Citation: Cai Qian, Ma Haowen. Recent Advances of Chiral Hypervalent Iodine Reagents[J]. Acta Chimica Sinica, ;2019, 77(3): 213-230. doi: 10.6023/A18110470 shu

Recent Advances of Chiral Hypervalent Iodine Reagents

Cai Qian ^, ,
Ma Haowen

College of Pharmacy, Jinan University, Guangzhou 510530

Corresponding author: Cai Qian, caiqian@jnu.edu.cn
Received Date: 21 November 2018
Available Online: 28 March 2019
Fund Project: the National Natural Science Foundation of China 21772066Guangdong Special Support Program 2017TX04R059Project supported by the National Natural Science Foundation of China (Nos. 21772066, 21572229) and Guangdong Special Support Program (No. 2017TX04R059)the National Natural Science Foundation of China 21572229

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Hypervalent iodine chemistry has arose as an important field in organic chemistry in the past decades. Hypervalent iodine compounds, with reactivities similarly to transition metals in many different types of transformations, have attracted broad interests in organic community due to their practical advantages in the mild conditions, low costs, environmental benign and low toxicity. Great progresses have been made in this field. Chiral hypervalent iodine reagents or precursors have also been developed and utilized in a variety of asymmetric reactions in a stoichiometric or catalytic way. Important advances have been witnessed in the field of chiral hypervalent iodine chemistry in recent years. However, great limitations still exist. In this review, we have made a summary of different types of chiral hypervalent iodine reagents and precursors according to the characteristics of these compounds and the timeline. It may be helpful for the researchers to better understand the development and limitations of chiral hypervalent iodine chemistry.
- chirality,
- chiral hypervalent iodine,
- chiral aryl iodide,
- asymmetric reaction,
- catalytic asymmetric synthesis
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