Citation: Li Zhangnan, Sha Haoyan, Yang Nan, Yuan Ye, Zhu Guangshan. Phosphoric Acid Based Porous Aromatic Framework for Uranium Extraction[J]. Acta Chimica Sinica, ;2019, 77(5): 469-474. doi: 10.6023/A19010028 shu

Phosphoric Acid Based Porous Aromatic Framework for Uranium Extraction

Li Zhangnan ^a ,
Sha Haoyan ^b ,
Yang Nan ^c ,
Yuan Ye ^a,, ,
Zhu Guangshan ^a

a.
Key Laboratory of Polyoxometalate Science of Ministry of Education, Northeast Normal University, Changchun 130024
b.
Department of Chemical Engineering, University of California, Davis, Davis, California 95616, United States
c.
China Faw New Energy Vehicle Branch, Changchun 130011

Corresponding author: Yuan Ye, Yuany101@nenu.edu.cn
Received Date: 16 January 2019
Available Online: 14 May 2019
Fund Project: the National Basic Research Program of China 2014CB931804Project supported by the National Basic Research Program of China (973 Program, No. 2014CB931804) and the National Natural Science Foundation of China (NSFC Project, Nos. 91622106, 21531003, 21601031)the National Natural Science Foundation of China 21601031the National Natural Science Foundation of China 91622106the National Basic Research Program of China 973 Programthe National Natural Science Foundation of China 21531003

Figures(11)

