Citation: Ma Chao, Wu Jiawei, Zhu Lin, Han Xiaoxia, Ruan Weidong, Song Wei, Wang Xu, Zhao Bing. Trace Detection of Rhodamine B in Infant Candy by g-C₃N₄/Ag Nanocomposite as Surface-Enhanced Raman Scattering Substrate[J]. Acta Chimica Sinica, ;2019, 77(10): 1024-1030. doi: 10.6023/A19050191 shu

Trace Detection of Rhodamine B in Infant Candy by g-C₃N₄/Ag Nanocomposite as Surface-Enhanced Raman Scattering Substrate

State Key Laboratory of Supramolecular Structure and Materials, Institute of Theoretical Chemistry, Jilin University, Changchun 130012, China

Corresponding author: Song Wei, weisong@jlu.edu.cn Wang Xu, wxu@jlu.edu.cn
Received Date: 23 May 2019
Available Online: 13 October 2019
Fund Project: the National Natural Science Foundation of China 21773080the National Natural Science Foundation of China 21473068the Jilin Province Science and Technology Development Plan Project 20180101295JCProject supported by the National Natural Science Foundation of China (Nos. 21473068, 21711540292, 21773080) and the Jilin Province Science and Technology Development Plan Project (No. 20180101295JC)the National Natural Science Foundation of China 21711540292

Figures(7)

