Citation: Ma Yali, Liu Ruxue, Meng Shuangyan, Niu Litong, Yang Zhiwang, Lei Ziqiang. Preparation and Photocatalytic Activity of Fe-ZrO₂ Composites from UiO-66 Precursor under Visible Light Irritation[J]. Acta Chimica Sinica, ;2019, 77(2): 153-159. doi: 10.6023/A18090372 shu

Preparation and Photocatalytic Activity of Fe-ZrO₂ Composites from UiO-66 Precursor under Visible Light Irritation

College of Chemistry and Chemical Engineering, Northwest Normal University, Key Laboratory of Eco-Environment-Related Polymer Material of Ministry of Education, Key Laboratory of Polymer Materials of Gansu Province, Lanzhou 730070

Corresponding author: Yang Zhiwang, yangzw@nwnu.edu.cn Lei Ziqiang,
Received Date: 6 September 2018
Available Online: 10 February 2018
Fund Project: the Innovation Team Basic Scientific Research Project of Gansu Province 1606RJIA324the National Natural Science Foundation of China 21563026Project supported by the National Natural Science Foundation of China (No. 21563026), the Program for Changjiang Scholars and Innovative Research Team in University (No. IRT15R56), and the Innovation Team Basic Scientific Research Project of Gansu Province (No. 1606RJIA324)the Program for Changjiang Scholars and Innovative Research Team in University IRT15R56

Figures(10)

