Citation: Qu Luping, Ren Tong, Wang Ning, Shi Yueli, Zhuang Quanchao. Electrochemical Impedance Spectroscopy Study on the First Sodium Insertion Process of Hard Carbon Material Electrode[J]. Acta Chimica Sinica, ;2019, 77(7): 634-640. doi: 10.6023/A19030103 shu

Electrochemical Impedance Spectroscopy Study on the First Sodium Insertion Process of Hard Carbon Material Electrode

Lithium Ion Battery Laboratory, Engineering Laboratory of High Efficiency Energy Storage Technology & Equipments, Jiangsu Provincial, School of Materials Science & Engineering, China University of Mining & Technology, Xuzhou 221116

Corresponding author: Zhuang Quanchao, zhuangquanchao@126.com
Received Date: 29 March 2019
Available Online: 12 July 2019

Figures(8)

In this study, electrochemical impedance spectroscopy (EIS) combined with cyclic volt-ampere (CV), charge-discharge measurement and scanning electron microscope were used. The electrode interface characteristics of hard carbon electrodes for sodium ion batteries in 1 mol/L NaClO₄-EC:DEC and 1 mol/L-NaClO₄-EC:DEC:PC electrolyte systems were discussed. The hard carbon material electrode is composed of 80 wt% active material, 10 wt% PVDF-HFP adhesive and 10 wt% conductive carbon black. The charge and discharge performance was tested with 2032 button battery and metal sodium sheet as counter electrode, the charge and discharge rate was 0.1 C, and the cut-off voltage was 0~3 V. The three-electrode glass cell system was used for CV and EIS test, and the metal sodium sheet was used as the reference and auxiliary electrode. In the CV test, the scanning speed is 1 mV/s, EIS and the frequency scanning range is 10⁵ to 10^-2 Hz. The amplitude of AC signal applied by 2 mV is 5 mV. The electrochemical impedance spectra obtained in the experiment were simulated by Zview software. The results of CV show that the intercalation process of sodium ion in hard carbon materials is mainly divided into two steps, that is, the filling process of sodium ion in nano-pores, the intercalation of sodium ion in graphene layer and the adsorption and desorption of sodium ion on the surface or defect. The filling process of sodium ion in the nanoporous is accompanied by the formation of solid electrolyte interface (SEI) film on the surface of the electrode. The results of electrochemical impedance spectroscopy show that the spectrum consists of two semicircles and a oblique line, which can be attributed to the contact impedance, the diffusion of sodium ions through SEI film and the process of charge transfer. The oblique domain reflects the oblique line related to the solid diffusion of sodium ion in the particles of hard carbon materials. By selecting the appropriate equivalent circuit and fitting the experimental results, we can get the variation of SEI film resistance and electron resistance with the electrode polarization potential in the process of sodium insertion in the first week of the hard carbon electrode.
- hard carbon,
- electrolyte system,
- sodium ion battery,
- electrochemical property
1. [1]
