Efficient Synthesis of Representative Flavone-7-O-Glycosides
- Corresponding author: Cao Xin, caox@fudan.edu.cn Yu Biao, byu@sioc.ac.cn
Citation: Shao Wenbo, An Quanlin, Cao Xin, Yu Biao. Efficient Synthesis of Representative Flavone-7-O-Glycosides[J]. Acta Chimica Sinica, ;2019, 77(10): 999-1007. doi: 10.6023/A19060233
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Reagents and conditions: (a) hexanoyl chloride, DMAP, pyridine/ CHCl3 (V:V=2:1), -78~-20 ℃, 90%; (b) 4-thiocresol, imidazole, NMP, 0 ℃ to r.t., 78% (for 10); (c) Ac2O, pyridine, 0 ℃ to r.t., 71%; (d) AllBr, KI, K2CO3, DMF, r.t., 68%; (e) conc. HCl, EtOH, reflux, 96%; (f) KI, BnBr, K2CO3, acetone, reflux, 50%; (g) (Ph3P)4Pd, NaBH4, THF, r.t., 57%.