; Wang, H. F.; Lang, J. P. J. Mater. Chem. A 2020, 142, 700.
25. [25]
  Shi, Y. X.; Zhang, W. H.; Abrahanms, B. F.; Braunstein, P.; Lang, J. P. Angew. Chem. Int. Ed. 2019, 58, 9453. doi: 10.1002/anie.201903757
26. [26]
  Shi, Y. X.; Chen, H. H.; Zhang, W. H.; Day, G. S.; Lang, J. P.; Zhou, H. C. Chem. Eur. J. 2019, 25, 8543. doi: 10.1002/chem.201900347
27. [27]
  Jiang, Y.; Tan, P.; Qi, S. C.; Liu, X. Q.; Yan, J. H.; Fan, F.; Sun, L. B. Angew. Chem. Int. Ed. 2019, 58, 6600. doi: 10.1002/anie.201900141
28. [28]
  Li, J. R.; Yu, J. M.; Lu, W. G.; Sun, L. B.; Sculley, J.; Balbuena, P. B.; Zhou, H. C. Nat. Commun. 2013, 4, 2041. doi: 10.1038/ncomms3041
29. [29]
  Hao, G. P.; Li, W. C.; Qian, D.; Lu, A. H. Adv. Mater. 2010, 22, 853. doi: 10.1002/adma.200903765
30. [30]
  Yagai, S.; Kitamura, A. Chem. Soc. Rev. 2008, 8, 1520.
31. [31]
  Wang, C.; Guo, Y. S.; Wang, Y. P.; Xu, H. P.; Zhang, X. Chem. Commun. 2009, 36, 5380.
32. [32]
  Li, X. J.; Ma, W.; Li, H. M.; Zhang, Q. H.; Liu, H. W. Coord. Chem. Rev. 2020, 408, 3723.
33. [33]
  Wu, Q. R.; Tan, P.; Gu, C.; Zhou, R.; Qi, S. C.; Liu, X. Q.; Jiang, Y.; Sun, L. B. Sci. China Mater. 2020, https://doi.org/10.1007/s40843-020-1423-8.
34. [34]
  Moon, H. J.; Ko, D. Y.; Park, M. H.; Joo, M. K.; Jeong, B. Chem. Soc. Rev. 2012, 41, 4860. doi: 10.1039/c2cs35078e
35. [35]
  Park, J.; Yuan, D. Q.; Pham, K. T.; Li, J. R.; Yakovenko, A.; Zhou, H. C. J. Am. Chem. Soc. 2012, 134, 99. doi: 10.1021/ja209197f
36. [36]
  Lyndon, R.; Konstas, K.; Ladewig, B. P.; Southon, P. D.; Kepert, C. J.; Hill, M. R. Angew. Chem. Int. Ed. 2013, 125, 3783. doi: 10.1002/ange.201206359
37. [37]
  Zhu, J.; Tan, P.; Yang, P. P.; Liu, X. Q.; Jiang, Y.; Sun, L. B. Chem. Commun. 2017, 53, 3281. doi: 10.1039/C7CC90087B
38. [38]
  Qi, S. C.; Wu, J. K.; Lu, J.; Yu, G. X.; Zhu, R. R.; Liu, Y.; Liu, X.; Liu, X. Q.; Sun, L. B. J. Mater. Chem. A 2019, 7, 17842. doi: 10.1039/C9TA04785A
39. [39]
  Yu, Z. Z.; Li, N.; Zheng, P. P.; Pan, W.; Tang, B. Chem. Commun. 2014, 50, 3494. doi: 10.1039/C3CC49183H
40. [40]
  Yue, M. C.; Hoshino, Y.; Ohshiro, Y.; Imamura, K.; Miura, Y. Angew. Chem. Int. Ed. 2014, 53, 2654. doi: 10.1002/anie.201309758
41. [41]
  Connolly, B. M.; Aragones-Anglada, M.; Gandara-Loe, J.; Danaf, N. A.; Lamb, D. C.; Mehta, J. P.; Vulpe, D.; Wuttke, S.; Silvestre-Albero, J.; Moghadam, P. Z.; Wheatley, A. E. H.; Fairen-Jimenez, D. Nat. Commun. 2019, 10, 1723. doi: 10.1038/s41467-019-09339-y
1. [1]
  Jie ZHAO , Sen LIU , Qikang YIN , Xiaoqing LU , Zhaojie WANG . Theoretical calculation of selective adsorption and separation of CO₂ by alkali metal modified naphthalene/naphthalenediyne. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 515-522. doi: 10.11862/CJIC.20230385
2. [2]
  Qianqian Zhong , Yucui Hao , Guotao Yu , Lijuan Zhao , Jingfu Wang , Jian Liu , Xiaohua Ren . Comprehensive Experimental Design for the Preparation of the Magnetic Adsorbent Based on Enteromorpha Prolifera and Its Utilization in the Purification of Heavy Metal Ions Wastewater. University Chemistry, 2024, 39(8): 184-190. doi: 10.3866/PKU.DXHX202312013
3. [3]
  Xinyu Yin , Haiyang Shi , Yu Wang , Xuefei Wang , Ping Wang , Huogen Yu . Spontaneously Improved Adsorption of H₂O and Its Intermediates on Electron-Deficient Mn^(3+δ)+ for Efficient Photocatalytic H₂O₂ Production. Acta Physico-Chimica Sinica, 2024, 40(10): 2312007-. doi: 10.3866/PKU.WHXB202312007
4. [4]
  Fei Xie , Chengcheng Yuan , Haiyan Tan , Alireza Z. Moshfegh , Bicheng Zhu , Jiaguo Yu . d带中心调控过渡金属单原子负载COF吸附O₂的理论计算研究. Acta Physico-Chimica Sinica, 2024, 40(11): 2407013-. doi: 10.3866/PKU.WHXB202407013
5. [5]
  Xiaosong PU , Hangkai WU , Taohong LI , Huijuan LI , Shouqing LIU , Yuanbo HUANG , Xuemei LI . Adsorption performance and removal mechanism of Cd(Ⅱ) in water by magnesium modified carbon foam. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1537-1548. doi: 10.11862/CJIC.20240030
6. [6]
