Citation: Jiang Jinhui, Zhu Yunqing, Du Jianzhong. Challenges and Perspective on Ring-Opening Polymerization-Induced Self-Assembly[J]. Acta Chimica Sinica, ;2020, 78(8): 719-724. doi: 10.6023/A20050162 shu

Challenges and Perspective on Ring-Opening Polymerization-Induced Self-Assembly

Jiang Jinhui ^a ,
Zhu Yunqing ^a,b,, ,
Du Jianzhong ^a,b,,

a.
Department of Polymeric Materials, School of Materials Science and Engineering, Tongji University, Shanghai 201804, China
b.
Department of Orthopedics, Shanghai Tenth People's Hospital, Tongji University School of Medicine, Shanghai 200072, China

Corresponding author: Zhu Yunqing, 1019zhuyq@tongji.edu.cn Du Jianzhong, jzdu@tongji.edu.cn
Received Date: 11 May 2020
Available Online: 19 June 2020
Fund Project: the National Science Fund for Distinguished Young Scholars 21925505the National Natural Science Foundation of China 21674081the National Natural Science Foundation of China 51903190Shanghai Pujiang Program 19PJ1409600Project supported by the National Science Fund for Distinguished Young Scholars (No. 21925505), the National Natural Science Foundation of China (Nos. 21674081, 51903190) and Shanghai Pujiang Program (No. 19PJ1409600)

Figures(5)