In recent years, food safety problems caused by illegal additions in infant foods have received widespread attention. Surface-enhanced Raman scattering (SERS) technique is used to rapidly and non-destructively detect the banned RhB that is usually added in food. In this study, we have prepared g-C₃N₄/Ag composites via a simple method successfully, their morphology and structure were characterized by transmission electron microscope (TEM), ultraviolet-visible (UV-Vis), X-ray diffraction (XRD), fluorescence spectrophotometer and confocal micro-Raman spectrometer (Raman). The g-C₃N₄ nanosheet possesses good adsorption performance due to its highly delocalized π-conjugated system, which acts as a carrier for Ag nanoparticles. Therefore, Ag nanoparticles are more uniformly and stably distributed on the surface of g-C₃N₄ nanosheets to form g-C₃N₄/Ag nanocomposite, which can be used for rapid adsorption and trace detection of RhB. In the experiment, the pH of the test and the absorbed time between the substrate and RhB were optimized. The influence of pH on the SPR of the substrate and the SERS intensity of the probe molecule were investigated in detail. As g-C₃N₄/Ag nanocomposite shows a significant higher absorption in the visible region around 500 nm than Ag nanoparticles, g-C₃N₄/Ag nanocomposite is more favorable for SPR absorption. A wide SPR absorption range is achieved due to the synergy between g-C₃N₄ and Ag nanoparticles, providing an improved SERS enhancement performance. Under the optimal experimental conditions by using RhB as probe molecule, an enhancement factor of 7.6×10⁵ is achieved. Due to the electrostatic interaction and π-π interaction between the substrate and the probe molecules, the substrate can enrich in a large amount of cationic dyes, offering a detection of RhB. The g-C₃N₄/Ag SERS substrate can be used to detect RhB with a linear relationship from 1.0×10^-9 to 1.0×10^-6 mol/L and a detection limit as low as 0.39 nmol/L. In addition, the g-C₃N₄/Ag nanocomposite SERS substrate can also detect trace amounts of RhB molecules in the commercially available rainbow lollipops with a high sensitivity, and the recovery were 93.6%~95.04%. In summary, the g-C₃N₄/Ag nanocomposite is not only a SERS substrate with high sensitivity, uniformity and stability, but also can be used as a rapid trace detection method of Rhodamine B in real food and environment.
- surface enhanced Raman spectroscopy (SERS),
- g-C₃N₄/Ag nanocomposites,
- Rhodamine B,
- candy,
- trace detection
1. [1]
  Wang, C.; Cheng, F.; Wang, Y.; Gong, Z.; Fan, M. Anal. Methods 2014, 6, 7218. doi: 10.1039/C4AY01487A
2. [2]
  Vineis, P.; Pirastu, R. Cancer Causes Control. 1997, 346, 355.
3. [3]
  Oplatowska, M.; Elliott, C. T. Analyst 2011, 136, 2403. doi: 10.1039/c0an00934b
4. [4]
  Qi, P.; Lin, Z.; Li, J.; Wang, C.; Meng, W.; Hong, H.; Zhang, X. Food Chem. 2014, 164, 98. doi: 10.1016/j.foodchem.2014.05.036
5. [5]
  Jiao, C.-L.; Wang, W.; Liu, J.; Yuan, Y.-X.; Xu, M.-M.; Yao, J.-L. Acta Chim. Sinica 2018, 76, 526.
6. [6]
  Hussain, M.; Sun, H.; Karim, S.; Nisar, A.; Khan, M.; ul Haq, A.; Iqbal, M.; Ahmad, M. J. Nanopart. Res. 2016, 18, 95. doi: 10.1007/s11051-016-3397-y
7. [7]
