Citation: Qi Meiwei, Liu Yong, Zhou Yongfeng. A Supramolecular Janus Hyperbranched Polymer and Its Electrochemically Responsive Self-Assembly Behavior[J]. Acta Chimica Sinica, ;2020, 78(6): 528-533. doi: 10.6023/A20040121 shu

A Supramolecular Janus Hyperbranched Polymer and Its Electrochemically Responsive Self-Assembly Behavior

School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University, Shanghai 200240

Corresponding author: Zhou Yongfeng, songguo@pku.edu.cn
Received Date: 24 April 2020
Available Online: 2 June 2020
Fund Project: Project supported by the National Natural Science Foundation of China (Nos. 21890730, 21890733)the National Natural Science Foundation of China 21890730the National Natural Science Foundation of China 21890733

Figures(7)

Herein, we report a Janus supramolecular polymer consisting of two chemically distinct hyperbranched polymers, which is coined as Janus hyperbranched polymer (JHBP). Firstly, hydrophilic hyperbranched polyglycerol with an apex of β-cyclodextrin (CD-g-HPG) and hydrophobic hyperbranched poly(3-ethyl-3-oxetanemethanol) with an apex of a ferrocene (Fc-g-HBPO) were synthesized according to the anionic ring-opening multi-branching polymerization and cationic ring-opening polymerization, respectively. Then, amphiphilic supramolecular JHBP HBPO-b-HPG was constructed by adding H₂O to cosolvent DMF through the special Fc/CD host-guest interactions and such an amphiphilic supramolecular polymer can further aggregated into assemblies. The formation and self-assembly process of supramolecular JHBP HBPO-b-HPG was tracked by dynamic light scattering (DLS). The results showed that when the volume percentage ratio of H₂O/DMF was increased to 16%, the HBPO-b-HPG was formed with D_h of 5.6 nm, which is close to the size of the 1:1 complex of CD-g-HPG and Fc-g-HBPO, then, with H₂O/DMF ratio continuing to increase, HBPO-b-HPG rapidly aggregated into assemblies. The 2D NOESY and cyclic voltammetry (CV) curves were also used to verify the Fc/CD host-guest complexation ability. The scanning electron microscopy (SEM) and transmission electron microscopy (TEM) were employed to characterize the morphology of the assemblies. The results showed that the HBPO-b-HPG self-assembled into unilamellar bilayer vesicles of around 260 nm. When NaCl was added after electrochemical oxidation, such vesicles could disassemble due to the cooperation of the transformation of Fc to oxidation state Fc⁺ and equal potential destruction. Finally, DLS tracking proved that such vesicles showed excellent stability under the conditions of heating and adding host and guest competition molecules.
- Janus particle,
- hyperbranched polymer,
- host-guest interaction,
- vesicle,
- electrochemically responsive
1. [1]
  Walther, A; Müller, A. H. E. Soft Matter 2008, 4, 663. doi: 10.1039/b718131k
2. [2]
  de Gennes, P. G. Angew. Chem., Int. Ed. 1992, 31, 842. doi: 10.1002/anie.199208421
3. [3]
  Hu, J.; Zhou, S. X.; Sun, Y. Y.; Fang, X. S.; Wu, L. M. Chem. Soc. Rev. 2012, 41, 4356. doi: 10.1039/c2cs35032g
4. [4]
  Du, J. Z.; O'Reilly, R. K. Chem. Soc. Rev. 2011, 40, 2402. doi: 10.1039/c0cs00216j
5. [5]
  Pang, X; Wan, C.; Wang, M.; Lin, Z. Angew. Chem., Int. Ed. 2014, 53, 5524. doi: 10.1002/anie.201309352
6. [6]
  Chen, Q.; Whitmer, J. K.; Jiang, S.; Bae, S. C.; Luijten, E.; Granick, S. Science 2011, 311, 199.
7. [7]