As a clean, safe, efficient, and economical energy, nuclear energy plays an irreplaceable role in the resource sector. However, uranium deposits on land will run out in the coming decades. The uranium content in seawater is huge but its concentration is as low as~3 ppb. So it is an urgent problem to design and synthesize adsorbent materials with high extraction efficiency. In this paper, taking the actual industrialization as the direction, we adopted biphenyl as the building block and synthesize the porous aromatic framework material (PAF-45) in a low price. Then porous aromatic framework material (PAF-45-PG) with phosphoric acid groups was prepared through a post-modification procedure. The structure and pore characteristics of the compound were investigated by FTIR, TGA, PXRD, SEM, TEM and N₂ adsorption experiments. FTIR spectrum indicates that the emerging vibrational peaks at 900~1250 cm^-1 can be ascribed to the successful decoration of phosphate groups in PAF-45-PG compared with pure PAF-45. Powder X-ray diffraction shows that PAF-45 and PAF-45-PG are amorphous. And transmission electron microscope (TEM) images also agree with the conclusion of PXRD that PAF materials possess disordered structure. Moreover, there is no significant weight loss before 400℃ demonstrated by thermogravimetric analysis, which indicates the high thermal stability of two PAF resultants. The porosity of PAF networks was characterized by measuring the N₂ adsorption isotherm at 77 K. Calculated by Brunauer-Emmett-Teller (BET) adsorption model, the specific surface area of PAF-45-PG is 426 m²·g^-1, which is lower than that of pure PAF-45 (828 m²·g^-1). This reduction of surface area is attributed to the introduction of functional groups which increase the weight per constitutional unit and occupy the space in the porous structure. After that, we tested the UO₂²⁺ ion adsorption of PAFs in simulated seawater. The equilibrium adsorption capacity of PAF-45-PG increases with the increase of uranium concentration, and reaches the maximum value (101 mg·g^-1) at about 8 ppm. Because the maximum capacity of PAF-45 is 5.9 mg·g^-1, this result indicates that the adsorption of uranium ion in PAF-45-PG is mainly caused by the post-modified phosphate functional group on its pore surface. Due to the low cost and simple preparation process, the material (PAF-45-PG) has a great industrial prospect.
- porous aromatic frameworks,
- phosphate group,
- Scholl reaction,
- uranium extraction,
- industrialization
1. [1]
  Kim, J.; Tsouris, C.; Mayes, R. T.; Oyola, Y.; Saito, T.; Janke, C. J.; Dai, S.; Schneider, E.; Sachde, D. Sep. Sci. Technol. 2013, 48, 367. doi: 10.1080/01496395.2012.712599
2. [2]
  Yue, Y.; Mayes, R. T.; Gill, G.; Kuo, L.; Wood, J.; Binder, A.; Brown, S.; Dai, S. RSC Adv. 2015, 5, 50005. doi: 10.1039/C5RA02131F
3. [3]
  Kim, J.; Tsouris, C.; Oyola, Y.; Janke, C. J.; Mayes, R. T.; Dai, S.; Gill, G.; Kuo, L.; Wood, J.; Choe, K.; Schneider, E.; Lindner, H. Ind. Eng. Chem. Res. 2014, 53, 6076. doi: 10.1021/ie4039828
4. [4]
  Saito, T.; Brown, S.; Chatterjee, S.; Kim, J.; Tsouris, C.; Mayes, R.T.; Kuo, L.; Gill, G.; Oyola, Y.; Janke, C. J.; Dai, S. J. Mater. Chem. A 2014, 2, 14674. doi: 10.1039/C4TA03276D
5. [5]
  Kim, J.; Oyola, Y.; Tsouris, C.; Cole, C. R.; Mayes, R. T.; Janke, J. C.; Dai, S. Ind. Eng. Chem. Res. 2013, 52, 9433. doi: 10.1021/ie400587f
6. [6]
  Sholl, D. S.; Lively, R. P. Nature 2016, 532, 435. doi: 10.1038/532435a
7. [7]
  Lu, Y. Nat. Chem. 2014, 6, 175. doi: 10.1038/nchem.1880
8. [8]
  Yue, Y.; Mayes, R.; Kim, J.; Sun, X.; Chen, J.; Dai, S. Angew. Chem., Int. Ed. 2013, 52, 13458. doi: 10.1002/anie.201307825
9. [9]
  Liu, C.; Xie, J.; Zhao, J.; Wu, T.; Wang, H.; Liu, W.; Zhang, J.; Cui, Y. Nat. Energy. 2017, 2, 17007. doi: 10.1038/nenergy.2017.7
10. [10]
  Feng, M.; Sarma, D.; Qi, X.; Du, K.; Huang, X. J. Am. Chem. Soc. 2016, 138, 12578. doi: 10.1021/jacs.6b07351
11. [11]
  Sun, Q.; Aguila, B. Adv. Mater. 2018, 1705479.
12. [12]
