Citation: Wang Shan, Fan Xiaoyong, Cui Yu, Gou Lei, Wang Xingang, Li Donglin. Three-dimensional Porous Current Collector for Lithium Storage Enhancement of NiO Electrode[J]. Acta Chimica Sinica, ;2019, 77(6): 551-558. doi: 10.6023/A19020057 shu

Three-dimensional Porous Current Collector for Lithium Storage Enhancement of NiO Electrode

School of Materials Science and Engineering, Chang'an University, Xi'an 710061, China

Corresponding author: Fan Xiaoyong, xyfan@chd.edu.cn Li Donglin, dlli@chd.edu.cn
Received Date: 3 February 2019
Available Online: 20 June 2019
Fund Project: the National Natural Science Foundation of China 21473014the Special Fund for Basic Scientific Research of Central Colleges, Chang'an University, China 310831153505the China Postdoctoral Science Foundation 2016M590908Project supported by the National Natural Science Foundation of China (No. 21473014), the China Postdoctoral Science Foundation (No. 2016M590908) and the Special Fund for Basic Scientific Research of Central Colleges, Chang'an University, China (Grant No. 310831153505)

Figures(12)

Three-dimensional (3D) porous metals have been applied as current collector to improve the cycle stability and high-rate capacities of lithium-ion battery due to they can accommodate volumetric changes of electrodes during lithium storage, and provide rapid transfer channels for lithium ions. NiO has attracted more and more attention due to its high theoretical specific capacity as anode of lithium-ion battery. However its low electrical conductivity and large volumetric changes during electrochemical cycling result in poor cyclability and low high-rate capacity. Besides, the large first irreversible capacity causing from the low reaction activity between the first lithiation products Ni⁰ and Li₂O, hinders its commercial application. In this work, we produce 3D porous Cu with interconnected pores (ca. 5 μm) by a facile and scalable electroless plating method and investigate its role on electrochemical storage improvement for NiO electrode. NiO@3D porous Cu is produced by electrodepositing Ni(OH)₂ film coupled with sequential high temperature with 3D porous Cu as the substrate. The NiO film deposited on the 3D porous Cu has mesoporous structure. This unique architecture can provide rapid transfer channels for lithium-ion battery and free place for accommodating volumetric changes of NiO during electrochemical cycling, meanwhile increases reactive points for Ni⁰ and Li₂O. Thus, this electrode demonstrates excellent high-rate capacity and high first columbic efficiency. The first discharge and charge capacities at 200 mA·g^-1 are 1522.3 and 1230.2 mAh·g^-1 respectively with high columbic efficiency of 80.8%. The same electrode shows high capacity of 578 mAh·g^-1 at high current density of 20 A·g^-1, which is 48.8% of that at 0.2 A·g^-1. The electrochemical impedance spectra (EIS) demonstrate the NiO@3D porous Cu electrode has smaller charge transfer resistance and