  Nie, L.; Liu, S. Y.; Shen, W. M.; Chen, D. Y.; Jiang, M. Angew. Chem., Int. Ed. 2007, 46, 6321. doi: 10.1002/anie.200700209
8. [8]
  Zhang, K. K.; Jiang, M.; Chen, D. Y. Prog. Polym. Sci. 2012, 37, 445. doi: 10.1016/j.progpolymsci.2011.09.003
9. [9]
  Hawker, C. J.; Fréchet, J. M. J. J. Am. Chem. Soc. 1992, 114, 8405. doi: 10.1021/ja00048a009
10. [10]
  Rosen, B. M.; Wilson, C. J.; Wilson, D. A.; Peterca, M.; Imam, M. R.; Percec, V. Chem. Rev. 2009, 109, 6275. doi: 10.1021/cr900157q
11. [11]
  Saez, I. M.; Goodby, J. W. Chem. Commun. 2003, 1726.
12. [12]
  Saez, I. M.; Goodby, J. W. Chem. Eur. J. 2003, 9, 4869. doi: 10.1002/chem.200305100
13. [13]
  Percec, V.; Iman, M. R.; Peterca, M.; Leowanawat, P. J. Am. Chem. Soc. 2012, 134, 4408. doi: 10.1021/ja2118267
14. [14]
  Percec, V.; Imam, M. R.; Bera, T. K.; Balagurusamy, V. S. K.; Peterca, M.; Heiney, P. A. Angew. Chem., Int. Ed. 2005, 44, 4739. doi: 10.1002/anie.200501254
15. [15]
  Khandare, J.; Calderon, M.; Dagia, N. M.; Haag, R. Chem. Soc. Rev. 2012, 41, 2824. doi: 10.1039/C1CS15242D
16. [16]
  Percec, V.; Wilson, D. A.; Leowanawat, P.; Wilson, C. J.; Hughes, A. D.; Kaucher, M. S.; Hammer, D. A.; Levine, D. H.; Kim, A. J.; Bates, F. S.; Davis, K. P.; Lodge, T. P.; Klein, M. L.; DeVane, R. H.; Aqad, E.; Rosen, B. M.; Argintaru, A. O.; Sienkowska, M. J.; Rissanen, K.; Nummelin, S.; Ropponen, J. Science 2010, 328, 1009. doi: 10.1126/science.1185547
17. [17]
  Peterca, M.; Percec, V.; Leowanawat, P.; Bertin, A. J. Am. Chem. Soc. 2011, 133, 20507. doi: 10.1021/ja208762u
18. [18]
  Flory, P. J. Am. Chem. Soc, 1952, 74, 2718. doi: 10.1021/ja01131a008
19. [19]
  Kim, Y.; Webster, O. Polym Prepr. 1988, 29, 310.
20. [20]
  Yan, D. Y.; Gao, C. Macromolecules 2000, 33, 7693. doi: 10.1021/ma000438j
21. [21]
  Gao, C.; Yan, D. Y. Prog. Polym. Sci. 2004, 29, 183. doi: 10.1016/j.progpolymsci.2003.12.002
22. [22]
  Jin, H. B.; Huang, W.; Zhu, X. Y.; Zhou, Y. F.; Yan, D. Y. Chem. Soc. Rev. 2012, 41, 5986. doi: 10.1039/c2cs35130g
23. [23]
  Zhou, Y. F.; Huang, W.; Liu, J. Y.; Zhu, X. Y.; Yan, D. Y. Adv. Mater. 2010, 22, 4567. doi: 10.1002/adma.201000369
24. [24]
  Bednarek, M.; Kubisa, P.; Penczek, S. Macromolecules 2011, 34, 5112.
25. [25]
  Ohta, Y.; Abe, Y.; Hoka, K.; Baba, E.; Lee, Y. P.; Dai, C. A.; Yokozawa, T. Polym. Chem. 2019, 10, 4246. doi: 10.1039/C8PY01419A
26. [26]
  Qie, S. Y.; Hao, Y.; Liu, Z. J.; Wang, J.; Xi, J. N. Acta Chim. Sinica 2020, 78, 232.
27. [27]
  Hofmeier, H.; Schubert, U. S. Chem. Soc. Rev. 2004, 33, 373. doi: 10.1039/B400653B
28. [28]
  Aida, T.; Meijer, E. W.; Stupp, S. I. Science 2012, 335, 813. doi: 10.1126/science.1205962
29. [29]
  Zhang, X.; Wang, L. Y.; Xu, J. F.; Chen, D. Y.; Shi, L. Q.; Zhou, Y. F.; Shen, Z. H. Acta Polym. Sin. 2019, 50, 973. doi: 10.11777/j.issn1000-3304.2019.19109
30. [30]
  Liu, Y.; Yu, C. Y.; Jin, H. B.; Zhu, X. Y.; Zhou, Y. F.; Lu, Z. Y.; Yan, D. Y. J. Am. Chem. Soc. 2013, 132, 4765.
31. [31]
  Yang, L.; Guo, Y. Z.; Lei, Z. L. J. Mater. Chem. A 2015, 3, 17098. doi: 10.1039/C5TA03937A
32. [32]
  Harada, A.; Takahashi, S. J. Am. Chem. Soc. 1984, 10, 645.
33. [33]
  Matsue, T.; Evans, D. H.; Osa, T.; Kobayashi, N. J. Am. Chem. Soc. 1985, 107, 3411. doi: 10.1021/ja00298a003
34. [34]
  Nakahata, M.; Takashima, Y.; Yamaguchi, H.; Harada, A. Nat. Commun. 2011, 2, 511. doi: 10.1038/ncomms1521
35. [35]
  Wang, Z. P.; Feng Z. Q.; Gao, C. Y. Chem. Mater. 2008, 20, 4194. doi: 10.1021/cm8003358