  Barber, P. S.; Kelley, S. P.; Griggs, C. S.; Wallace, S.; Rogers, R. D. Green Chem. 2014, 16, 1828. doi: 10.1039/C4GC00092G
13. [13]
  Yue, Y.; Sun, X.; Mayes, R. T.; Kim, J.; Fulvio, P. F.; Qiao, Z.; Brown, S.; Tsouris, C.; Oyola, Y.; Dai, S. Sci. China: Chem. 2013, 56, 1510.
14. [14]
  Kobuke, Y.; Tabushi, I.; Aoki, T.; Kamaishi, T.; Hagiwara, I. Ind. Eng. Chem. Res. 1988, 27, 1461. doi: 10.1021/ie00080a018
15. [15]
  Carboni, M.; Abney, C. W.; Liu, S.; Lin, W. Chem. Sci. 2013, 4, 2396. doi: 10.1039/c3sc50230a
16. [16]
  Manos, M. J.; Kanatzidis, M. G. J. Am. Chem. Soc. 2012, 134, 16441. doi: 10.1021/ja308028n
17. [17]
  Kobayashi, S.; Tokunoh, M.; Saegusa, T.; Mashio, F. Macromolecules 1985, 18, 2357. doi: 10.1021/ma00154a004
18. [18]
  Chen, H. J.; Huang, S. Y.; Zhang, Z. B.; Liu, Y. H.; Wang, X. K. Acta Chim. Sinica 2017, 75, 560(in Chinese). doi: 10.11862/CJIC.2017.075
19. [19]
  Chatterjee, S.; Bryantsev, V. S.; Brown, S.; Johnson, J. C.; Grant, C. D.; Mayes, R. T.; Hay, B. P. Ind. Eng. Chem. Res. 2016, 55, 4161. doi: 10.1021/acs.iecr.5b03212
20. [20]
  Yue, Y.; Zhang, C.; Tang, Q.; Mayes, R. T.; Liao, W.; Liao, C.; Dai, S. Ind. Eng. Chem. Res. 2016, 55, 4125. doi: 10.1021/acs.iecr.5b03372
21. [21]
  Shao, D.; Wang, X.; Ren, X.; Hu, S.; Wen, J.; Tan, Z.; Marwani, H. M. J. Ind. Eng. Chem. 2018, 67, 380. doi: 10.1016/j.jiec.2018.07.012
22. [22]
  Birnbaum, J. C.; Busche, B.; Lin, Y.; Shaw, W. J.; Fryxell, G. E. Chem. Commun. 2002, 1374.
23. [23]
  Ren, X.; Yang, S.; Tan, X.; Chen, C.; Sheng, G.; Wang, X. J. Hazard. Mater. 2012, 237, 199.
24. [24]
  Yantasee, W.; Fryxell, G. E.; Addleman, R. S.; Wiacek, R. J.; Koonsiripaiboon, V.; Pattamakomsan, K.; Xu, J.; Raymond, K. N. J. Hazard. Mater. 2009, 168, 1233. doi: 10.1016/j.jhazmat.2009.03.004
25. [25]
  Ma, T.; Yuan, Z. Dalton Trans. 2010, 39, 9570. doi: 10.1039/c0dt00179a
26. [26]
  Venkateswarlu, S.; Yoon, M. RSC Adv. 2015, 5, 65444. doi: 10.1039/C5RA10628A
27. [27]
  Zhu, Y.; Liu, Y.; Ren, T.; Yuan, Z. Nanoscale 2014, 6, 6627. doi: 10.1039/C4NR00629A
28. [28]
  Das, S.; Pandey, A. K.; Athawale, A. A.; Natarajan, V.; Manchanda, V. K. Water Treat. 2012, 38, 1140.
29. [29]
  Yang, Y.; Yan, Z.; Wang, L.; Meng, Q.; Yuan, Y.; Zhu, G. J. Mater. Chem. A 2018, 6, 5202. doi: 10.1039/C8TA00382C
30. [30]
  Yuan, Y.; Sun, F.; Zhang, F.; Ren, H.; Jing, X.; Gao, X. Adv. Mater. 2013, 25, 6619. doi: 10.1002/adma.201301955
31. [31]
  Yuan, Y.; Sun, F.; Li, L.; Cui, P.; Zhu, G. Nat. Commun. 2014, 4260.
32. [32]
  Li, L.-N. Ph.D. Dissertation, Jilin University, Changchun, 2015 (in Chinese).
33. [33]
  Egawa, H.; Nonaka, T.; Ikari, M. J. Appl. Polym. Sci. 2010, 29, 2045.
1. [1]
  Guang Huang , Lei Li , Dingyi Zhang , Xingze Wang , Yugai Huang , Wenhui Liang , Zhifen Guo , Wenmei Jiao . Cobalt’s Valor, Nickel’s Foe: A Comprehensive Chemical Experiment Utilizing a Cobalt-based Imidazolate Framework for Nickel Ion Removal. University Chemistry, 2024, 39(8): 174-183. doi: 10.3866/PKU.DXHX202311051
2. [2]
  Jinyao Du , Xingchao Zang , Ningning Xu , Yongjun Liu , Weisi Guo . Electrochemical Thiocyanation of 4-Bromoethylbenzene. University Chemistry, 2024, 39(6): 312-317. doi: 10.3866/PKU.DXHX202310039
3. [3]
  Wentao Lin , Wenfeng Wang , Yaofeng Yuan , Chunfa Xu . Concerted Nucleophilic Aromatic Substitution Reactions. University Chemistry, 2024, 39(6): 226-230. doi: 10.3866/PKU.DXHX202310095
4. [4]
  Danqing Wu , Jiajun Liu , Tianyu Li , Dazhen Xu , Zhiwei Miao . Research Progress on the Simultaneous Construction of C—O and C—X Bonds via 1,2-Difunctionalization of Olefins through Radical Pathways. University Chemistry, 2024, 39(11): 146-157. doi: 10.12461/PKU.DXHX202403087
5. [5]
  Renxiao Liang , Zhe Zhong , Zhangling Jin , Lijuan Shi , Yixia Jia . A Palladium/Chiral Phosphoric Acid Relay Catalysis for the One-Pot Three-Step Synthesis of Chiral Tetrahydroquinoline. University Chemistry, 2024, 39(5): 209-217. doi: 10.3866/PKU.DXHX202311024
6. [6]
  Yangrui Xu , Yewei Ren , Xinlin Liu , Hongping Li , Ziyang Lu . 具有高传质和亲和表面的NH₂-UIO-66基疏水多孔液体用于增强CO₂光还原. Acta Physico-Chimica Sinica, 2024, 40(11): 2403032-. doi: 10.3866/PKU.WHXB202403032