Polymerization-induced self-assembly (PISA) is one of the most cutting-edge strategies towards the preparation of nanoparticles with a range of morphologies (spheres, worms, vesicles, etc.) as it combines polymerization and self-assembly and thus can afford high solid contents in various media. Additionally, nanoparticle morphology can be accurately targeted by adjusting the degree of polymerization of the soluble stabilizer block and the insoluble core-forming block, as well as solid contents in PISA formula. Unfortunately, this highly efficient approach is limited to specific polymerization methods, and hence specific monomer types. Currently, PISA based on reversible addition-fragmentation chain-transfer polymerization (RAFT) has been well-established for the in situ preparation of a range of nanoparticle morphologies. This method is relatively mature especially in the mechanism exploration, morphological control, and characterization, which has important impact to other fields of polymer chemistry. However, methacrylates, acrylates, and styrene monomers are often essential for reversible addition-fragmentation chain-transfer polymerization-induced self-assembly (RAFT-PISA), leading to the carbon-carbon backbone, which normally produces nonbiodegradable structures. These drawbacks are detrimental in terms of biomedical applications. Fortunately, new PISA strategies based on ring-opening polymerizations, including ring-opening metathesis polymerization-induced self-assembly (ROMPISA), ring-opening polymerization of N-carboxy- anhydride-induced self-assembly (NCA-PISA) and radical ring-opening polymerization-induced self-assembly (rROPISA), have been developed to overcome these problems. ROMPISA has proven to be an efficient approach for fabricating multifunctional nanoparticles due to its great tolerance for many functional groups. Biodegradable nanoparticles, including spheres and vesicles, have been successfully prepared by rROPISA and NCA-PISA. Therefore, ring-opening PISA (ROPISA) provides not only new polymerization methods but also new strategies for fabricating biodegradable nanoparticles with a range of monomer species. In this perspective, we briefly summarize the current progress and analyze the challenges of ROPISA. Finally, we provide a perspective for the further development of ROPISA addressed on the mechanism, monomers and applications, which provides an insight into ROPISA as well as some suggestions and directions for its future research.
1. [1]
  Kim, J. K.; Yang, S. Y.; Lee, Y.; Kim, Y. Prog. Polym. Sci. 2010, 35, 1325. doi: 10.1016/j.progpolymsci.2010.06.002
2. [2]
  Cai, C. H.; Wang, L. Q.; Lin, J. P. Chem. Commun. 2011, 47, 11189. doi: 10.1039/c1cc12683k
3. [3]
  Guan, X. L.; Wang, L.; Li, Z. F.; Liu, M. N.; Wang, K. L.; Lin, B.; Yang, X. Q.; Lai, S. J.; Lei, Z. Q. Acta Chim. Sinica 2019, 77, 1036 (in Chinese).
4. [4]
  Zhu, Y. Q.; Yang, B.; Chen, S.; Du, J. Z. Prog. Polym. Sci. 2017, 64, 1. doi: 10.1016/j.progpolymsci.2015.05.001
5. [5]
  Ma, G. H.; Yue, H. Chin. J. Chem. 2020, 38, 911. doi: 10.1002/cjoc.202000135
6. [6]
  Mai, Y.; Eisenberg, A. Chem. Soc. Rev. 2012, 41, 5969. doi: 10.1039/c2cs35115c
7. [7]
  Canning, S. L.; Smith, G. N.; Armes, S. P. Macromolecules 2016, 49, 1985. doi: 10.1021/acs.macromol.5b02602
8. [8]
  Chen, S. L.; Shi, P. F.; Zhang, W. Q. Chin. J. Polym. Sci. 2017, 35, 455. doi: 10.1007/s10118-017-1907-8
9. [9]
  Cheng, G.; Pérez-Mercader, J. Macromol. Rapid Commun. 2019, 40, 1800513. doi: 10.1002/marc.201800513
10. [10]
  Zhao, Q. Q.; Liu, Q. Z.; Li, C.; Cao, L.; Ma, L.; Wang, X. Y.; Cai, Y. L. Chem. Commun. 2020, 56, 4954. doi: 10.1039/D0CC00427H
11. [11]