36. [36]
  Mai, Y. Y.; Eisenberg, A. Chem. Soc. Rev. 2012, 41, 5969. doi: 10.1039/c2cs35115c
37. [37]
  Jiang, W. F.; Zhou, Y. F. Chem. Soc. Rev. 2015, 44, 3874. doi: 10.1039/C4CS00274A
38. [38]
  Sun, H.; Wang, F.; Du, J. Z. Sci. Sin. Chim. 2019, 49, 877.
39. [39]
  Zhu, Y. Q.; Yang, B.; Chen, S.; Du, J. Z. Prog. Polym. Sci. 2017, 64, 1. doi: 10.1016/j.progpolymsci.2015.05.001
40. [40]
  Atthoff, B.; Trollsås, M.; Claesson, H.; Hedrick, J. L. Macromol. Chem. Phys. 1999, 200, 1333. doi: 10.1002/(SICI)1521-3935(19990601)200:6<1333::AID-MACP1333>3.0.CO;2-G
41. [41]
  Strelets, V. V.; Mamedjarova, I. A.; Nefedova, M. N.; Pysnograeva, N. I.; Sokolov, V. I.; Pospíšil, L. J. Electroanal. Chem. Interf. Electrochem. 1991, 310, 179. doi: 10.1016/0022-0728(91)85261-M
42. [42]
  Du, P.; Liu, J.; Chen, G.; Jiang, M. Langmuir 2011, 27, 9602. doi: 10.1021/la201843z
43. [43]
  Hong, H. Y. Ph.D. Dissertation, Shanghai Jiao Tong University, Shanghai, 2009.
1. [1]
  Tiantian MA , Sumei LI , Chengyu ZHANG , Lu XU , Yiyan BAI , Yunlong FU , Wenjuan JI , Haiying YANG . Methyl-functionalized Cd-based metal-organic framework for highly sensitive electrochemical sensing of dopamine. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 725-735. doi: 10.11862/CJIC.20230351
2. [2]
  Jiahong ZHENG , Jiajun SHEN , Xin BAI . Preparation and electrochemical properties of nickel foam loaded NiMoO₄/NiMoS₄ composites. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 581-590. doi: 10.11862/CJIC.20230253
3. [3]
  Zhihuan XU , Qing KANG , Yuzhen LONG , Qian YUAN , Cidong LIU , Xin LI , Genghuai TANG , Yuqing LIAO . Effect of graphene oxide concentration on the electrochemical properties of reduced graphene oxide/ZnS. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1329-1336. doi: 10.11862/CJIC.20230447
4. [4]
  Qin ZHU , Jiao MA , Zhihui QIAN , Yuxu LUO , Yujiao GUO , Mingwu XIANG , Xiaofang LIU , Ping NING , Junming GUO . Morphological evolution and electrochemical properties of cathode material LiAl_0.08Mn_1.92O₄ single crystal particles. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1549-1562. doi: 10.11862/CJIC.20240022
5. [5]
  Qingtang ZHANG , Xiaoyu WU , Zheng WANG , Xiaomei WANG . Performance of nano Li₂FeSiO₄/C cathode material co-doped by potassium and chlorine ions. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1689-1696. doi: 10.11862/CJIC.20240115
6. [6]
  Lu XU , Chengyu ZHANG , Wenjuan JI , Haiying YANG , Yunlong FU . Zinc metal-organic framework with high-density free carboxyl oxygen functionalized pore walls for targeted electrochemical sensing of paracetamol. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 907-918. doi: 10.11862/CJIC.20230431
7. [7]
  Yuanchao LI , Weifeng HUANG , Pengchao LIANG , Zifang ZHAO , Baoyan XING , Dongliang YAN , Li YANG , Songlin WANG . Effect of heterogeneous dual carbon sources on electrochemical properties of LiMn_0.8Fe_0.2PO₄/C composites. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 751-760. doi: 10.11862/CJIC.20230252
8. [8]
  Xinpeng LIU , Liuyang ZHAO , Hongyi LI , Yatu CHEN , Aimin WU , Aikui LI , Hao HUANG . Ga₂O₃ coated modification and electrochemical performance of Li_1.2Mn_0.54Ni_0.13Co_0.13O₂ cathode material. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1105-1113. doi: 10.11862/CJIC.20230488
9. [9]