large Li-ion diffusion efficiency compared with NiO@Cu foil. The SEM images show that the NiO@3D porous Cu electrode suffered 100 cycles remains well 3D porous structure. A full cell is assembled using NiO@3D porous Cu as negative electrode and LiNi_1/3Co_1/3Mn_1/3O₂ as positive electrode. The full cell delivers first charge and discharge capacities of 1514 and 1060 mAh·g^-1 respectively at 0.2 A·g^-1 (based on NiO) with a coulomb efficiency of 70%, a first discharge capacity of 873 mAh·g^-1 at 1.0 A·g^-1 with 709 mAh·g^-1 remained after 100 cycles (the retention is 81%). This work may offer an effective method for lithium storage enhancement of transition metal oxides.
- lithium-ion battery,
- anode,
- NiO,
- three-dimensional porous,
- current density
1. [1]
  Guo, Y.-G.; Hu, J.-S.; Wan, L.-J. Adv. Mater. 2008, 20, 2878. doi: 10.1002/adma.v20:15
2. [2]
  Xia, L.; Yu, L.-P.; Hu, D.; Chen, Z. Acta Chim. Sinica 2017, 75, 173. doi: 10.7503/cjcu20160462
3. [3]
  Liang, C.; Gao, M.-X; Pan, H.; Liu, Y.; Yan, M. J. Alloys Compd. 2013, 575, 246. doi: 10.1016/j.jallcom.2013.04.001
4. [4]
  Yu, P.; Liu, X.; Wang, L.; Tian, C.-G.; Yu, H.-T.; Fu, H. ACS Sustainable Chem. Eng. 2017, 5, 11238. doi: 10.1021/acssuschemeng.7b01640
5. [5]
  Chang, S.-L.; Liang, F.; Yao, Y.-C.; Ma, W.-H.; Yang, B.; Dai, Y.-N. Acta Chim. Sinica 2018, 76, 515. doi: 10.11862/CJIC.2018.038
6. [6]
  Zhao, T. P.; Gao, D. S.; Lei, G. T.; Li, Z. H. Acta Chim. Sinica 2009, 67, 1957. doi: 10.3321/j.issn:0567-7351.2009.17.003
7. [7]
  Wang, X.; Qiao, L.; Sun, X.; Li, X.; Hu, D.; Zhang, Q.; He, D.-Y. J. Mater. Chem. A 2013, 1, 4173. doi: 10.1039/c3ta01640d
8. [8]
  Wen, W.; Wu, J.-M.; Cao, M.-H. Nano Energy 2013, 2, 1383. doi: 10.1016/j.nanoen.2013.07.002
9. [9]
  Wen, W.; Wu, J.-M.; Cao, M.-H. J. Mater. Chem. A 2013, 1, 3881. doi: 10.1039/c3ta01626a
10. [10]
  Kang, C.; Cha, E.; Lee, S. H.; Choi, W. RSC Adv. 2018, 8, 7414. doi: 10.1039/C7RA10987C
11. [11]
  Oh, S. H.; Park, J.-S.; Jo, M. S.; Kang, Y. C.; Cho, J. S. Chem. Eng. J. 2018, 347, 889. doi: 10.1016/j.cej.2018.04.156
12. [12]
  Zhang, Y.-H.; Wang, Z.-Y.; Shi, C.-S.; Liu, E.-Z.; He, C.-N.; Zhao, N.-J. Acta Phys.-Chim. Sin. 2015, 31, 268. doi: 10.3866/PKU.WHXB201411261
13. [13]
  Sun, X.; Yan, C.-L; Chen, Y.; Si, W.; Deng, J.; Oswald, S.; Liu, L.; Schmidt, O. G. Adv. Eng. Mater. 2014, 4, 1300912. doi: 10.1002/aenm.201300912
14. [14]
  Lv, P.; Zhao, H.-L; Zeng, Z.; Gao, C.; Liu, X.; Zhang, T. Appl. Surf. Sci. 2015, 329, 301. doi: 10.1016/j.apsusc.2014.12.170
15. [15]
  Ma, J.; Yin, L.-W.; Ge, T. CrystEngComm 2015, 17, 9336. doi: 10.1039/C5CE00818B
16. [16]
  Yu, P.; Wang, L.; Sun, F.; Zhao, D.; Tian, C.; Zhao, L.; Liu, X.; Wang, J.-Q.; Fu, H.-G. Chem. Eur. J. 2015, 21, 3249. doi: 10.1002/chem.201406188
17. [17]
  Vlad, A.; Antohe, V.-A.; Martinez-Huerta, J. M.; Ferain, E.; Gohy, J.-F.; Piraux, L. J. Mater. Chem A 2016, 4, 1603. doi: 10.1039/C5TA10639G
18. [18]
