Citation: Shui Ziyi, He Nana, Chen Li, Zhao Wei, Chen Xi. Porous Perovskite towards Oxygen Reduction Reaction in Flexible Aluminum-Air Battery[J]. Acta Chimica Sinica, ;2020, 78(6): 557-564. doi: 10.6023/A20030068 shu

Porous Perovskite towards Oxygen Reduction Reaction in Flexible Aluminum-Air Battery

Shui Ziyi ^a ,
He Nana ^a ,
Chen Li ^a ,
Zhao Wei ^a,, ,
Chen Xi ^a,b,,

a.
Northwest University, School of Chemical Engineering, Xi'an 710069
b.
Columbia University, Department of Earth and Environmental Engineering, New York NY 10027

Corresponding author: Zhao Wei, zhaowei3313@nwu.edu.cn Chen Xi, xichen863@hotmail.com
Received Date: 14 March 2020
Available Online: 18 May 2020
Fund Project: the National Natural Science Foundation of China 11872302the Shaanxi Provincial Department of Education Natural Science Special Project 20JK0927the Natural Science Basic Research Program of Shaanxi Province 2019JQ-431Project supported by the National Natural Science Foundation of China (No. 11872302), the Natural Science Basic Research Program of Shaanxi Province (No. 2019JQ-431) and the Shaanxi Provincial Department of Education Natural Science Special Project (No. 20JK0927)

Figures(9)