  Tarascon, J. M. Nat. Chem. 2010, 2, 510. doi: 10.1038/nchem.680
2. [2]
  Xiang, X. D.; Lu, Y. Y.; Chen, J. Acta Chim. Sinica 2017, 75, 154.
3. [3]
  Vikström, H.; Davidsson, S.; Höök, M. Appl. Energy 2013, 110, 252. doi: 10.1016/j.apenergy.2013.04.005
4. [4]
  Kundu, D.; Talaie, E.; Duffort, V.; Nazar, L. F. Angew. Chem., Int. Ed. 2015, 54, 3431. doi: 10.1002/anie.201410376
5. [5]
  Li, H.; Wang, Z.; Chen, L.; Huang, X. Adv. Mater. 2009, 21, 4593. doi: 10.1002/adma.v21:45
6. [6]
  Komaba, S.; Murata, W.; Ishikawa, T.; Yabuuchi, N.; Ozeki, T.; Nakayama, T.; Ogata, A.; Gotoh, K.; Fujiwara, K. Adv. Funct. Mater. 2011, 21, 3859. doi: 10.1002/adfm.v21.20
7. [7]
  Zhang, S. W.; Zhang, J.; Wu, S. D.; Lv, W.; Kang, F. Y.; Yang, Q. H. Acta Chim. Sinica 2017, 75, 163. doi: 10.11862/CJIC.2017.023
8. [8]
  Wang, L.; Yang, G. R.; Wang, J. N.; Wang, S. L.; Peng, S. J.; Yan, W. Acta Chim. Sinica 2018, 76, 666. doi: 10.3969/j.issn.0253-2409.2018.06.004
9. [9]
  Narayanrao, R.; Joglekar, M.; Inguva, S. J. Electrochem. Soc. 2013, 160, A125. doi: 10.1149/2.013302jes
10. [10]
  Lin, X.; Park, J.; Liu, L.; Lee, Y.; Sastry, A.; Lu, W. J. Electrochem. Soc. 2013, 160, A1701. doi: 10.1149/2.040310jes
11. [11]
  Pinson, M. B.; Bazant, M. Z. J. Electrochem. Soc. 2013, 160, A243. doi: 10.1149/2.044302jes
12. [12]
  Xu, K. Chem. Rev. 2014, 114, 11503. doi: 10.1021/cr500003w
13. [13]
  Zhuang, Q. C.; Xu, S. D.; Qiu, X. Y.; Cui, Y. L.; Fang, L.; Sun, S. G. Prog. Chem. 2010, 22, 1044.
14. [14]
  Qin, Y. P.; Zhuang, Q. C.; Shi, Y. L.; Jiang, L.; Sun, Z.; Sun, S. G. Prog. Chem. 2011, 23, 390.
15. [15]
  Qiu, X. Y.; Zhuang, Q. C.; Zhang, Q. Q.; Cao, R.; Ying, P. Z.; Qiang, Y. H.; Sun, S. G. Phys. Chem. Chem. Phys. 2012, 14, 2617. doi: 10.1039/c2cp23626e
16. [16]
  Zhuang, Q. C.; Wei, T.; Du, L. L.; Cui, Y. L.; Fang, L.; Sun, S. G. J. Phys. Chem. C 2010, 114, 8614. doi: 10.1021/jp9109157
17. [17]
  Qiu, X. Y.; Zhuang, Q. C.; Zhang, Q. Q.; Cao, R.; Qiang, Y. H.; Ying, P. Z.; Sun, S. G. J. Electroanal. Chem. 2012, 687, 35. doi: 10.1016/j.jelechem.2012.09.027
18. [18]
  Wei, T.; Zhuang, Q. C.; Wu, C.; Cui, Y. L.; Fang, L.; Sun, S. G. Acta Chim. Sinica 2010, 68, 1481. doi: 10.3866/PKU.WHXB20100621
19. [19]
  Zhuang, Q. C.; Wei, T.; Wei, G. Z.; Dong, Q. F.; Sun, S. G. Acta Chim. Sinica 2009, 67, 2184.
20. [20]
  Zheng, M.; Liu, Y.; Xiao, Y.; Zhu, Y.; Guan, Q.; Yuan, D.; Zhang, J. J. Phys. Chem. C 2009, 113, 8455. doi: 10.1021/jp811356a
21. [21]
  Cao, Y.; Xiao, L.; Sushko, M. L.; Wang, W.; Schwenzer, B.; Xiao, J.; Nie, Z.; Saraf, L. V.; Yang, Z.; Liu, J. Nano Lett. 2012, 12, 3783. doi: 10.1021/nl3016957
22. [22]
  Li, Y.; Hu, Y. S.; Titirici, M. M.; Chen, L.; Huang, X. Adv. Energy Mater. 2016, 6, 1600659. doi: 10.1002/aenm.201600659
23. [23]
  Liu, P.; Li, Y.; Hu, Y. S.; Li, H.; Chen, L.; Huang, X. J. Mater. Chem. A 2016, 4, 13046. doi: 10.1039/C6TA04877C
24. [24]
  Holzapfel, M.; Martinent, A.; Alloin, F.; Le Gorrec, B.; Yazami, R.; Montella, C. J. Electroanal. Chem. 2003, 546, 41. doi: 10.1016/S0022-0728(03)00144-X
25. [25]
  Chang, Y. C.; Sohn, H. J. J. Electrochem. Soc. 2000, 147, 50. doi: 10.1149/1.1393156