  Park, G.-D.; Hong, J.-H.; Park, S. K.; Kang, Y. C. Appl. Surf. Sci. 2019, 464, 597. doi: 10.1016/j.apsusc.2018.09.122
19. [19]
  Fan, Z.; Liang, J.; Yu, W.; Ding, S.-J.; Cheng, S.; Yang, G.; Wang, Y.; Xi, Y.; Xi, K.; Kumar, R. V. Nano Energy 2015, 16, 152. doi: 10.1016/j.nanoen.2015.06.009
20. [20]
  Liang, J.; Hu, H.; Park, H.; Xiao, C.; Ding, S.-J.; Paik, U.; Lou, X. W. Eng. Environ. Sci. 2015, 8, 1707.
21. [21]
  Park, S. K.; Choi, J. H.; Kang, Y. C. Chem. Eng. J. 2018, 354, 327. doi: 10.1016/j.cej.2018.08.018
22. [22]
  Zou, F.; Chen, Y. M.; Liu, K.; Yu, Z.; Liang, W.; Bhaway, S. M.; Gao, M.; Zhu, Y. ACS Nano 2016, 10, 377. doi: 10.1021/acsnano.5b05041
23. [23]
  Hien, V.-X.; Vuong, D. D.; Chien, N. D.; Heo, Y.-W. Mater. Chem. Phys. 2018, 217, 74. doi: 10.1016/j.matchemphys.2018.06.054
24. [24]
  Jiang, J.; Ma, C.; Yang, Y.; Ding, J.; Ji, H.; Shi, S.; Yang, G. Appl. Surf. Sci. 2018, 441, 232. doi: 10.1016/j.apsusc.2018.02.053
25. [25]
  Long, H.; Shi, T.; Hu, H.; Jiang, S.; Xi, S.; Tang, Z.-R. Sci. Rep. 2014, 4, 7413.
26. [26]
  Meng, X.; Deng, D. Chem. Eng. Sci. 2019, 194, 134. doi: 10.1016/j.ces.2018.06.038
27. [27]
  Xia, Y.; Sun, B.; Zhu, S.; Mao, S.; Li, X.; Guo, B.; Zeng, Y.; Wang, H.; Zhao, Y. J. Solid State Chem. 2019, 269, 132. doi: 10.1016/j.jssc.2018.09.024
28. [28]
  Hu, N.; Tang, Z.; Shen, P. K. RSC. Adv. 2018, 8, 26589. doi: 10.1039/C8RA03599G
29. [29]
  Fan, X.-Y.; Han, J.-X; Jiang, Y.; Ni, J.; Gou, L.; Li, D.-L.; Li, L. ACS Appl. Energy Mater. 2018, 1, 3598. doi: 10.1021/acsaem.8b00872
30. [30]
  Fan, X.-Y; Shi, Y.; Gou, L.; Li, D. Electrochim. Acta 2014, 142, 268. doi: 10.1016/j.electacta.2014.08.003
31. [31]
  Sun, C.; Yang, J.; Rui, X.; Zhang, W.; Yan, Q.; Chen, P.; Huo, F.; Huang, W.; Dong, X. C. J. Mater. Chem. A 2015, 3, 8483. doi: 10.1039/C5TA00455A
32. [32]
  Feng, Y.; Zhang, H.; Li, W.; Fang, L.; Wang, Y. J. Power Sources 2016, 301, 78. doi: 10.1016/j.jpowsour.2015.09.101
33. [33]
  Yang, W.; Cheng, G.; Dong, C.; Bai, Q.; Chen, X.; Peng, Z.; Zhang, Z.-H. J. Mater. Chem. A 2014, 2, 20022. doi: 10.1039/C4TA04809A
34. [34]
  Ni, S.; Lv, X.; Ma, J.; Yang, X.-L.; Zhang, L. J. Power Sources 2014, 270, 564. doi: 10.1016/j.jpowsour.2014.07.137
35. [35]
  Hu, Y.; Wei, J.; Liang, Y.; Zhang, H.; Zhang, X.; Shen, W.; Wang, H.-T. Angew. Chem. Int. Ed. 2016, 55, 2048. doi: 10.1002/anie.201509213
36. [36]
  Wu, J.; Yin, W. J.; Liu, W.-W.; Guo, P.; Liu, G.; Liu, X.; Geng, D.; Lau, W.-M.; Liu, H.; Liu, L. M. J. Mater. Chem. A 2016, 4, 10940. doi: 10.1039/C6TA03137D
37. [37]
  Kvasha, A.; Azaceta, E.; Leonet, O.; Bengoechea, M.; Boyano, I.; Tena-Zaera, R.; Meatza, I. d.; Miguel, O.; Grande, H.-J.; Blazquez, J. A. Electrochim. Acta 2015, 180, 16. doi: 10.1016/j.electacta.2015.08.030
38. [38]
  Yan, X.-Y.; Tong, X.; Wang, J.; Gong, C.; Zhang, M.; Liang, L. J. Alloys Compd. 2013, 556, 561.
39. [39]
  Fan, X.-Y.; Zhuang, Q.-C.; Wei, G.-Z.; Ke, F.-S.; Huang, L.; Dong, Q.-F.; Sun, S.-G. Acta Chim. Sinica 2009, 67, 1547. doi: 10.3321/j.issn:0567-7351.2009.14.003
40. [40]