  Penfold, N. J. W.; Yeow, J.; Boyer, C.; Armes, S. P. ACS Macro Lett. 2019, 8, 1029. doi: 10.1021/acsmacrolett.9b00464
12. [12]
  Liu, C.; Hong, C. Y.; Pan, C. Y. Polym. Chem. 2020, 11, 3673. doi: 10.1039/D0PY00455C
13. [13]
  D'Agosto, F.; Rieger, J.; Lansalot, M. Angew. Chem., Int. Ed. 2019, 59, 2.
14. [14]
  Tan, J. B.; Xu, Q.; Li, X. L.; He, J.; Zhang, Y. X.; Dai, X. C.; Yu, L. L.; Zeng, R. M.; Zhang, L. Macromol. Rapid Commun. 2018, 39, 1700871. doi: 10.1002/marc.201700871
15. [15]
  Zheng, J. W.; Wang, X.; An, Z. S. Acta Polym. Sin. 2019, 50, 1167 (in Chinese).
16. [16]
  Mane, S. R. New J. Chem. 2020, 44, 6690. doi: 10.1039/C9NJ05638F
17. [17]
  Zhu, Y.; Ye, W. L.; Liu, Z. F.; Deng, W.; Liu, M. N. Acta Polym. Sin. 2019, 50, 44 (in Chinese).
18. [18]
  Slugovc, C. Macromol. Rapid Commun. 2004, 25, 1283. doi: 10.1002/marc.200400150
19. [19]
  Bielawski, C. W.; Grubbs, R. H. Prog. Polym. Sci. 2007, 32, 1. doi: 10.1016/j.progpolymsci.2006.08.006
20. [20]
  Frenzel, U.; Nuyken, O. J. Polym. Sci., Part A: Polym. Chem. 2002, 40, 2895. doi: 10.1002/pola.10324
21. [21]
  Bielawski, C. W.; Grubbs, R. H. Angew. Chem., Int. Ed. 2000, 39, 2903. doi: 10.1002/1521-3773(20000818)39:16<2903::AID-ANIE2903>3.0.CO;2-Q
22. [22]
  Vougioukalakis, G. C.; Grubbs, R. H. Chem. Rev. 2010, 110, 1746. doi: 10.1021/cr9002424
23. [23]
  Claverie, J. P.; Viala, S.; Maurel, V.; Novat, C. Macromolecules 2001, 34, 382. doi: 10.1021/ma001570m
24. [24]
  Chemtob, A.; Héroguez, V.; Gnanou, Y. Macromolecules 2002, 35, 9262. doi: 10.1021/ma020871o
25. [25]
  Le, D.; Montembault, V.; Pascual, S.; Collette, F.; Héroguez, V.; Fontaine, L. Polym. Chem. 2013, 4, 2168. doi: 10.1039/c3py21103g
26. [26]
  Hilf, S.; Kilbinger, A. F. M. Nat. Chem. 2009, 1, 537. doi: 10.1038/nchem.347
27. [27]
  Le, D.; Dilger, M.; Pertici, V.; Diabaté, S.; Gigmes, D.; Weiss, C.; Delaittre, G. Angew. Chem., Int. Ed. 2019, 58, 4725. doi: 10.1002/anie.201813434
28. [28]
  Zhang, L. Y.; Song, C.; Yu, J. H.; Yang, D.; Xie, M. R. J. Polym. Sci., Part A: Polym. Chem. 2010, 48, 5231. doi: 10.1002/pola.24323
29. [29]
  Liu, J. W.; Liao, Y.; He, X. H.; Yu, J. H.; Ding, L.; Xie, M. R. Macromol. Chem. Phys. 2011, 212, 55. doi: 10.1002/macp.201000416
30. [30]
  Yoon, K.-Y.; Lee, I.-H.; Kim, K. O.; Jang, J.; Lee, E.; Choi, T.-L. J. Am. Chem. Soc. 2012, 134, 14291. doi: 10.1021/ja305150c
31. [31]
  Wright, D. B.; Touve, M. A.; Adamiak, L.; Gianneschi, N. C. ACS Macro Lett. 2017, 6, 925. doi: 10.1021/acsmacrolett.7b00408
32. [32]
  Foster, J. C.; Varlas, S.; Blackman, L. D.; Arkinstall, L. A.; O'Reilly, R. K. Angew. Chem., Int. Ed. 2018, 57, 10672. doi: 10.1002/anie.201806719
33. [33]
  Varlas, S.; Foster, J. C.; Arkinstall, L. A.; Jones, J. R.; Keogh, R.; Mathers, R. T.; O'Reilly, R. K. ACS Macro Lett. 2019, 8, 466. doi: 10.1021/acsmacrolett.9b00117
34. [34]
  Wright, D. B.; Touve, M. A.; Thompson, M. P.; Gianneschi, N. C. ACS Macro Lett. 2018, 7, 401. doi: 10.1021/acsmacrolett.8b00091
35. [35]
  Sha, Y.; Rahman, M. A.; Zhu, T. Y.; Cha, Y. J.; McAlister, C. W.; Tang, C. B. Chem. Sci. 2019, 10, 9782. doi: 10.1039/C9SC03056E
36. [36]
  Torres-Rocha, O. L.; Wu, X. W.; Zhu, C. Y.; Crudden, C. M.; Cunningham, M. F. Macromol. Rapid Commun. 2019, 40, 1800326. doi: 10.1002/marc.201800326
37. [37]
  Wright, D. B.; Proetto, M. T.; Touve, M. A.; Gianneschi, N. C. Polym. Chem. 2019, 10, 2996. doi: 10.1039/C8PY01539B
38. [38]
  Wright, D. B.; Thompson, M. P.; Touve, M. A.; Carlini, A. S.; Gianneschi, N. C. Macromol. Rapid Commun. 2019, 40, 1800467. doi: 10.1002/marc.201800467
39. [39]
  Deming, T. J. Prog. Polym. Sci. 2007, 32, 858. doi: 10.1016/j.progpolymsci.2007.05.010
40. [40]
  Shen, Y.; Fu, X. H.; Fu, W. X.; Li, Z. B. Chem. Soc. Rev. 2015, 44, 612. doi: 10.1039/C4CS00271G
41. [41]
