Citation: Yan Tengfei, Liu Junqiu. Novel Covalent Cross-linked Nanocapsules: Fabrication, Modulation and Functions[J]. Acta Chimica Sinica, ;2020, 78(8): 713-718. doi: 10.6023/A20050164 shu

Novel Covalent Cross-linked Nanocapsules: Fabrication, Modulation and Functions

Yan Tengfei ^a ,
Liu Junqiu ^a,b,,

a.
College of Material, Chemistry and Chemical Engineering, Hangzhou Normal University, Hangzhou 310036
b.
College of Chemistry, State Key Laboratory of Supramolecular Structure and Materials, Jilin University, Changchun 130012

Corresponding author: Liu Junqiu, junqiuliu@jlu.edu.cn
Received Date: 12 May 2020
Available Online: 29 May 2020
Fund Project: Project supported by Key Research and Development Projects of the Ministry of Science and Technology (Nos. 2018YF09101602, 2018YFA0901600)Key Research and Development Projects of the Ministry of Science and Technology 2018YFA0901600Key Research and Development Projects of the Ministry of Science and Technology 2018YF09101602

Figures(7)

Monomolecular layer polymeric nanocapsules can be easily prepared by the covalent self-assembly of the horizontal cross-linking of rigid building blocks and flexible cross-linker under certain conditions. Compared with the traditional noncovalent supramolecular vesicles, this new type of covalently self-assembled polymeric nanocapsules possess many advantages such as stable structure, controllable size, and excellent dispersibility. Therefore, it is of great significance to fabricate new covalent nanocapsules by means of chemical synthesis to realize their structural control and application exploration. Focusing on these problems, we have developed functionalized pillar[5]arene, tetraphenyl ethylene, porphyrin, triazine, phenylboronic anhydride, etc. to serve as basic building blocks, which were polymerized by flexible alkyl linkers to finally obtain the covalently cross-linked polymeric nanocapsules. Through the structural modification and regulation, we found the functionalized polymeric nanocapsules showed potential application in the field of light harvesting, artificial enzyme, antimicrobial and drug delivery. In the future, more application fields of the covalent polymeric nanocapsules are expected to be further explored.
- covalent cross-linking,
- monomolecular layer,
- nanocapsule,
- structural regulation,
- functionalization
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