  Fan, X.-Y.; Shi, Y.-X.; Cui, Y.; Li, D.-L.; Gou, L. Ionics 2015, 21, 1909. doi: 10.1007/s11581-015-1372-8
1. [1]
  Yifeng Xu , Jiquan Liu , Bin Cui , Yan Li , Gang Xie , Ying Yang . “Xiao Li’s School Adventures: The Working Principles and Safety Risks of Lithium-ion Batteries”. University Chemistry, 2024, 39(9): 259-265. doi: 10.12461/PKU.DXHX202404009
2. [2]
  Siyu Zhang , Kunhong Gu , Bing'an Lu , Junwei Han , Jiang Zhou . Hydrometallurgical Processes on Recycling of Spent Lithium-lon Battery Cathode: Advances and Applications in Sustainable Technologies. Acta Physico-Chimica Sinica, 2024, 40(10): 2309028-. doi: 10.3866/PKU.WHXB202309028
3. [3]
  Qi Li , Pingan Li , Zetong Liu , Jiahui Zhang , Hao Zhang , Weilai Yu , Xianluo Hu . Fabricating Micro/Nanostructured Separators and Electrode Materials by Coaxial Electrospinning for Lithium-Ion Batteries: From Fundamentals to Applications. Acta Physico-Chimica Sinica, 2024, 40(10): 2311030-. doi: 10.3866/PKU.WHXB202311030
4. [4]
  Qingtang ZHANG , Xiaoyu WU , Zheng WANG , Xiaomei WANG . Performance of nano Li₂FeSiO₄/C cathode material co-doped by potassium and chlorine ions. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1689-1696. doi: 10.11862/CJIC.20240115
5. [5]
  Jie XIE , Hongnan XU , Jianfeng LIAO , Ruoyu CHEN , Lin SUN , Zhong JIN . Nitrogen-doped 3D graphene-carbon nanotube network for efficient lithium storage. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1840-1849. doi: 10.11862/CJIC.20240216
6. [6]
  Yuanchao LI , Weifeng HUANG , Pengchao LIANG , Zifang ZHAO , Baoyan XING , Dongliang YAN , Li YANG , Songlin WANG . Effect of heterogeneous dual carbon sources on electrochemical properties of LiMn_0.8Fe_0.2PO₄/C composites. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 751-760. doi: 10.11862/CJIC.20230252
7. [7]
  Xinpeng LIU , Liuyang ZHAO , Hongyi LI , Yatu CHEN , Aimin WU , Aikui LI , Hao HUANG . Ga₂O₃ coated modification and electrochemical performance of Li_1.2Mn_0.54Ni_0.13Co_0.13O₂ cathode material. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1105-1113. doi: 10.11862/CJIC.20230488
8. [8]
  Zhihuan XU , Qing KANG , Yuzhen LONG , Qian YUAN , Cidong LIU , Xin LI , Genghuai TANG , Yuqing LIAO . Effect of graphene oxide concentration on the electrochemical properties of reduced graphene oxide/ZnS. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1329-1336. doi: 10.11862/CJIC.20230447
9. [9]
  Junke LIU , Kungui ZHENG , Wenjing SUN , Gaoyang BAI , Guodong BAI , Zuwei YIN , Yao ZHOU , Juntao LI . Preparation of modified high-nickel layered cathode with LiAlO₂/cyclopolyacrylonitrile dual-functional coating. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1461-1473. doi: 10.11862/CJIC.20240189
10. [10]
  Ruiqing LIU , Wenxiu LIU , Kun XIE , Yiran LIU , Hui CHENG , Xiaoyu WANG , Chenxu TIAN , Xiujing LIN , Xiaomiao FENG . Three-dimensional porous titanium nitride as a highly efficient sulfur host. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 867-876. doi: 10.11862/CJIC.20230441