  Alesso, M.; Bondioli, G.; Talío, M. C.; Luconi, M. O.; Fernández, L. P. Food Chem. 2012, 134, 513. doi: 10.1016/j.foodchem.2012.02.110
8. [8]
  Zhao, H.; Hasi, W.; Bao, L.; Liu, H.; Yang, Z.; Meng, L.; Sun, Y.; Wang, J.; Yang, L.; Tian, Z. Chin. J. Chem. 2017, 35, 1522. doi: 10.1002/cjoc.201700168
9. [9]
  Kreno, L, E.; Greeneltch, N. G.; Farha, O. K.; Hupp, J. T.; Van Duyne, R. P. Analyst 2014, 139, 4073. doi: 10.1039/C4AN00413B
10. [10]
  Liu, J.; Sun, H.-L; Yin, L.; Yuan, Y.-X.; Xu, M.-M.; Yao, J.-L. Acta Chim. Sinica 2019, 77, 257. doi: 10.3866/PKU.WHXB201803191
11. [11]
  Zhang, C.-J.; Zhang, J.; Lin, J.-R.; Xu, M.-M.; Yao, J.-L. Acta Chim. Sinica 2017, 75, 860.
12. [12]
  Jiang, J.; Zhu, L.; Zou, J.; Qu, Y.-L.; Zheng, A.; Tang, H. Carbon 2015, 87, 193. doi: 10.1016/j.carbon.2015.02.025
13. [13]
  Xu, H.; Yan, J.; She, X.; Xu, L.; Xia, J.; Xu, Y.; Li, H. Nanoscale 2014, 6, 1406. doi: 10.1039/C3NR04759H
14. [14]
  Qu, L.; Wang, N.; Xu, H.; Wang, W.; Liu, Y.; Ku, L.; Li, H. Adv. Funct. Mater. 2017, 27, 1701714. doi: 10.1002/adfm.201701714
15. [15]
  Wang, Y. N.; Zhang, Y.; Zhang, W. S.; Xu, Z. R. Sens. Actuators, B 2018, 260, 400. doi: 10.1016/j.snb.2017.12.173
16. [16]
  Su, Y.-Y.; Peng, T.-H.; Xin, F.-F.; Li, D.; Fan, C.-H. Acta Chim. Sinica 2017, 75, 1036.
17. [17]
  Gao, Z.-G.; Zheng, T.-T.; Deng, J.; Li, X.-R.; Qu, Y.-Y.; Lu, Y.; Liu, T.-J. Acta Chim. Sinica 2017, 75, 355. doi: 10.7503/cjcu20160572
18. [18]
  Xu, Q.; Cheng, B.; Yu, J.; Liu, G. Carbon 2017, 118, 241. doi: 10.1016/j.carbon.2017.03.052
19. [19]
  Jin, J.; Zhu, S.; Song, Y.; Zhao, H.; Zhang, Z.; Guo, Y.; Zhao, B. ACS Appl. Mater. Interfaces 2016, 8, 27956. doi: 10.1021/acsami.6b07807
20. [20]
  Jiang, J.; Zou, J.; Wee, A. T. S.; Zhang, W. Sci. Rep. 2016, 6, 34599. doi: 10.1038/srep34599
21. [21]
  Bu, T.; Ma, X.; Zhao, B.; Song, W. Chem. Res. Chin. Univ. 2018, 34, 290. doi: 10.1007/s40242-018-7212-4
22. [22]
  Zhai, C.; Peng, Y.-K.; Li, Y.-Y.; Xu, T.-F. Acta Chim. Sinica 2015, 73, 1167. doi: 10.3969/j.issn.0253-2409.2015.10.003
23. [23]
  Fan, M.; Andrade, G. F. S.; Brolo, A. G. Anal. Chim. Acta 2011, 693, 7. doi: 10.1016/j.aca.2011.03.002
24. [24]
  Saleh, T. A.; Al-Shalalfeh, M.; Al-Saadi, A. Sens. Actuators, B 2018, 254, 1110. doi: 10.1016/j.snb.2017.07.179
25. [25]
  Nie, S.; Emory, S. R. Science 1997, 275, 1102. doi: 10.1126/science.275.5303.1102
26. [26]
  Ding, S.-Y.; Wu, D.-Y.; Yang, Z.-L.; Ren, B.; Xu, X.; Tian, Z.-Q. Chem. J. Chin. Univ. 2008, 29, 2569. doi: 10.3321/j.issn:0251-0790.2008.12.048
27. [27]
  Zhang, J.; Li, X.; Sun, X.; Li, Y. J. Phys. Chem. B 2005, 109, 12544. doi: 10.1021/jp050471d
28. [28]
  Li, K. Y.; Fang, Z. L.; Xiong, S.; Luo, J. Mater. Technol. 2017, 32, 391. doi: 10.1080/10667857.2016.1262309
29. [29]
  Wang, M.; Yan, X.; Wei, D.-Q.; Liang, L.-J.; Wang, Y.-P. Acta Chim. Sinica 2019, 77, 184.
30. [30]
  Jiang, J.; Zhu, L.; Zou, J.; Qu, Y.-L.; Zheng, A.; Tang, H. Carbon 2015, 87, 193. doi: 10.1016/j.carbon.2015.02.025
31. [31]
  Zhang, L.; Li, P.; Luo, L.; Bu, X.; Wang, X.; Zhao, B.; Tian, Y. Appl. Spectrosc. 2017, 71, 2395. doi: 10.1177/0003702817711700
32. [32]
  Zuo, F.-T.; Xu, W.; Zhao, A.-W. Acta Chim. Sinica 2019, 77, 379. doi: 10.7503/cjcu20180485
