Sulfonyl Chlorides Mediated Alkynylation of Non-activated Alkenes via Distal Alkynyl Group Migration
- Corresponding author: Zhu Chen, chzhu@suda.edu.cn
Citation: Tang Nana, Shao Xin, Wang Mingyang, Wu Xinxin, Zhu Chen. Sulfonyl Chlorides Mediated Alkynylation of Non-activated Alkenes via Distal Alkynyl Group Migration[J]. Acta Chimica Sinica, ;2019, 77(9): 922-926. doi: 10.6023/A19050158
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doi: 10.1002/anie.201700413
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Reaction Conditions: propargyl alcohol 1 (0.2 mmol), Na2CO3 (0.2 mmol, 1.0 equiv.), fac-Ir(ppy)3 (0.006 mmol, 3 mol%), and sulfonyl chloride (0.3 mmol, 1.5 equiv.), irradiated with 15 W blue LEDs at room temperature under N2 atmosphere. Yields of isolated products are given.
Reaction Conditions: propargyl alcohol 1 (0.2 mmol), K2HPO4 (0.16 mmol, 0.8 equiv.), fac-Ir(ppy)3 (0.008 mmol, 4 mol%), and CF3SO2Cl (0.44 mmol, 2.2 equiv. in two portions), irradiated with 15 W blue LEDs at r.t. under N2 atmosphere. Yields of isolated products.