11. [11]
  Zhenming Xu , Mingbo Zheng , Zhenhui Liu , Duo Chen , Qingsheng Liu . Experimental Design of Project-Driven Teaching in Computational Materials Science: First-Principles Calculations of the LiFePO₄ Cathode Material for Lithium-Ion Batteries. University Chemistry, 2024, 39(4): 140-148. doi: 10.3866/PKU.DXHX202307022
12. [12]
  Zhihong LUO , Yan SHI , Jinyu AN , Deyi ZHENG , Long LI , Quansheng OUYANG , Bin SHI , Jiaojing SHAO . Two-dimensional silica-modified polyethylene oxide solid polymer electrolyte to enhance the performance of lithium-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 1005-1014. doi: 10.11862/CJIC.20230444
13. [13]
  Qingyan JIANG , Yanyong SHA , Chen CHEN , Xiaojuan CHEN , Wenlong LIU , Hao HUANG , Hongjiang LIU , Qi LIU . Constructing a one-dimensional Cu-coordination polymer-based cathode material for Li-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 657-668. doi: 10.11862/CJIC.20240004
14. [14]
  Jianbao Mei , Bei Li , Shu Zhang , Dongdong Xiao , Pu Hu , Geng Zhang . Enhanced Performance of Ternary NASICON-Type Na_3.5-xMn_0.5V_1.5-xZr_x(PO₄)₃/C Cathodes for Sodium-Ion Batteries. Acta Physico-Chimica Sinica, 2024, 40(12): 2407023-. doi: 10.3866/PKU.WHXB202407023
15. [15]
  Xiaoning TANG , Junnan LIU , Xingfu YANG , Jie LEI , Qiuyang LUO , Shu XIA , An XUE . Effect of sodium alginate-sodium carboxymethylcellulose gel layer on the stability of Zn anodes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1452-1460. doi: 10.11862/CJIC.20240191
16. [16]
  Qiuyang LUO , Xiaoning TANG , Shu XIA , Junnan LIU , Xingfu YANG , Jie LEI . Application of a densely hydrophobic copper metal layer in-situ prepared with organic solvents for protecting zinc anodes. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1243-1253. doi: 10.11862/CJIC.20240110
17. [17]
  Doudou Qin , Junyang Ding , Chu Liang , Qian Liu , Ligang Feng , Yang Luo , Guangzhi Hu , Jun Luo , Xijun Liu . Addressing Challenges and Enhancing Performance of Manganese-based Cathode Materials in Aqueous Zinc-Ion Batteries. Acta Physico-Chimica Sinica, 2024, 40(10): 2310034-. doi: 10.3866/PKU.WHXB202310034
18. [18]
  Xiaoning TANG , Shu XIA , Jie LEI , Xingfu YANG , Qiuyang LUO , Junnan LIU , An XUE . Fluorine-doped MnO₂ with oxygen vacancy for stabilizing Zn-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1671-1678. doi: 10.11862/CJIC.20240149
19. [19]
  Peiran ZHAO , Yuqian LIU , Cheng HE , Chunying DUAN . A functionalized Eu³⁺ metal-organic framework for selective fluorescent detection of pyrene. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 713-724. doi: 10.11862/CJIC.20230355
20. [20]
  Fengmiao Yu , Yang Sheng , Chanyue Li , Bao Li . The Three Lives of Aspirin. University Chemistry, 2024, 39(9): 115-121. doi: 10.12461/PKU.DXHX202402033

Get Citation

PDF

XML

Metrics

PDF Downloads(7)
Abstract views(1523)
HTML views(323)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142