Perovskite-type catalytic materials have received wide attention as high-performance and low-cost alternatives to precious metal catalysts on the market at present, which have much considerable activity and stability as catalysts for oxygen reduction reactions. Current efforts are mainly focused on the use of perovskite make-up and preparation techniques to influence elemental composition, morphology, surface area, and structural control. For a typical perovskite oxide (ABO₃), due to the high calcination temperature in the preparation process, the perovskite material usually has a small specific surface area, which limits the increase of activity in heterogeneous catalytic reactions. In this paper, the perovskite La_0.7Sr_0.3MnO₃ (LSMO) material with large specific surface and high catalytic activity is prepared by means of the SiO₂ template. The physicochemical properties of the synthesized materials are characterized by scanning electron microscope (SEM), energy dispersed X-ray spectroscopy (EDS), X-ray diffraction (XRD) and BET. The catalytic activity of LSMO as an oxygen reduction reaction (ORR) catalyst is measured by a rotating disk test system. After that, the catalyst material is applied to a flexible aluminum-air battery and its discharge behavior and flexibility is studied and tested. The test results show that the LSMO prepared by template method has a large specific surface area (31.1825 m²·g^-1), and pore volume (0.161113 cm³·g^-1), and it also shows higher electrocatalytic activity in the electrochemical test system. When it is used in aluminum-air batteries, the activity of 3D porous LSMO is significantly better than that of sheet and bulk LSMO. The aluminum-air battery assembled by LSMO prepared by the template method has a higher discharge voltage (up to 1.46 V) at a constant current. Compared to the template-free method and the sol-gel method, the discharge voltage in flexible aluminum-air battery can be increased by 8.2% and 24.5%, respectively, and the performance degradation is significantly slowed during high-current discharge. The specific capacity and energy density of the battery are up to 1048.6 mA·h·g^-1 and 1020.6 mW·h·g^-1, respectively. When the battery is in a deformed state, its output voltage can be stabilized above 1.38 V. Once released, the voltage can be immediately restored to over 99% of the initial value. This paper not only provides a solution for the commercialization of fuel cell, but also provides a new direction for the future development of variable power supply.
- perovskite oxide,
- specific surface area,
- oxygen reduction reaction,
- catalytic activity,
- flexible aluminum-air battery
1. [1]
  Song, M. J.; Shin, M. W. Appl. Surf. Sci. 2014, 320, 435. doi: 10.1016/j.apsusc.2014.09.100
2. [2]
  Arora, P.; Zhang, Z. J. Chem. Rev. 2004, 104, 4419 doi: 10.1021/cr020738u
3. [3]
  Xu, Y.; Zhao, Y.; Ren, J.; Zhang, Y.; Peng, H. Angew. Chem., Int. Ed. 2016, 55, 7979. doi: 10.1002/anie.201601804
4. [4]
  Que, Y.; Qi, M.; Shi, P. Chin. Battery Ind. 2019, 23, 147. doi: 10.3969/j.issn.1008-7923.2019.03.007
5. [5]
  Xie, K.; Wei, B. Adv. Mater. 2014, 26, 3592. doi: 10.1002/adma.201305919
6. [6]
  Cheng, F.; Chen, J. Chem. Soc. Rev. 2012, 41, 2172. doi: 10.1039/c1cs15228a
7. [7]
  Cheng, F.; Chen, J. Acta Chim. Sinica 2013, 71, 473. doi: 10.3866/PKU.WHXB201212273
8. [8]
  Hong, Q.; Lu, H. Sci. Rep. 2017, 7, 3378. doi: 10.1038/s41598-017-03609-9
9. [9]
  Li, Y. C.; Xu, Z. C.; Gasteiger, H. A.; Chen, S.; Hamad-Schifferli, K.; Yang, S.-H. J. Am. Chem. Soc. 2010, 132, 12170. doi: 10.1021/ja1036572
10. [10]
  Meng, H.; Shen, P. K. Electrochem. Commun. 2006, 8, 588. doi: 10.1016/j.elecom.2006.01.020
11. [11]
  Hao, J.; Liu, Y.; Li, W.; Li, J. Mater. Rev. 2019, 33, 127. doi: 10.11896/cldb.201901014
12. [12]
  Jin, Q.; Pei, L.; Hu, Y.; Du, J.; Han, X.; Cheng, F.; Chen, J. Acta Chim. Sinica 2014, 72, 920.
13. [13]
  Wang, D.; Chen, X.; Evans, D.-G.; Yang, W. Nanoscale 2013, 5, 5312. doi: 10.1039/c3nr00444a
