Citation: Ma Guojia, Zheng Haikun, Chang Shinan, Wang Shuoshuo. Wettability Analysis and Design of Micro-nanostructured Superhydrophobic Surface[J]. Acta Chimica Sinica, ;2019, 77(3): 269-277. doi: 10.6023/A18100430 shu

Wettability Analysis and Design of Micro-nanostructured Superhydrophobic Surface

a.
Science and Technology on Power Beam Processes Laboratory, Beijing Aeronautical Manufacturing Technology Research Institute, Beijing 100024
b.
School of Aeronautic Science and Engineering, Beihang University, Beijing 100191

Corresponding author: Chang Shinan, sn_chang@buaa.edu.cn
Received Date: 16 October 2018
Available Online: 3 March 2018
Fund Project: National Basic Research Program of China 2015CB755803the National Natural Science Foundation of China 11672024the National Natural Science Foundation of China 11372026Project supported by the National Natural Science Foundation of China (Grant Nos. 11672024, 11372026) and National Basic Research Program of China (Grants No. 2015CB755803)

Figures(8)

The special wettability of superhydrophobic surface usually has high contact angles (CA>150°) and low contact angle hysteresis (CAH < 5°), which has been exploited for many potential applications. It is well known that wettability is mainly determined by micro/nano structure and surface composition, and various types of natural superhydrophobic surface could exhibit different wetting states, showing different wetting properties, such as low adhesive lotus leaf; the anisotropic superhydrophobic rice leaf; high adhesive rose petal. Therefore, the relationship between the wetting state and the surface structure should have a deeper understanding, especially in the design preliminary stage. The "droplet-superhydrophobic surface" system is taken as the research objects, four stable wetting state expressions are analyzed based on the principle of minimum energy. Wetting state transitions are studied on superhydrophobic surface coverd with micro/nano structured pillars of different distributions. The calculation formula of intrinsic contact angle is derived and the intrinsic contact angle of common materials is investigated. Based on the four wetting state of apparent contact angle equations, wetting diagrams were drew for investigating the wetting behavior, which include "one point, three lines, six areas, four state". The influence of the relative structure spacing and relative structure height on the wetting state is analyzed. It is found that the larger relative structure height, the smaller relative structure spacing, which can reduce the critical parameters of the transition state of the infiltration state, thereby expanding the range of the superhydrophobic surface, the more design options are available. It is also beneficial to the stability of the superhydrophobic surface, but should be controlled within certain scales because of mechanical stability. The simulation results accurately reflect the wetting state with the changes of the relative structure spacing and relative structure height. Finally, the general design of the superhydrophobic surface is refined. The results can provide theoretical guidance and technical fundament for the design of superhydrophobic surfaces.
- wettability,
- superhydrophobic surface,
- critical relative structure spacing,
- critical relative structure height,
- design clue,
- wetting state transition
1. [1]
  Barthlott, W.; Neinhuis, C. Planta 1997, 202, 1. doi: 10.1007/s004250050096
2. [2]
  Marmur, A. Langmuir 2003, 19, 5956. doi: 10.1021/la034490v
3. [3]
  Zheng, H. K.; Chang, S. N.; Zhao, Y. Y. Prog. Chem. 2017, 29, 102.
4. [4]
  Kreder, M. J.; Alvarenga, J.; Kim, P.; Aizenberg, J. Nat. Rev. Mater. 2016, 1, 15003. doi: 10.1038/natrevmats.2015.3
5. [5]
  Liang, W. X.; Zhang, Y. B.; Wang, B.; Guo, Z. G.; Liu, W. M. Acta Chim. Sinica 2012, 70, 2393
6. [6]
  Zhang, J. N.; Yu, J. H. Chin. J. Chem. 2018, 36, 51. doi: 10.1002/cjoc.201700579
7. [7]
  Cui, L. Y.; Fan, S. S.; Yu, C. L.; Kuang, M. X.; Wang, J. X. Acta Chim. Sinica 2017, 75, 967.
8. [8]
  Wenzel, R. N. Ind. Eng. Chem. 1936, 28, 988. doi: 10.1021/ie50320a024
9. [9]
  Cassie, A. B. D.; Baxter, S. Trans. Faraday Soc. 1944, 40, 546. doi: 10.1039/tf9444000546
10. [10]