  Jing SU , Bingrong LI , Yiyan BAI , Wenjuan JI , Haiying YANG , Zhefeng Fan . Highly sensitive electrochemical dopamine sensor based on a highly stable In-based metal-organic framework with amino-enriched pores. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1337-1346. doi: 10.11862/CJIC.20230414
10. [10]
  Hongyi LI , Aimin WU , Liuyang ZHAO , Xinpeng LIU , Fengqin CHEN , Aikui LI , Hao HUANG . Effect of Y(PO₃)₃ double-coating modification on the electrochemical properties of Li[Ni_0.8Co_0.15Al_0.05]O₂. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1320-1328. doi: 10.11862/CJIC.20230480
11. [11]
  Donghui PAN , Yuping XU , Xinyu WANG , Lizhen WANG , Junjie YAN , Dongjian SHI , Min YANG , Mingqing CHEN . Preparation and in vivo tracing of ⁶⁸Ga-labeled PM_2.5 mimetic particles for positron emission tomography imaging. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 669-676. doi: 10.11862/CJIC.20230468
12. [12]
  Peiran ZHAO , Yuqian LIU , Cheng HE , Chunying DUAN . A functionalized Eu³⁺ metal-organic framework for selective fluorescent detection of pyrene. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 713-724. doi: 10.11862/CJIC.20230355
13. [13]
  Jinlong YAN , Weina WU , Yuan WANG . A simple Schiff base probe for the fluorescent turn-on detection of hypochlorite and its biological imaging application. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1653-1660. doi: 10.11862/CJIC.20240154
14. [14]
  Di WU , Ruimeng SHI , Zhaoyang WANG , Yuehua SHI , Fan YANG , Leyong ZENG . Construction of pH/photothermal dual-responsive delivery nanosystem for combination therapy of drug-resistant bladder cancer cell. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1679-1688. doi: 10.11862/CJIC.20240135
15. [15]
  Guangming YIN , Huaiyao WANG , Jianhua ZHENG , Xinyue DONG , Jian LI , Yi'nan SUN , Yiming GAO , Bingbing WANG . Preparation and photocatalytic degradation performance of Ag/protonated g-C₃N₄ nanorod materials. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1491-1500. doi: 10.11862/CJIC.20240086
16. [16]
  Zongfei YANG , Xiaosen ZHAO , Jing LI , Wenchang ZHUANG . Research advances in heteropolyoxoniobates. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 465-480. doi: 10.11862/CJIC.20230306
17. [17]
  Yufang GAO , Nan HOU , Yaning LIANG , Ning LI , Yanting ZHANG , Zelong LI , Xiaofeng LI . Nano-thin layer MCM-22 zeolite: Synthesis and catalytic properties of trimethylbenzene isomerization reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1079-1087. doi: 10.11862/CJIC.20240036
18. [18]
  Qilu DU , Li ZHAO , Peng NIE , Bo XU . Synthesis and characterization of osmium-germyl complexes stabilized by triphenyl ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1088-1094. doi: 10.11862/CJIC.20240006
19. [19]
  Haitang WANG , Yanni LING , Xiaqing MA , Yuxin CHEN , Rui ZHANG , Keyi WANG , Ying ZHANG , Wenmin WANG . Construction, crystal structures, and biological activities of two Ln^Ⅲ₃ complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1474-1482. doi: 10.11862/CJIC.20240188
20. [20]
  Chuanming GUO , Kaiyang ZHANG , Yun WU , Rui YAO , Qiang ZHAO , Jinping LI , Guang LIU . Performance of MnO₂-0.39IrO_x composite oxides for water oxidation reaction in acidic media. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1135-1142. doi: 10.11862/CJIC.20230459

Get Citation

PDF

XML

Metrics

PDF Downloads(16)
Abstract views(1246)
HTML views(227)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142