14. [14]
  Wang, Y.; Wei, Z. J. Electrochem. 2018, 24, 427.
15. [15]
  Yin, W.; Shen, Y.; Zou, F.; Hu, X.; Chi, B.; Huang, Y. ACS Appl. Mater. Interfaces 2015, 7, 4947. doi: 10.1021/am509143t
16. [16]
  Liu, M.; Zhang, R.; Chen, W. Chem. Rev. 2014, 114, 5117. doi: 10.1021/cr400523y
17. [17]
  Liu, L.; Yuan, Z.; Qiu, C.; Liu, J. Solid State Ionics 2013, 241, 25. doi: 10.1016/j.ssi.2013.03.031
18. [18]
  Wang, Y.; Zhang, L.; Hu, T. Acta Chim. Sinica 2015, 73, 316.
19. [19]
  Miyazaki, K.; Kawakita, K.; Abe, T.; Fukutsuka, T.; Kojima, K.; Ogumi, Z. J. Mater. Chem. 2011, 21, 1913. doi: 10.1039/C0JM02600J
20. [20]
  Lin, S.; Xu, S.-F.; Wang, J.-D.; Xie, C.-S.; Yuan, A.-H.; Han, G.-F.; Zhang, L.; Zhang, L.-M.; Li, Y.; Yan, Z.-M. Acta Chim. Sinica 2005, 63, 385.
21. [21]
  Takeguchi, T.; Yamanaka, T.; Takahashi, H.; Watanabe, H.; Kuroki, T.; Nakanishi, H.; Orikasa, Y.; Uchimoto, Y.; Takano, H.; Ohguri, N.; Matsuda, M.; Murota, T.; Uosaki, K.; Ueda, W. J. Am. Chem. Soc. 2013, 135, 11125. doi: 10.1021/ja403476v
22. [22]
  Xue, Y.; Miao, H.; Sun, S.; Wang, Q.; Li, S.; Liu, Z. J. Power Sources 2017, 342, 192. doi: 10.1016/j.jpowsour.2016.12.065
23. [23]
  Stoerzinger, K. A.; Lü, W.; Li, C.; Ariando; Venkatesan, T.; Yang, S.-H. J. Phys. Chem. Lett. 2015, 6, 1435. doi: 10.1021/acs.jpclett.5b00439
24. [24]
  Hu, J.; Wang, L.; Shi, L.; Huang, H. J. Power Sources 2014, 269, 144. doi: 10.1016/j.jpowsour.2014.07.004
25. [25]
  Liu, Y.; Dai, H.; Du, Y.; Deng, J.; Zhang, L.; Zhao, Z.; Au, C. T. J. Catal. 2012, 287, 149. doi: 10.1016/j.jcat.2011.12.015
26. [26]
  Lee, Y. C.; Peng, P. Y.; Chang, W. S.; Huang, C. M. J. Taiwan Chem. Eng. 2014, 45, 2334. doi: 10.1016/j.jtice.2014.05.023
27. [27]
  Stöber, W.; Fink, A.; Bohn, E. J. Colloid Interface Sci. 1968, 26, 62. doi: 10.1016/0021-9797(68)90272-5
28. [28]
  Yang, C. H.; Chen, B. J.; Lu, J.; Yang, J. H.; Zhou, J.; Chen, Y. M.; Suo, Z. Extreme Mech. Lett. 2015, 25, 59.
29. [29]
  Tan, P.; Chen, B.; Xu, H.; Zhang, H.; Cai, W.; Ni, M.; Liu, M.; Shao, Z. Energy Environ. Sci. 2017, 10, 2056. doi: 10.1039/C7EE01913K
30. [30]
  Song, S.-D.; Tang, Z.-Y.; Pan, L.-Z.; Nan, J.-M. Acta Chim. Sinica 2005, 63, 363.
31. [31]
  Liu, Y.; Li, J.; Li, W.; Li, Y.; Zhan, F.; Tang, H.; Chen, Q. Int. J. Hydrogen Energy 2016, 41, 10354. doi: 10.1016/j.ijhydene.2015.10.109
32. [32]
  Zhang, Z.; Zuo, C.; Liu, Z.; Yu, Y.; Zuo, Y.; Song, Y. J. Power Sources 2014, 251, 470. doi: 10.1016/j.jpowsour.2013.11.020
1. [1]
  Xiaofeng Zhu , Bingbing Xiao , Jiaxin Su , Shuai Wang , Qingran Zhang , Jun Wang . Transition Metal Oxides/Chalcogenides for Electrochemical Oxygen Reduction into Hydrogen Peroxides. Acta Physico-Chimica Sinica, 2024, 40(12): 2407005-. doi: 10.3866/PKU.WHXB202407005
2. [2]
  Hailang JIA , Hongcheng LI , Pengcheng JI , Yang TENG , Mingyun GUAN . Preparation and performance of N-doped carbon nanotubes composite Co₃O₄ as oxygen reduction reaction electrocatalysts. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 693-700. doi: 10.11862/CJIC.20230402
3. [3]
  Heng Chen , Longhui Nie , Kai Xu , Yiqiong Yang , Caihong Fang . 两步焙烧法制备大比表面积和结晶性增强超薄g-C₃N₄纳米片及其高效光催化产H₂O₂. Acta Physico-Chimica Sinica, 2024, 40(11): 2406019-. doi: 10.3866/PKU.WHXB202406019
4. [4]
  Ping ZHANG , Chenchen ZHAO , Xiaoyun CUI , Bing XIE , Yihan LIU , Haiyu LIN , Jiale ZHANG , Yu'nan CHEN . Preparation and adsorption-photocatalytic performance of ZnAl@layered double oxides. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1965-1974. doi: 10.11862/CJIC.20240014
5. [5]
  Zhaomei LIU , Wenshi ZHONG , Jiaxin LI , Gengshen HU . Preparation of nitrogen-doped porous carbons with ultra-high surface areas for high-performance supercapacitors. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 677-685. doi: 10.11862/CJIC.20230404
6. [6]
  Endong YANG , Haoze TIAN , Ke ZHANG , Yongbing LOU . Efficient oxygen evolution reaction of CuCo₂O₄/NiFe-layered bimetallic hydroxide core-shell nanoflower sphere arrays. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 930-940. doi: 10.11862/CJIC.20230369