  Bico, J.; Tiele, U.; Quere, D. Colloid Surface A 2002, 206, 41. doi: 10.1016/S0927-7757(02)00061-4
11. [11]
  Bhushan, B.; Nosonovsky, M. Phil. Trans. R. Soc. A 2010, 368, 4713. doi: 10.1098/rsta.2010.0203
12. [12]
  Suzuki, S.; Ueno, K. Langmuir 2017, 33, 138. doi: 10.1021/acs.langmuir.6b03832
13. [13]
  Hejazi, V.; Nosonovsky, M. Colloid Polym. Sci. 2013, 291, 329. doi: 10.1007/s00396-012-2838-0
14. [14]
  Tuvshindorj, U.; Yildirim, A.; Ozturk, F. E.; Bayindir, M. ACS Appl. Mater. Inter. 2014, 6, 9680. doi: 10.1021/am502117a
15. [15]
  Wang, S.; Jiang, L. Adv. Mater. 2007, 19, 3423. doi: 10.1002/(ISSN)1521-4095
16. [16]
  Rahmawan, Y.; Moon, M. W.; Kim, K. S. Langmuir 2009, 26, 484.
17. [17]
  Wu, B. B.; Wu, H. P.; Zhang, Z.; Dong, C. C.; Chai, G. Z. Acta Phys. Sin. 2015, 64, 176801.
18. [18]
  Lv, P. Y.; Xue, Y. H.; Duan, H. L. Adv. Mech. 2016, 46, 179.
19. [19]
  Moosmann, M.; Schimmel, T.; Barthlott, W.; Mail, M. Beilstein J. Nanotech. 2017, 8, 1671. doi: 10.3762/bjnano.8.167
20. [20]
  Seo, J.; García-Mayoral, R.; Mani, A. J. Fluid Mech. 2018, 8, 35.
21. [21]
  Lafuma, A.; Queré, D. Nat. Mater. 2003, 2, 457. doi: 10.1038/nmat924
22. [22]
  Ye, X. M.; Zhang, X. S.; Li, M. L.; Li, C. X. Acta Phys. Sin. 2018, 67, 114702. doi: 10.7498/aps.67.20180159
23. [23]
  Kwon, H. M.; Paxson, A. T.; Varanasi, K. K.; Patankar, N. A. Phys. Rev. Lett. 2011, 106, 036102. doi: 10.1103/PhysRevLett.106.036102
24. [24]
  Bartolo, D.; Bouamrirene, F.; Verneuil, É.; Buguin, A.; Silberzan, P.; Moulinet, S. EPL 2006, 74, 299. doi: 10.1209/epl/i2005-10522-3
25. [25]
  Bormashenko, E.; Pogreb, R.; Whyman, G.; Erlich, G. Langmuir 2007, 23, 12217. doi: 10.1021/la7016374
26. [26]
  Girifalco, L. A.; Good, R. J. J. Phys. Chem. 1957, 61, 904. doi: 10.1021/j150553a013
27. [27]
  Zisman, W. A. Adv. Chem. 1964, 43, 1. doi: 10.1021/advances
28. [28]
  Barthlott, W.; Neinhuis, C.; Cutler, D.; Ditsch, F.; Meusel, I.; Theisen, I. Bot. J. Linn. Soc. 1998, 126, 237. doi: 10.1111/boj.1998.126.issue-3
29. [29]
  Nishino, T.; Meguro, M.; Nakamae, K. Langmuir 1999, 15, 4321. doi: 10.1021/la981727s
30. [30]
  Han, J. T.; Sun, Y. K.; Woo, J. S.; Lee, G. W. Adv. Mater. 2010, 20, 3724.
31. [31]
  Raza, M. A.; Kooij, E. S.; Silfhout, A. Langmuir 2010, 26, 12962. doi: 10.1021/la101867z
32. [32]
  Liu, X.; Dai, B.; Zhou, L.; Sun, J. J. Mater. Chem. 2009, 19, 497. doi: 10.1039/B817467A
33. [33]
  Dong, J.; Jin, Y.; Dong, H.; Sun, L. Langmuir 2017, 33, 1041.
34. [34]
  Guan, Z. S.; Zhang, Q. Acta Chim. Sinica 2005, 63, 880.
35. [35]
  Kulinich, S. A.; Farhadi, S.; Nose, K. Langmuir 2011, 27, 25. doi: 10.1021/la104277q
1. [1]
  Xiutao Xu , Chunfeng Shao , Jinfeng Zhang , Zhongliao Wang , Kai Dai . Rational Design of S-Scheme CeO₂/Bi₂MoO₆ Microsphere Heterojunction for Efficient Photocatalytic CO₂ Reduction. Acta Physico-Chimica Sinica, 2024, 40(10): 2309031-. doi: 10.3866/PKU.WHXB202309031
2. [2]
  Xinlong WANG , Zhenguo CHENG , Guo WANG , Xiaokuen ZHANG , Yong XIANG , Xinquan WANG . Enhancement of the fragile interface of high voltage LiCoO₂ by surface gradient permeation of trace amounts of Mg/F. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 571-580. doi: 10.11862/CJIC.20230259
3. [3]
  Qi Li , Pingan Li , Zetong Liu , Jiahui Zhang , Hao Zhang , Weilai Yu , Xianluo Hu . Fabricating Micro/Nanostructured Separators and Electrode Materials by Coaxial Electrospinning for Lithium-Ion Batteries: From Fundamentals to Applications. Acta Physico-Chimica Sinica, 2024, 40(10): 2311030-. doi: 10.3866/PKU.WHXB202311030
4. [4]
  Cheng PENG , Jianwei WEI , Yating CHEN , Nan HU , Hui ZENG . First principles investigation about interference effects of electronic and optical properties of inorganic and lead-free perovskite Cs₃Bi₂X₉ (X=Cl, Br, I). Chinese Journal of Inorganic Chemistry, 2024, 40(3): 555-560. doi: 10.11862/CJIC.20230282
5. [5]
  Liang MA , Honghua ZHANG , Weilu ZHENG , Aoqi YOU , Zhiyong OUYANG , Junjiang CAO . Construction of highly ordered ZIF-8/Au nanocomposite structure arrays and application of surface-enhanced Raman spectroscopy. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1743-1754. doi: 10.11862/CJIC.20240075
6. [6]