26. [26]
  Levi, M.; Aurbach, D. J. Phys. Chem. B 1997, 101, 4630. doi: 10.1021/jp9701909
27. [27]
  Xu, S. D.; Zhuang, Q. C.; Tian, L. L.; Qin, Y. P.; Fang, L.; Sun, S. G. J. Phys. Chem. C 2011, 115, 9210. doi: 10.1021/jp107406s
28. [28]
  Zhuang, Q. C.; Li, J.; Tian, L. L. J. Power Sources 2013, 222, 177. doi: 10.1016/j.jpowsour.2012.08.050
1. [1]
  Jianbao Mei , Bei Li , Shu Zhang , Dongdong Xiao , Pu Hu , Geng Zhang . Enhanced Performance of Ternary NASICON-Type Na_3.5-xMn_0.5V_1.5-xZr_x(PO₄)₃/C Cathodes for Sodium-Ion Batteries. Acta Physico-Chimica Sinica, 2024, 40(12): 2407023-. doi: 10.3866/PKU.WHXB202407023
2. [2]
  Kun Xu , Xinxin Song , Zhilei Yin , Jian Yang , Qisheng Song . Comprehensive Experimental Design of Preferential Orientation of Zinc Metal by Heat Treatment for Enhanced Electrochemical Performance. University Chemistry, 2024, 39(4): 192-197. doi: 10.3866/PKU.DXHX202309050
3. [3]
  Xinpeng LIU , Liuyang ZHAO , Hongyi LI , Yatu CHEN , Aimin WU , Aikui LI , Hao HUANG . Ga₂O₃ coated modification and electrochemical performance of Li_1.2Mn_0.54Ni_0.13Co_0.13O₂ cathode material. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1105-1113. doi: 10.11862/CJIC.20230488
4. [4]
  Qi Li , Pingan Li , Zetong Liu , Jiahui Zhang , Hao Zhang , Weilai Yu , Xianluo Hu . Fabricating Micro/Nanostructured Separators and Electrode Materials by Coaxial Electrospinning for Lithium-Ion Batteries: From Fundamentals to Applications. Acta Physico-Chimica Sinica, 2024, 40(10): 2311030-. doi: 10.3866/PKU.WHXB202311030
5. [5]
  Jiahong ZHENG , Jiajun SHEN , Xin BAI . Preparation and electrochemical properties of nickel foam loaded NiMoO₄/NiMoS₄ composites. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 581-590. doi: 10.11862/CJIC.20230253
6. [6]
  Qingtang ZHANG , Xiaoyu WU , Zheng WANG , Xiaomei WANG . Performance of nano Li₂FeSiO₄/C cathode material co-doped by potassium and chlorine ions. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1689-1696. doi: 10.11862/CJIC.20240115
7. [7]
  Feiya Cao , Qixin Wang , Pu Li , Zhirong Xing , Ziyu Song , Heng Zhang , Zhibin Zhou , Wenfang Feng . Magnesium-Ion Conducting Electrolyte Based on Grignard Reaction: Synthesis and Properties. University Chemistry, 2024, 39(3): 359-368. doi: 10.3866/PKU.DXHX202308094
8. [8]
  Zhihuan XU , Qing KANG , Yuzhen LONG , Qian YUAN , Cidong LIU , Xin LI , Genghuai TANG , Yuqing LIAO . Effect of graphene oxide concentration on the electrochemical properties of reduced graphene oxide/ZnS. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1329-1336. doi: 10.11862/CJIC.20230447
9. [9]
  Qin ZHU , Jiao MA , Zhihui QIAN , Yuxu LUO , Yujiao GUO , Mingwu XIANG , Xiaofang LIU , Ping NING , Junming GUO . Morphological evolution and electrochemical properties of cathode material LiAl_0.08Mn_1.92O₄ single crystal particles. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1549-1562. doi: 10.11862/CJIC.20240022
10. [10]