  Sun, H.; Hong, Y. X.; Xi, Y. J.; Zou, Y. J.; Gao, J. Y.; Du, J. Z. Biomacromolecules 2018, 19, 1701. doi: 10.1021/acs.biomac.8b00208
42. [42]
  Xu, Y.; Zhao, Y.; Zhang, Y. J.; Cui, Z. F.; Wang, L. H.; Fan, C. H.; Gao, J. M.; Sun, Y. H. Acta Chim. Sinica 2018, 76, 393 (in Chinese).
43. [43]
  Lv, M. X.; Mai, W. P.; Lu, Q.; Duan, B. C.; Zhao, Y. F. Chin. J. Org. Chem. 2018, 38, 148 (in Chinese).
44. [44]
  Deming, T. J. Nature 1997, 390, 386. doi: 10.1038/37084
45. [45]
  González-Henríquez, C. M.; Sarabia-Vallejos, M. A.; Rodríguez- Hernández, J. Polymers 2017, 9, 551. doi: 10.3390/polym9110551
46. [46]
  Jiang, J. H.; Zhang, X. Y.; Fan, Z.; Du, J. Z. ACS Macro Lett. 2019, 8, 1216. doi: 10.1021/acsmacrolett.9b00606
47. [47]
  Grazon, C.; Salas-Ambrosio, P.; Ibarboure, E.; Buol, A.; Garanger, E.; Grinstaff, M. W.; Lecommandoux, S.; Bonduelle, C. Angew. Chem., Int. Ed. 2020, 59, 622. doi: 10.1002/anie.201912028
48. [48]
  Song, T.; Xi, Y. J.; Du, J. Z. Acta Polym. Sin. 2018, 119 (in Chinese).
49. [49]
  Zou, Y. J.; He, S. S.; Du, J. Z. Chin. J. Polym. Sci. 2018, 36, 1239. doi: 10.1007/s10118-018-2156-1
50. [50]
  Agarwal, S. Polym. Chem. 2010, 1, 953. doi: 10.1039/c0py00040j
51. [51]
  Nuyken, O.; Pask, D. S. Polymers 2013, 5, 361. doi: 10.3390/polym5020361
52. [52]
  Tardy, A.; Nicolas, J.; Gigmes, D.; Lefay, C.; Guillaneuf, Y. Chem. Rev. 2017, 117, 1319. doi: 10.1021/acs.chemrev.6b00319
53. [53]
  Guégain, E.; Zhu, C.; Giovanardi, E.; Nicolas, J. Macromolecules 2019, 52, 3612. doi: 10.1021/acs.macromol.9b00161
1. [1]
  Lu XU , Chengyu ZHANG , Wenjuan JI , Haiying YANG , Yunlong FU . Zinc metal-organic framework with high-density free carboxyl oxygen functionalized pore walls for targeted electrochemical sensing of paracetamol. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 907-918. doi: 10.11862/CJIC.20230431
2. [2]
  Jing SU , Bingrong LI , Yiyan BAI , Wenjuan JI , Haiying YANG , Zhefeng Fan . Highly sensitive electrochemical dopamine sensor based on a highly stable In-based metal-organic framework with amino-enriched pores. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1337-1346. doi: 10.11862/CJIC.20230414
3. [3]
  Yuhao SUN , Qingzhe DONG , Lei ZHAO , Xiaodan JIANG , Hailing GUO , Xianglong MENG , Yongmei GUO . Synthesis and antibacterial properties of silver-loaded sod-based zeolite. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 761-770. doi: 10.11862/CJIC.20230169
4. [4]
  Doudou Qin , Junyang Ding , Chu Liang , Qian Liu , Ligang Feng , Yang Luo , Guangzhi Hu , Jun Luo , Xijun Liu . Addressing Challenges and Enhancing Performance of Manganese-based Cathode Materials in Aqueous Zinc-Ion Batteries. Acta Physico-Chimica Sinica, 2024, 40(10): 2310034-. doi: 10.3866/PKU.WHXB202310034
5. [5]
  Wen YANG , Didi WANG , Ziyi HUANG , Yaping ZHOU , Yanyan FENG . La promoted hydrotalcite derived Ni-based catalysts: In situ preparation and CO₂ methanation performance. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 561-570. doi: 10.11862/CJIC.20230276
6. [6]
  Qiangqiang SUN , Pengcheng ZHAO , Ruoyu WU , Baoyue CAO . Multistage microporous bifunctional catalyst constructed by P-doped nickel-based sulfide ultra-thin nanosheets for energy-efficient hydrogen production from water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1151-1161. doi: 10.11862/CJIC.20230454
7. [7]
  Zhaoyang WANG , Chun YANG , Yaoyao Song , Na HAN , Xiaomeng LIU , Qinglun WANG . Lanthanide(Ⅲ) complexes derived from 4′-(2-pyridyl)-2, 2′∶6′, 2″-terpyridine: Crystal structures, fluorescent and magnetic properties. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1442-1451. doi: 10.11862/CJIC.20240114
8. [8]
