Citation: Zhu Guifen, Chen Letian, Cheng Guohao, Zhao Juan, Yang Can, Zhang Yaozong, Wang Xing, Fan Jing. Efficient Removal of Levofloxacin Hydrochloride from Environment by UiO-66/CoSO₄ Composites[J]. Acta Chimica Sinica, ;2019, 77(5): 434-441. doi: 10.6023/A18120511 shu

Efficient Removal of Levofloxacin Hydrochloride from Environment by UiO-66/CoSO₄ Composites

School of Environment, Henan Normal University, Key Laboratory for Yellow River and Huai River Water Environment and Pollution Control, Ministry of Education, Henan Key Laboratory for Environmental Pollution Control, Xinxiang 453007

Corresponding author: Zhu Guifen, gfzhu617@163.com; fanjing@htu.cn Fan Jing, fanjing@htu.cn
Received Date: 25 December 2018
Available Online: 20 May 2019
Fund Project: Key Scientific Research Foundation of the Higher Education Institutions of Henan Province 2016GGJS-047Project supported by the National Natural Science Foundation of China (Nos. 21507023, 21876045 and 21777038), Key Scientific Research Foundation of the Higher Education Institutions of Henan Province (No. 2016GGJS-047) and Scientific and Technological Department of Henan Province (No. 182102310656)the National Natural Science Foundation of China 21507023Scientific and Technological Department of Henan Province 182102310656the National Natural Science Foundation of China 21777038the National Natural Science Foundation of China 21876045

Figures(9)