  Yong Zhou , Jia Guo , Yun Xiong , Luying He , Hui Li . Comprehensive Teaching Experiment on Electrochemical Corrosion in Galvanic Cell for Chemical Safety and Environmental Protection Course. University Chemistry, 2024, 39(7): 330-336. doi: 10.3866/PKU.DXHX202310109
11. [11]
  Kai CHEN , Fengshun WU , Shun XIAO , Jinbao ZHANG , Lihua ZHU . PtRu/nitrogen-doped carbon for electrocatalytic methanol oxidation and hydrogen evolution by water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1357-1367. doi: 10.11862/CJIC.20230350
12. [12]
  Yuanchao LI , Weifeng HUANG , Pengchao LIANG , Zifang ZHAO , Baoyan XING , Dongliang YAN , Li YANG , Songlin WANG . Effect of heterogeneous dual carbon sources on electrochemical properties of LiMn_0.8Fe_0.2PO₄/C composites. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 751-760. doi: 10.11862/CJIC.20230252
13. [13]
  Jiahong ZHENG , Jingyun YANG . Preparation and electrochemical properties of hollow dodecahedral CoNi₂S₄ supported by MnO₂ nanowires. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1881-1891. doi: 10.11862/CJIC.20240170
14. [14]
  Doudou Qin , Junyang Ding , Chu Liang , Qian Liu , Ligang Feng , Yang Luo , Guangzhi Hu , Jun Luo , Xijun Liu . Addressing Challenges and Enhancing Performance of Manganese-based Cathode Materials in Aqueous Zinc-Ion Batteries. Acta Physico-Chimica Sinica, 2024, 40(10): 2310034-. doi: 10.3866/PKU.WHXB202310034
15. [15]
  Fengqiao Bi , Jun Wang , Dongmei Yang . Specialized Experimental Design for Chemistry Majors in the Context of “Dual Carbon”: Taking the Assembly and Performance Evaluation of Zinc-Air Fuel Batteries as an Example. University Chemistry, 2024, 39(4): 198-205. doi: 10.3866/PKU.DXHX202311069
16. [16]
  Yixuan Gao , Lingxing Zan , Wenlin Zhang , Qingbo Wei . Comprehensive Innovation Experiment: Preparation and Characterization of Carbon-based Perovskite Solar Cells. University Chemistry, 2024, 39(4): 178-183. doi: 10.3866/PKU.DXHX202311091
17. [17]
  Hongyi LI , Aimin WU , Liuyang ZHAO , Xinpeng LIU , Fengqin CHEN , Aikui LI , Hao HUANG . Effect of Y(PO₃)₃ double-coating modification on the electrochemical properties of Li[Ni_0.8Co_0.15Al_0.05]O₂. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1320-1328. doi: 10.11862/CJIC.20230480
18. [18]
  Lei Shu , Zhengqing Hao , Kai Yan , Hong Wang , Lihua Zhu , Fang Chen , Nan Wang . Development of a Double-Carbon Related Experiment: Preparation, Characterization and Carbon-Capture Ability of Eggshell-Derived CaO. University Chemistry, 2024, 39(4): 149-156. doi: 10.3866/PKU.DXHX202310134
19. [19]
  Wenjun Zheng . Application in Inorganic Synthesis of Ionic Liquids. University Chemistry, 2024, 39(8): 163-168. doi: 10.3866/PKU.DXHX202401020
20. [20]
  Tao Jiang , Yuting Wang , Lüjin Gao , Yi Zou , Bowen Zhu , Li Chen , Xianzeng Li . Experimental Design for the Preparation of Composite Solid Electrolytes for Application in All-Solid-State Batteries: Exploration of Comprehensive Chemistry Laboratory Teaching. University Chemistry, 2024, 39(2): 371-378. doi: 10.3866/PKU.DXHX202308057

Get Citation

PDF

XML

Metrics

PDF Downloads(59)
Abstract views(2265)
HTML views(557)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142