  Jingke LIU , Jia CHEN , Yingchao HAN . Nano hydroxyapatite stable suspension system: Preparation and cobalt adsorption performance. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1763-1774. doi: 10.11862/CJIC.20240060
7. [7]
  Ping ZHANG , Chenchen ZHAO , Xiaoyun CUI , Bing XIE , Yihan LIU , Haiyu LIN , Jiale ZHANG , Yu'nan CHEN . Preparation and adsorption-photocatalytic performance of ZnAl@layered double oxides. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1965-1974. doi: 10.11862/CJIC.20240014
8. [8]
  Fang Niu , Rong Li , Qiaolan Zhang . Analysis of Gas-Solid Adsorption Behavior in Resistive Gas Sensing Process. University Chemistry, 2024, 39(8): 142-148. doi: 10.3866/PKU.DXHX202311102
9. [9]
  Shasha Ma , Zujin Yang , Jianyong Zhang . Facile Synthesis of FeBTC Metal-Organic Gel and Its Adsorption of Cr₂O₇²⁻: A Physical Chemistry Innovation Experiment. University Chemistry, 2024, 39(8): 314-323. doi: 10.3866/PKU.DXHX202401008
10. [10]
  Youlin SI , Shuquan SUN , Junsong YANG , Zijun BIE , Yan CHEN , Li LUO . Synthesis and adsorption properties of Zn(Ⅱ) metal-organic framework based on 3, 3', 5, 5'-tetraimidazolyl biphenyl ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1755-1762. doi: 10.11862/CJIC.20240061
11. [11]
  Baohua LÜ , Yuzhen LI . Anisotropic photoresponse of two-dimensional layered α-In₂Se₃(2H) ferroelectric materials. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1911-1918. doi: 10.11862/CJIC.20240105
12. [12]
  Wenlong LI , Xinyu JIA , Jie LING , Mengdan MA , Anning ZHOU . Photothermal catalytic CO₂ hydrogenation over a Mg-doped In₂O_3-x catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 919-929. doi: 10.11862/CJIC.20230421
13. [13]
  Kun WANG , Wenrui LIU , Peng JIANG , Yuhang SONG , Lihua CHEN , Zhao DENG . Hierarchical hollow structured BiOBr-Pt catalysts for photocatalytic CO₂ reduction. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1270-1278. doi: 10.11862/CJIC.20240037
14. [14]
  Shihui Shi , Haoyu Li , Shaojie Han , Yifan Yao , Siqi Liu . Regioselectively Synthesis of Halogenated Arenes via Self-Assembly and Synergistic Catalysis Strategy. University Chemistry, 2024, 39(5): 336-344. doi: 10.3866/PKU.DXHX202312002
15. [15]
  Yunhao Zhang , Yinuo Wang , Siran Wang , Dazhen Xu . Progress in Selective Construction of Functional Aromatics from Nitrogenous Cycloalkanes. University Chemistry, 2024, 39(11): 136-145. doi: 10.3866/PKU.DXHX202401083
16. [16]
  Peiran ZHAO , Yuqian LIU , Cheng HE , Chunying DUAN . A functionalized Eu³⁺ metal-organic framework for selective fluorescent detection of pyrene. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 713-724. doi: 10.11862/CJIC.20230355
17. [17]
  Xilin Zhao , Xingyu Tu , Zongxuan Li , Rui Dong , Bo Jiang , Zhiwei Miao . Research Progress in Enantioselective Synthesis of Axial Chiral Compounds. University Chemistry, 2024, 39(11): 158-173. doi: 10.12461/PKU.DXHX202403106
18. [18]
  Wen YANG , Didi WANG , Ziyi HUANG , Yaping ZHOU , Yanyan FENG . La promoted hydrotalcite derived Ni-based catalysts: In situ preparation and CO₂ methanation performance. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 561-570. doi: 10.11862/CJIC.20230276
19. [19]
  Jiakun BAI , Ting XU , Lu ZHANG , Jiang PENG , Yuqiang LI , Junhui JIA . A red-emitting fluorescent probe with a large Stokes shift for selective detection of hypochlorous acid. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1095-1104. doi: 10.11862/CJIC.20240002
20. [20]
  Ruolin CHENG , Haoran WANG , Jing REN , Yingying MA , Huagen LIANG . Efficient photocatalytic CO₂ cycloaddition over W₁₈O₄₉/NH₂-UiO-66 composite catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 523-532. doi: 10.11862/CJIC.20230349

Get Citation

PDF

XML

Metrics

PDF Downloads(4)
Abstract views(1194)
HTML views(288)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Smart Light-responsive CO2 Adsorbents for Regulating Strong Active Sites

Metrics

通讯作者: 陈斌, bchen63@163.com

Smart Light-responsive CO₂ Adsorbents for Regulating Strong Active Sites