7. [7]
  Lin Song , Dourong Wang , Biao Zhang . Innovative Experimental Design and Research on Preparing Flexible Perovskite Fluorescent Gels Using 3D Printing. University Chemistry, 2024, 39(7): 337-344. doi: 10.3866/PKU.DXHX202310107
8. [8]
  Yixuan Gao , Lingxing Zan , Wenlin Zhang , Qingbo Wei . Comprehensive Innovation Experiment: Preparation and Characterization of Carbon-based Perovskite Solar Cells. University Chemistry, 2024, 39(4): 178-183. doi: 10.3866/PKU.DXHX202311091
9. [9]
  Xiaoxia WANG , Ya'nan GUO , Feng SU , Chun HAN , Long SUN . Synthesis, structure, and electrocatalytic oxygen reduction reaction properties of metal antimony-based chalcogenide clusters. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1201-1208. doi: 10.11862/CJIC.20230478
10. [10]
  Zeyuan WANG , Songzhi ZHENG , Hao LI , Jingbo WENG , Wei WANG , Yang WANG , Weihai SUN . Effect of I₂ interface modification engineering on the performance of all-inorganic CsPbBr₃ perovskite solar cells. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1290-1300. doi: 10.11862/CJIC.20240021
11. [11]
  Jizhou Liu , Chenbin Ai , Chenrui Hu , Bei Cheng , Jianjun Zhang . 六氯锡酸铵促进钙钛矿太阳能电池界面电子转移及其飞秒瞬态吸收光谱研究. Acta Physico-Chimica Sinica, 2024, 40(11): 2402006-. doi: 10.3866/PKU.WHXB202402006
12. [12]
  Chuanming GUO , Kaiyang ZHANG , Yun WU , Rui YAO , Qiang ZHAO , Jinping LI , Guang LIU . Performance of MnO₂-0.39IrO_x composite oxides for water oxidation reaction in acidic media. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1135-1142. doi: 10.11862/CJIC.20230459
13. [13]
  Rui Li , Huan Liu , Yinan Jiao , Shengjian Qin , Jie Meng , Jiayu Song , Rongrong Yan , Hang Su , Hengbin Chen , Zixuan Shang , Jinjin Zhao . 卤化物钙钛矿的单双向离子迁移. Acta Physico-Chimica Sinica, 2024, 40(11): 2311011-. doi: 10.3866/PKU.WHXB202311011
14. [14]
  Cheng PENG , Jianwei WEI , Yating CHEN , Nan HU , Hui ZENG . First principles investigation about interference effects of electronic and optical properties of inorganic and lead-free perovskite Cs₃Bi₂X₉ (X=Cl, Br, I). Chinese Journal of Inorganic Chemistry, 2024, 40(3): 555-560. doi: 10.11862/CJIC.20230282
15. [15]
  Tong Zhou , Jun Li , Zitian Wen , Yitian Chen , Hailing Li , Zhonghong Gao , Wenyun Wang , Fang Liu , Qing Feng , Zhen Li , Jinyi Yang , Min Liu , Wei Qi . Experiment Improvement of “Redox Reaction and Electrode Potential” Based on the New Medical Concept. University Chemistry, 2024, 39(8): 276-281. doi: 10.3866/PKU.DXHX202401005
16. [16]
  Ji-Quan Liu , Huilin Guo , Ying Yang , Xiaohui Guo . Calculation and Discussion of Electrode Potentials in Redox Reactions of Water. University Chemistry, 2024, 39(8): 351-358. doi: 10.3866/PKU.DXHX202401031
17. [17]
  Junli Liu . Practice and Exploration of Research-Oriented Classroom Teaching in the Integration of Science and Education: a Case Study on the Synthesis of Sub-Nanometer Metal Oxide Materials and Their Application in Battery Energy Storage. University Chemistry, 2024, 39(10): 249-254. doi: 10.12461/PKU.DXHX202404023
18. [18]
  Chunmei GUO , Weihan YIN , Jingyi SHI , Jianhang ZHAO , Ying CHEN , Quli FAN . Facile construction and peroxidase-like activity of single-atom platinum nanozyme. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1633-1639. doi: 10.11862/CJIC.20240162
19. [19]
  Xinyuan Shi , Chenyangjiang , Changyu Zhai , Xuemei Lu , Jia Li , Zhu Mao . Preparation and Photoelectric Performance Characterization of Perovskite CsPbBr₃ Thin Films. University Chemistry, 2024, 39(6): 383-389. doi: 10.3866/PKU.DXHX202312019
20. [20]
  Zhuo WANG , Junshan ZHANG , Shaoyan YANG , Lingyan ZHOU , Yedi LI , Yuanpei LAN . Preparation and photocatalytic performance of CeO₂-reduced graphene oxide by thermal decomposition. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1708-1718. doi: 10.11862/CJIC.20240067

Get Citation

PDF

XML

Metrics

PDF Downloads(15)
Abstract views(1351)
HTML views(128)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142