  Youlin SI , Shuquan SUN , Junsong YANG , Zijun BIE , Yan CHEN , Li LUO . Synthesis and adsorption properties of Zn(Ⅱ) metal-organic framework based on 3, 3', 5, 5'-tetraimidazolyl biphenyl ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1755-1762. doi: 10.11862/CJIC.20240061
9. [9]
  Ruolin CHENG , Haoran WANG , Jing REN , Yingying MA , Huagen LIANG . Efficient photocatalytic CO₂ cycloaddition over W₁₈O₄₉/NH₂-UiO-66 composite catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 523-532. doi: 10.11862/CJIC.20230349
10. [10]
  Ziling Jiang , Shaoqing Chen , Chaochao Wei , Ziqi Zhang , Zhongkai Wu , Qiyue Luo , Liang Ming , Long Zhang , Chuang Yu . Enabling superior electrochemical performance of NCA cathode in Li_5.5PS_4.5Cl_1.5-based solid-state batteries with a dual-electrolyte layer. Chinese Chemical Letters, 2024, 35(4): 108561-. doi: 10.1016/j.cclet.2023.108561
11. [11]
  Xinyu ZENG , Guhua TANG , Jianming OUYANG . Inhibitory effect of Desmodium styracifolium polysaccharides with different content of carboxyl groups on the growth, aggregation and cell adhesion of calcium oxalate crystals. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1563-1576. doi: 10.11862/CJIC.20230374
12. [12]
  Junke LIU , Kungui ZHENG , Wenjing SUN , Gaoyang BAI , Guodong BAI , Zuwei YIN , Yao ZHOU , Juntao LI . Preparation of modified high-nickel layered cathode with LiAlO₂/cyclopolyacrylonitrile dual-functional coating. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1461-1473. doi: 10.11862/CJIC.20240189
13. [13]
  Peng XU , Shasha WANG , Nannan CHEN , Ao WANG , Dongmei YU . Preparation of three-layer magnetic composite Fe₃O₄@polyacrylic acid@ZiF-8 for efficient removal of malachite green in water. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 544-554. doi: 10.11862/CJIC.20230239
14. [14]
  Le Ye , Wei-Xiong Zhang . Structural phase transition in a new organic-inorganic hybrid post-perovskite: (N,N-dimethylpyrrolidinium)[Mn(N(CN)2)3]. Chinese Journal of Structural Chemistry, 2024, 43(6): 100257-100257. doi: 10.1016/j.cjsc.2024.100257
15. [15]
  Xingfen Huang , Jiefeng Zhu , Chuan He . Catalytic enantioselective N-silylation of sulfoximine. Chinese Chemical Letters, 2024, 35(4): 108783-. doi: 10.1016/j.cclet.2023.108783
16. [16]
  Shengkai Li , Yuqin Zou , Chen Chen , Shuangyin Wang , Zhao-Qing Liu . Defect engineered electrocatalysts for C–N coupling reactions toward urea synthesis. Chinese Chemical Letters, 2024, 35(8): 109147-. doi: 10.1016/j.cclet.2023.109147
17. [17]
  Lijun Mao , Shuo Li , Xin Zhang , Zhan-Ting Li , Da Ma . Cucurbit[n]uril-based nanostructure construction and modification. Chinese Chemical Letters, 2024, 35(8): 109363-. doi: 10.1016/j.cclet.2023.109363
18. [18]
  Jianhui Yin , Wenjing Huang , Changyong Guo , Chao Liu , Fei Gao , Honggang Hu . Tryptophan-specific peptide modification through metal-free photoinduced N-H alkylation employing N-aryl glycines. Chinese Chemical Letters, 2024, 35(6): 109244-. doi: 10.1016/j.cclet.2023.109244
19. [19]
  Yun-Xin Huang , Lin-Qian Yu , Ke-Yu Chen , Hao Wang , Shou-Yan Zhao , Bao-Cheng Huang , Ren-Cun Jin . Biochar with self-doped N to activate peroxymonosulfate for bisphenol-A degradation via electron transfer mechanism: The active edge graphitic N site. Chinese Chemical Letters, 2024, 35(9): 109437-. doi: 10.1016/j.cclet.2023.109437
20. [20]
  Weichen Zhu , Wei Zuo , Pu Wang , Wei Zhan , Jun Zhang , Lipin Li , Yu Tian , Hong Qi , Rui Huang . Fe-N-C heterogeneous Fenton-like catalyst for the degradation of tetracycline: Fe-N coordination and mechanism studies. Chinese Chemical Letters, 2024, 35(9): 109341-. doi: 10.1016/j.cclet.2023.109341

Get Citation

PDF

XML

Metrics

PDF Downloads(32)
Abstract views(2690)
HTML views(817)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142