  Xinting XIONG , Zhiqiang XIONG , Panlei XIAO , Xuliang NIE , Xiuying SONG , Xiuguang YI . Synthesis, crystal structures, Hirshfeld surface analysis, and antifungal activity of two complexes Na(Ⅰ)/Cd(Ⅱ) assembled by 5-bromo-2-hydroxybenzoic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1661-1670. doi: 10.11862/CJIC.20240145
7. [7]
  Peiran ZHAO , Yuqian LIU , Cheng HE , Chunying DUAN . A functionalized Eu³⁺ metal-organic framework for selective fluorescent detection of pyrene. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 713-724. doi: 10.11862/CJIC.20230355
8. [8]
  Xin XIONG , Qian CHEN , Quan XIE . First principles study of the photoelectric properties and magnetism of La and Yb doped AlN. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1519-1527. doi: 10.11862/CJIC.20240064
9. [9]
  Jiakun BAI , Ting XU , Lu ZHANG , Jiang PENG , Yuqiang LI , Junhui JIA . A red-emitting fluorescent probe with a large Stokes shift for selective detection of hypochlorous acid. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1095-1104. doi: 10.11862/CJIC.20240002
10. [10]
  Jiaqi AN , Yunle LIU , Jianxuan SHANG , Yan GUO , Ce LIU , Fanlong ZENG , Anyang LI , Wenyuan WANG . Reactivity of extremely bulky silylaminogermylene chloride and bonding analysis of a cubic tetragermylene. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1511-1518. doi: 10.11862/CJIC.20240072
11. [11]
  Jin CHANG . Supercapacitor performance and first-principles calculation study of Co-doping Ni(OH)₂. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1697-1707. doi: 10.11862/CJIC.20240108
12. [12]
  Zizheng LU , Wanyi SU , Qin SHI , Honghui PAN , Chuanqi ZHAO , Chengfeng HUANG , Jinguo PENG . Surface state behavior of W doped BiVO₄ photoanode for ciprofloxacin degradation. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 591-600. doi: 10.11862/CJIC.20230225
13. [13]
  Jie ZHAO , Sen LIU , Qikang YIN , Xiaoqing LU , Zhaojie WANG . Theoretical calculation of selective adsorption and separation of CO₂ by alkali metal modified naphthalene/naphthalenediyne. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 515-522. doi: 10.11862/CJIC.20230385
14. [14]
  Xingyang LI , Tianju LIU , Yang GAO , Dandan ZHANG , Yong ZHOU , Meng PAN . A superior methanol-to-propylene catalyst: Construction via synergistic regulation of pore structure and acidic property of high-silica ZSM-5 zeolite. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1279-1289. doi: 10.11862/CJIC.20240026
15. [15]
  Zhaomei LIU , Wenshi ZHONG , Jiaxin LI , Gengshen HU . Preparation of nitrogen-doped porous carbons with ultra-high surface areas for high-performance supercapacitors. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 677-685. doi: 10.11862/CJIC.20230404
16. [16]
  Jing SU , Bingrong LI , Yiyan BAI , Wenjuan JI , Haiying YANG , Zhefeng Fan . Highly sensitive electrochemical dopamine sensor based on a highly stable In-based metal-organic framework with amino-enriched pores. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1337-1346. doi: 10.11862/CJIC.20230414
17. [17]
  Junke LIU , Kungui ZHENG , Wenjing SUN , Gaoyang BAI , Guodong BAI , Zuwei YIN , Yao ZHOU , Juntao LI . Preparation of modified high-nickel layered cathode with LiAlO₂/cyclopolyacrylonitrile dual-functional coating. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1461-1473. doi: 10.11862/CJIC.20240189
18. [18]
  Yuanpei ZHANG , Jiahong WANG , Jinming HUANG , Zhi HU . Preparation of magnetic mesoporous carbon loaded nano zero-valent iron for removal of Cr(Ⅲ) organic complexes from high-salt wastewater. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1731-1742. doi: 10.11862/CJIC.20240077
19. [19]
  Kun WANG , Wenrui LIU , Peng JIANG , Yuhang SONG , Lihua CHEN , Zhao DENG . Hierarchical hollow structured BiOBr-Pt catalysts for photocatalytic CO₂ reduction. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1270-1278. doi: 10.11862/CJIC.20240037
20. [20]
  Haitang WANG , Yanni LING , Xiaqing MA , Yuxin CHEN , Rui ZHANG , Keyi WANG , Ying ZHANG , Wenmin WANG . Construction, crystal structures, and biological activities of two Ln^Ⅲ₃ complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1474-1482. doi: 10.11862/CJIC.20240188

Get Citation

PDF

XML

Metrics

PDF Downloads(91)
Abstract views(3478)
HTML views(1049)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142