In this work, a newly UiO-66/CoSO₄ composite was prepared by introducing UiO-66 as precursor carrier. The morphology and structure of the presented UiO-66/CoSO₄ composite were characterized by scanning electron microscopy, elemental analysis, specific surface area analysis and X-ray diffraction. The adsorption performance of UiO-66/CoSO₄ towards levofloxacin hydrochloride (LV) in aqueous solution was investigated, and some parameters, such as pH value, temperature, contact time and initial concentration have been optimized. The results showed that the UiO-66/CoSO₄ composite has significant adsorption performance for levofloxacin hydrochloride. Compared with the control material UiO-66, the removal efficiency of the composite towards levofloxacin hydrochloride increased by 20% under the same conditions, which indicated that the properties of the composites have been greatly improved. Within 5 min, 95.3% of levofloxacin hydrochloride can be removed, and the equilibrium adsorption (99.8%) was achieved within 30 min and the adsorption process could be described by pseudo-second-order kinetic model. The adsorption isotherm verified that the maximum adsorption capacity was up to 108.42 mg·g^-1 and fitted well with the Langmuir isotherm model, which indicated that monolayer coverage of levofloxacin hydrochloride was formed on the surface of UiO-66/CoSO₄ composite. Data obtained from thermodynamic study showed that the adsorption process is spontaneous endothermic reaction and the chemical adsorption might play major role to control step. The UiO-66/CoSO₄ composite was easy to prepare with good reusability, and the adsorption efficiency is still higher than 92.2% after five cycles. Additionally, under the optimized condition, the UiO-66/CoSO₄ composite was successfully applied for the removal of levofloxacin hydrochloride from environmental water and soil samples. It was found that above 94.7% of target can be removed by the as-prepared UiO-66/CoSO₄ composite. This result proved that the composite with excellent recognition has been synthesized. The new UiO-66/CoSO₄ composite prepared in this work provided a way to treatment levofloxacin hydrochloride in environment with broad application prospect.
- UiO-66/CoSO₄,
- levofloxacin hydrochloride,
- environmental samples,
- removal
1. [1]
  Yang, T.; Cui, Y. N.; Chen, H. Y.; Li, W. H. Acta Chim. Sinica 2017, 75, 339(in Chinese).
2. [2]
  Cao, L. Y.; Wang, T. T.; Wang, C. Chin. J. Chem. 2018, 36, 754. doi: 10.1002/cjoc.v36.8
3. [3]
  Li, Y.; Zou, B.; Xiao, A. S.; Zhang, H. X. Chin. J. Chem. 2017, 35, 1501. doi: 10.1002/cjoc.v35.10
4. [4]
  Zhang, H.; Li, G. L.; Zhang, K. G.; Liao, C. Y. Acta Chim. Sinica 2017, 75, 841(in Chinese).
5. [5]
  Li, J.; Wang, X.; Zhao, G. Chem. Soc. Rev. 2018, 47, 2322. doi: 10.1039/C7CS00543A
6. [6]
  Pang, C. M.; Luo, S. H.; Hao, Z. F.; Gao, J.; Huang, Z. H.; Yu, J. H.; Yu, S. M.; Wang, Z.Y. Chin. J. Org. Chem. 2018, 38, 2606(in Chinese).
7. [7]
  Cao, J.; Yang, Z. H.; Xiong, W. P. Chem. Eng. J. 2018, 353, 126. doi: 10.1016/j.cej.2018.07.060
8. [8]
  Jin, T.; Yuan, W.; Xue, Y. Environ. Sci. Pollut. Res. 2017, 24, 5238. doi: 10.1007/s11356-016-8262-0
9. [9]
  Yan, B.; Niu, C. H.; Wang, J. Environ. Sci. Technol. 2017, 51, 8048. doi: 10.1021/acs.est.7b00327
10. [10]
  Dong, S.; Sun, Y.; Wu, J. Chemosphere 2016, 150, 759. doi: 10.1016/j.chemosphere.2015.11.075
11. [11]
  Yu, Y.; Wang, W.; Shi, J. Environ. Sci. Pollut. Res. 2017, 24, 10685. doi: 10.1007/s11356-017-8700-7
12. [12]
  Yi, S.; Sun, Y.; Hu, X. Environ. Sci. Pollut. Res. 2018, 25, 25629. doi: 10.1007/s11356-016-8342-1
13. [13]
  Li, H. R.; Song, L. N.; Hu, B. B.; Li, Z.; Li, S. M.; Wang, Z. Y. J. Shenyang Pharm. Univ. 2017, 34, 285(in Chinese).
14. [14]
  Yi, S.; Gao, B.; Sun, Y. Chemosphere 2016, 150, 694. doi: 10.1016/j.chemosphere.2015.12.112
15. [15]
  Shen, L. J.; Luo, M. B.; Liu, Y. H. Appl. Catal. B-Environ. 2015, 166, 445.
16. [16]
  Jin, J. H.; Yang, Z. H.; Xiong, W. P.; Zhou, Y. Y.; Xu, R.; Zhang, Y. R.; Cao, J.; Li, X. Sci. Total Environ. 2019, 650, 408. doi: 10.1016/j.scitotenv.2018.08.434
17. [17]
  Zhu, G. F.; Fan, J.; Gao, Y. P. Talanta 2011, 84, 1124. doi: 10.1016/j.talanta.2011.03.015
18. [18]
  Wu, C. L.; Zhu, G. F.; Fan, J. RSC Adv. 2016, 6, 86428. doi: 10.1039/C6RA15999K
19. [19]
  Xiong, H.; Wu, X.; Lu, W. Talanta 2018, 176, 187. doi: 10.1016/j.talanta.2017.08.019
20. [20]
  Zhu, G. F.; Gao, X.; Wang, X. L. J. Chromatogr. A 2018, 1532, 40. doi: 10.1016/j.chroma.2017.11.057
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沈阳化工大学材料科学与工程学院沈阳 110142

Efficient Removal of Levofloxacin Hydrochloride from Environment by UiO-66/CoSO4 Composites

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通讯作者: 陈斌, bchen63@163.com

Efficient Removal of Levofloxacin Hydrochloride from Environment by UiO-66/CoSO₄ Composites