33. [33]
  Tian, H.; Zhang, N.; Tong, L.; Zhang, J. Small Methods 2017, 1, 1700126. doi: 10.1002/smtd.201700126
34. [34]
  López, Arbeloa. F.; López, Arbeloa. T.; Tapia, Estévez. M. J.; López, Arbeloa, I. J. Phys. Chem. 1991, 95, 2203. doi: 10.1021/j100159a022
35. [35]
  Lu, Q.-N.; Dorn, J.-M.; Berry, M.-T.; Jiang, C., Lin, C.; May, P.-S. J. Colloid Interface Sci. 2011, 356, 151. doi: 10.1016/j.jcis.2010.12.077
36. [36]
  Wang, H.-B. Sci. Technol. Food Ind. 2019, 11, 1002.
37. [37]
  Lee, P. C.; Mei, S.-D. J. Phys. Chem. 1982, 86, 3391. doi: 10.1021/j100214a025
1. [1]
  Zhuomin Zhang , Hanbing Huang , Liangqiu Lin , Jingsong Liu , Gongke Li . Course Construction of Instrumental Analysis Experiment: Surface-Enhanced Raman Spectroscopy for Rapid Detection of Edible Pigments. University Chemistry, 2024, 39(2): 133-139. doi: 10.3866/PKU.DXHX202308034
2. [2]
  Liang MA , Honghua ZHANG , Weilu ZHENG , Aoqi YOU , Zhiyong OUYANG , Junjiang CAO . Construction of highly ordered ZIF-8/Au nanocomposite structure arrays and application of surface-enhanced Raman spectroscopy. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1743-1754. doi: 10.11862/CJIC.20240075
3. [3]
  Min WANG , Dehua XIN , Yaning SHI , Wenyao ZHU , Yuanqun ZHANG , Wei ZHANG . Construction and full-spectrum catalytic performance of multilevel Ag/Bi/nitrogen vacancy g-C₃N₄/Ti₃C₂T_x Schottky junction. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1123-1134. doi: 10.11862/CJIC.20230477
4. [4]
  Guangming YIN , Huaiyao WANG , Jianhua ZHENG , Xinyue DONG , Jian LI , Yi'nan SUN , Yiming GAO , Bingbing WANG . Preparation and photocatalytic degradation performance of Ag/protonated g-C₃N₄ nanorod materials. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1491-1500. doi: 10.11862/CJIC.20240086
5. [5]
  Heng Chen , Longhui Nie , Kai Xu , Yiqiong Yang , Caihong Fang . 两步焙烧法制备大比表面积和结晶性增强超薄g-C₃N₄纳米片及其高效光催化产H₂O₂. Acta Physico-Chimica Sinica, 2024, 40(11): 2406019-. doi: 10.3866/PKU.WHXB202406019
6. [6]
  Jingyi Chen , Fu Liu , Tiejun Zhu , Kui Cheng . Practice of Integrating Ideological and Political Education into Raman Spectroscopy Analysis Experiment Course. University Chemistry, 2024, 39(2): 140-146. doi: 10.3866/PKU.DXHX202310111
7. [7]
  Wei Peng , Baoying Wen , Huamin Li , Yiru Wang , Jianfeng Li . Exploration and Practice on Raman Scattering Spectroscopy Experimental Teaching. University Chemistry, 2024, 39(8): 230-240. doi: 10.3866/PKU.DXHX202312062
8. [8]
  Zhaoyue Lü , Zhehao Chen , Yi Ni , Duanbin Luo , Xianfeng Hong . Multi-Level Teaching Design and Practice Exploration of Raman Spectroscopy Experiment. University Chemistry, 2024, 39(11): 304-312. doi: 10.12461/PKU.DXHX202402047
9. [9]
  Guoqiang Chen , Zixuan Zheng , Wei Zhong , Guohong Wang , Xinhe Wu . 熔融中间体运输导向合成富氨基g-C₃N₄纳米片用于高效光催化产H₂O₂. Acta Physico-Chimica Sinica, 2024, 40(11): 2406021-. doi: 10.3866/PKU.WHXB202406021
10. [10]
  Kai Han , Guohui Dong , Ishaaq Saeed , Tingting Dong , Chenyang Xiao . Morphology and photocatalytic tetracycline degradation of g-C3N4 optimized by the coal gangue. Chinese Journal of Structural Chemistry, 2024, 43(2): 100208-100208. doi: 10.1016/j.cjsc.2023.100208
11. [11]
