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Citation: Chen Yingying, Liu Huan, Cheng Yan, Xie Qingji. Preparation of Honeycomb-structured AuPtCu Electrocatalyst by Dynamic Hydrogen Bubble and Sacrificial Cu Templates for Oxidation of Formic Acid[J]. Acta Chimica Sinica, ;2020, 78(4): 330-336. doi: 10.6023/A19110400 shu

Preparation of Honeycomb-structured AuPtCu Electrocatalyst by Dynamic Hydrogen Bubble and Sacrificial Cu Templates for Oxidation of Formic Acid

  • Key Laboratory of Chemical Biology & Traditional Chinese Medicine Research(Ministry of Education of China), College of Chemistry and Chemical Engineering, Hunan Normal University, Changsha 410081

  • Corresponding author: Xie Qingji, xieqj@hunnu.edu.cn
  • Received Date: 12 November 2019
    Available Online: 11 March 2020

    Fund Project: the National Natural Science Foundation of China 21475041Project supported by the National Natural Science Foundation of China (Nos. 21675050, 21475041 and 21775137), Hunan Lotus Scholars Program (2011) and Foundation of the Science & Technology Department of Hunan Province (No. 2016SK2020)the National Natural Science Foundation of China 21675050the National Natural Science Foundation of China 21775137Foundation of the Science & Technology Department of Hunan Province 2016SK2020Hunan Lotus Scholars Program 2011

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  • Improving the performance of electrocatalytic formic acid oxidation is the key issue to develop high-performance direct formic acid fuel cells (DFAFC). Pt-based and Pd-based materials are the important electrocatalysts for formic acid oxidation. Micro/nano-porous metal materials are widely concerned in the electrochemistry field due to the high specific electrode-surface area. The dynamic hydrogen bubble template (DHBT) method has been widely used for preparing the three-dimensional honeycomb-like porous nano-metals (3DHPNMs). However, as far as we know, the use of a sacrificial metal template to prepare the 3DHPNMs with improved performance for the electrocatalytic oxidation of small organic molecules has not been reported. Herein, a three-dimensional honeycomb-like porous nano-AuPtCu (3DHPN-AuPtCu) composite was electrodeposited on a gold-plated glassy carbon electrode (Aupla/GCE) by the DHBT method, followed by anodic stripping of Cu to yield a 3DHPN-AuPtCu/Aupla/GCE. The relevant modified electrodes were characterized by cyclic voltammetry (CV), metallographic microscopy, scanning electron microscopy (SEM), energy dispersive spectroscopy and inductively coupled plasma-atomic emission spectrometry. The SEM results clearly revealed that the use of the sacrificial Cu template can modulate the metal-honeycomb structure, and the 3DHPN-AuPtCu/Aupla/GCE can thus possess the better micro/nano-porous structure and the improved electrocatalytic performance than a Cu-template-free 3DHPN-AuPt/Aupla/GCE. In our opinion, the simultaneous electrodeposition of Cu can intervene in the electrodeposition of Au and Pt, and thus a new structure with more active sites exposed and the electrocatalysis performance improved can be obtained after the anodic stripping of electrodeposited Cu. As a result, the 3DHPN-AuPtCu/Aupla/GCE exhibited high anti-poisoning nature and high stability, because many discontinuous Pt atoms on this electrode can suppress the formation of adsorption-state COads during the electrocatalytic oxidation of formic acid. The electrocatalytic oxidation peak current density on 3DHPN-AuPtCu/Aupla/GCE in 0.5 mol/L aqueous H2SO4 containing 0.2 mol/L HCOOH was 12.5 mA·cmPt-2 (CV, -0.3~1.0 V, 50 mV/s), which is superior to the control electrodes and many reported Pt-based electrocatalysis electrodes. The suggested double- template method for preparing honeycomb-structured micro/nano-porous metal materials with improved performance has the potential for wider electrocatalysis and electroanalysis applications.
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