7. [7]
  Doudou Qin , Junyang Ding , Chu Liang , Qian Liu , Ligang Feng , Yang Luo , Guangzhi Hu , Jun Luo , Xijun Liu . Addressing Challenges and Enhancing Performance of Manganese-based Cathode Materials in Aqueous Zinc-Ion Batteries. Acta Physico-Chimica Sinica, 2024, 40(10): 2310034-. doi: 10.3866/PKU.WHXB202310034
8. [8]
  Shiyan Cheng , Yonghong Ruan , Lei Gong , Yumei Lin . Research Advances in Friedel-Crafts Alkylation Reaction. University Chemistry, 2024, 39(10): 408-415. doi: 10.12461/PKU.DXHX202403024
9. [9]
  Youlin SI , Shuquan SUN , Junsong YANG , Zijun BIE , Yan CHEN , Li LUO . Synthesis and adsorption properties of Zn(Ⅱ) metal-organic framework based on 3, 3', 5, 5'-tetraimidazolyl biphenyl ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1755-1762. doi: 10.11862/CJIC.20240061
10. [10]
  Peiran ZHAO , Yuqian LIU , Cheng HE , Chunying DUAN . A functionalized Eu³⁺ metal-organic framework for selective fluorescent detection of pyrene. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 713-724. doi: 10.11862/CJIC.20230355
11. [11]
  Wendian XIE , Yuehua LONG , Jianyang XIE , Liqun XING , Shixiong SHE , Yan YANG , Zhihao HUANG . Preparation and ion separation performance of oligoether chains enriched covalent organic framework membrane. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1528-1536. doi: 10.11862/CJIC.20240050
12. [12]
  Tiantian MA , Sumei LI , Chengyu ZHANG , Lu XU , Yiyan BAI , Yunlong FU , Wenjuan JI , Haiying YANG . Methyl-functionalized Cd-based metal-organic framework for highly sensitive electrochemical sensing of dopamine. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 725-735. doi: 10.11862/CJIC.20230351
13. [13]
  Chengqian Mao , Yanghan Chen , Haotong Bai , Junru Huang , Junpeng Zhuang . Photodimerization of Styrylpyridinium Salt and Its Application in Silk Screen Printing. University Chemistry, 2024, 39(5): 354-362. doi: 10.3866/PKU.DXHX202312014
14. [14]
  Feiya Cao , Qixin Wang , Pu Li , Zhirong Xing , Ziyu Song , Heng Zhang , Zhibin Zhou , Wenfang Feng . Magnesium-Ion Conducting Electrolyte Based on Grignard Reaction: Synthesis and Properties. University Chemistry, 2024, 39(3): 359-368. doi: 10.3866/PKU.DXHX202308094
15. [15]
  Yinuo Wang , Siran Wang , Yilong Zhao , Dazhen Xu . Selective Synthesis of Diarylmethyl Anilines and Triarylmethanes via Multicomponent Reactions: Introduce a Comprehensive Experiment of Organic Chemistry. University Chemistry, 2024, 39(8): 324-330. doi: 10.3866/PKU.DXHX202401063
16. [16]
  Zitong Chen , Zipei Su , Jiangfeng Qian . Aromatic Alkali Metal Reagents: Structures, Properties and Applications. University Chemistry, 2024, 39(8): 149-162. doi: 10.3866/PKU.DXHX202311054
17. [17]
  Yan LIU , Jiaxin GUO , Song YANG , Shixian XU , Yanyan YANG , Zhongliang YU , Xiaogang HAO . Exclusionary recovery of phosphate anions with low concentration from wastewater using a CoNi-layered double hydroxide/graphene electronically controlled separation film. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1775-1783. doi: 10.11862/CJIC.20240043
18. [18]
  Ruiqing LIU , Wenxiu LIU , Kun XIE , Yiran LIU , Hui CHENG , Xiaoyu WANG , Chenxu TIAN , Xiujing LIN , Xiaomiao FENG . Three-dimensional porous titanium nitride as a highly efficient sulfur host. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 867-876. doi: 10.11862/CJIC.20230441
19. [19]
  Lei Shi . Nucleophilicity and Electrophilicity of Radicals. University Chemistry, 2024, 39(11): 131-135. doi: 10.3866/PKU.DXHX202402018
20. [20]
  Zhaomei LIU , Wenshi ZHONG , Jiaxin LI , Gengshen HU . Preparation of nitrogen-doped porous carbons with ultra-high surface areas for high-performance supercapacitors. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 677-685. doi: 10.11862/CJIC.20230404

Get Citation

PDF

XML

Metrics

PDF Downloads(12)
Abstract views(802)
HTML views(142)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142