  Liang Ma , Zhou Li , Zhiqiang Jiang , Xiaofeng Wu , Shixin Chang , Sónia A. C. Carabineiro , Kangle Lv . Effect of precursors on the structure and photocatalytic performance of g-C3N4 for NO oxidation and CO2 reduction. Chinese Journal of Structural Chemistry, 2024, 43(11): 100416-100416. doi: 10.1016/j.cjsc.2023.100416
12. [12]
  Xuejiao Wang , Suiying Dong , Kezhen Qi , Vadim Popkov , Xianglin Xiang . Photocatalytic CO₂ Reduction by Modified g-C₃N₄. Acta Physico-Chimica Sinica, 2024, 40(12): 2408005-. doi: 10.3866/PKU.WHXB202408005
13. [13]
  Xin Zhou , Zhi Zhang , Yun Yang , Shuijin Yang . A Study on the Enhancement of Photocatalytic Performance in C/Bi/Bi₂MoO₆ Composites by Ferroelectric Polarization: A Recommended Comprehensive Chemical Experiment. University Chemistry, 2024, 39(4): 296-304. doi: 10.3866/PKU.DXHX202310008
14. [14]
  Junjie Zhang , Yue Wang , Qiuhan Wu , Ruquan Shen , Han Liu , Xinhua Duan . Preparation and Selective Separation of Lightweight Magnetic Molecularly Imprinted Polymers for Trace Tetracycline Detection in Milk. University Chemistry, 2024, 39(5): 251-257. doi: 10.3866/PKU.DXHX202311084
15. [15]
  Zhi Zhu , Xiaohan Xing , Qi Qi , Wenjing Shen , Hongyue Wu , Dongyi Li , Binrong Li , Jialin Liang , Xu Tang , Jun Zhao , Hongping Li , Pengwei Huo . Fabrication of graphene modified CeO2/g-C3N4 heterostructures for photocatalytic degradation of organic pollutants. Chinese Journal of Structural Chemistry, 2023, 42(12): 100194-100194. doi: 10.1016/j.cjsc.2023.100194
16. [16]
  Jianyu Qin , Yuejiao An , Yanfeng Zhang . In Situ Assembled ZnWO₄/g-C₃N₄ S-Scheme Heterojunction with Nitrogen Defect for CO₂ Photoreduction. Acta Physico-Chimica Sinica, 2024, 40(12): 2408002-. doi: 10.3866/PKU.WHXB202408002
17. [17]
  Xin Jiang , Han Jiang , Yimin Tang , Huizhu Zhang , Libin Yang , Xiuwen Wang , Bing Zhao . g-C₃N₄/TiO_2-X heterojunction with high-efficiency carrier separation and multiple charge transfer paths for ultrasensitive SERS sensing. Chinese Chemical Letters, 2024, 35(10): 109415-. doi: 10.1016/j.cclet.2023.109415
18. [18]
  Wei Zhong , Dan Zheng , Yuanxin Ou , Aiyun Meng , Yaorong Su . K原子掺杂高度面间结晶的g-C₃N₄光催化剂及其高效H₂O₂光合成. Acta Physico-Chimica Sinica, 2024, 40(11): 2406005-. doi: 10.3866/PKU.WHXB202406005
19. [19]
  Kexin Dong , Chuqi Shen , Ruyu Yan , Yanping Liu , Chunqiang Zhuang , Shijie Li . Integration of Plasmonic Effect and S-Scheme Heterojunction into Ag/Ag₃PO₄/C₃N₅ Photocatalyst for Boosted Photocatalytic Levofloxacin Degradation. Acta Physico-Chimica Sinica, 2024, 40(10): 2310013-. doi: 10.3866/PKU.WHXB202310013
20. [20]
  Min LI , Xianfeng MENG . Preparation and microwave absorption properties of ZIF-67 derived Co@C/MoS₂ nanocomposites. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1932-1942. doi: 10.11862/CJIC.20240065

Get Citation

PDF

XML

Metrics

PDF Downloads(17)
Abstract views(1261)
HTML views(85)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Trace Detection of Rhodamine B in Infant Candy by g-C3N4/Ag Nanocomposite as Surface-Enhanced Raman Scattering Substrate

Metrics

通讯作者: 陈斌, bchen63@163.com

Trace Detection of Rhodamine B in Infant Candy by g-C₃N₄/Ag Nanocomposite as Surface-Enhanced Raman Scattering Substrate