A new porous crystalline materials Zr-containing organic framework of UiO-66 has a large specific surface area, strong adsorption capacity, and the highly ordered arrangement of metal ions in its crystal structure. In this study, because UiO-66 has a good structural features, Fe-doped nano-ZrO₂ photocatalyst of Fe-ZrO₂ were successfully prepared by the adsorption of Fe³⁺ onto UiO-66, and calcination of the precursor of Fe³⁺/UiO-66, subsequently. The morphology and structure of the catalyst were characterized by scanning electron microscopy (SEM), X-ray diffractometry (XRD), X-ray photoelectron spectroscopy (XPS), N₂ adsorption-desorption isotherm, Fourier transform infrared spectroscopy (FT-IR) and UV-Vis absorption spectroscopy (UV-vis DRS). The electrochemical performance of the catalyst was analyzed by fluorescence (PL) and electrochemical impedance spectroscopy. Finally, the photodegradation of rhodamine B solution by the catalysis of Fe-ZrO₂ was studied. The results showed that the degradation rate of rhodamine B (RhB) under visible light irritation was 83% in 120 min with the catalyst of Fe-ZrO₂ from the calcination of the precursor Fe³⁺/UiO-66. The catalyst has a promising stability. The degradation rate to RhB could still reach 78% after three cycles.
- UiO-66,
- Fe-ZrO₂,
- visible-light photocatalysis,
- RhB,
- photodegradation
1. [1]
  Li, X. X.; Wan, T.; Qiu, J. Y.; Wei, H.; Qin, F. H.; Wang, Y. H.; Liao, Y. J.; Huang, Z. Y.; Tan, X. C. Appl. Catal. B Environ. 2017, 217, 591. doi: 10.1016/j.apcatb.2017.05.086
2. [2]
  Dhakshinamoorthy, A.; Asiri, A. M.; Garcia, H. Angew. Chem., Int. Ed. 2016, 55, 5414. doi: 10.1002/anie.201505581
3. [3]
  Zhao, K.; Zhao, S.; Gao, C.; Qi, J.; Yin, H. J.; Wei, D.; Megasia Feyissa Mideksa, Wang, X. L.; Gao, Y.; Tang, Z.Y.; Yu, R. B. Small 2018, 1800762, 1.
4. [4]
  Zhang, J.; Huang, Z. H.; Li, P. D.; Zhang, X. M.; Yuan, Y. Y.; Xu, L. Catal. Sci. Technol. 2017, 7, 2194. doi: 10.1039/C7CY00288B
5. [5]
  Eonikar, V. G.; Patil, S. S.; Tamboli, M. S.; Ambekar, J. D.; Kulkarni, M.V.; Panmand, R.; Umarji, G. G.; Shinde, M. D.; Rane, S. B.; Munirathnam, N. R.; Patil, D. R.; Kale, B. B. Phys. Chem. Chem. Phys. 2017, 19, 20541. doi: 10.1039/C7CP02328F
6. [6]
  Zhang, W.; Xu, N. W.; Yao, Z. J.; Li, K.; Zhu, Y.; Chen, L. Y.; Ye, W. L.; Deng, W. Chin. J. Org. Chem. 2016, 36, 2039.
7. [7]
  Neppolian, B.; Wang, Q.; Yamashita, H.; Choi, H. Appl. Catal. A Gen. 2007, 333, 264. doi: 10.1016/j.apcata.2007.09.026
8. [8]
  Reddy, C. V.; Babu, B.; Reddy, I. N.; Shim, J. Ceram Inter. 2018, 44, 6940. doi: 10.1016/j.ceramint.2018.01.123
9. [9]
  Jiang, W.; He, J.; Zhong, J. M.; Lu, J. Y.; Yuan, S. J.; Liang, B.; Appl. Surf. Sci. 2014, 307, 407. doi: 10.1016/j.apsusc.2014.04.047
10. [10]
  Liu, S. C. Master's Thesis, Guizhou University, 2015.
11. [11]
  Niu, Y. F.; Qian, Y.; Hu, X. D. Chin. J. Org. Chem. 2016, 36, 555.
12. [12]
  Zhang, S. F.; Yang, J. D.; Liu, M. Z.; Lü, S. Y.; Gao, C. M.; Wu, C.; Zhu, Z. Y. Acta Chim. Sinica 2016, 74, 401. doi: 10.3969/j.issn.0253-2409.2016.04.003
13. [13]
  Liu, H.; Zhang, S.; Liu, Y.; Yang, Z.; Feng, X.; Lu, X.; Huo, F. Small 2015, 11, 3130. doi: 10.1002/smll.v11.26
14. [14]
  Wang, M.; Xu, L.; Zhou, Y. N.; Liu, H.; Li, J.; Lu, X. H. J. Nanjing Univ. Technol. 2016, 38, 88.
15. [15]
  Qin, T. Y.; Zeng, Y.; Chen, J. P.; Yu, T. J.; Li, Y. Acta Chim. Sinica 2017, 75, 99.
16. [16]
  Cho, J. M.; Lee, S. R.; Sun, J.; Tsubaki, N.; Jang, E. J.; Bae, J. W. ACS Catal. 2017, 7, 5955. doi: 10.1021/acscatal.7b01989
17. [17]
  Zhao, J. K.; Ge, S. S.; Pan, D. J.; Lin, J.; Wan, Z.; Hu, Z.; Wu, T.; Guo, Z. Colloid Inter. Sci. 2018, 529, 111. doi: 10.1016/j.jcis.2018.05.091
18. [18]
  Reddy, C. V.; Reddy, I. N.; Shim, J.; Kim, D.; Yoo, K. Ceram. Int. 2018, 44, 12329. doi: 10.1016/j.ceramint.2018.04.020
19. [19]
  Li, W. H.; Nie, X. W.; Jiang, X.; Zhang, A. F.; Ding, F. S.; Liu, M.; Liu, Z. M.; Guo, X. W.; Song, C. S. Appl. Catal. B Environ. 2018, 220, 397. doi: 10.1016/j.apcatb.2017.08.048
20. [20]
  Hao, Y.; Li, L.; Liu, D.; Yu, H.; Zhou, Q. Mol. Catal. 2018, 447, 37. doi: 10.1016/j.mcat.2018.01.004
21. [21]
  An, M. Z.; Li, L.; Tian, Y.; Yu, H. L.; Zhou, Q. L. RSC Adv. 2018, 8, 18870. doi: 10.1039/C8RA00998H
22. [22]
  Yang, Z. W.; Xu, X. Q.; Liang, X. X.; Lei, C.; Gao, L.; Hao, R.; Lu, D. D.; Lei, Z. Q. Appl. Surf. Sci. 2017, 420, 276. doi: 10.1016/j.apsusc.2017.05.158
23. [23]
  Xie, H.; Lu, J.; Shekhar, M.; Elam, J. W.; Delgass, W. N.; Ribeiro, F. H.; Weitz, E.; Poeppelmeier, K. R. ACS Catal. 2013, 3, 61. doi: 10.1021/cs300596q
24. [24]
  Wang, X. X.; Zhang, L. H.; Lin, H. J.; Nong, Q. Y.; Wu, Y.; Wu, T. H.; He, Y. M. RSC Adv. 2014, 4, 40029. doi: 10.1039/C4RA06035K
25. [25]
  Xu, X. Q.; Liu, R. X.; Cui, Y. N.; Liang, X. X.; Lei, C.; Meng, S. Y.; Ma, Y. L.; Lei, Z. Q.; Yang, Z. W. Appl. Catal. B Environ. 2017, 210, 484. doi: 10.1016/j.apcatb.2017.04.021
26. [26]
  Shim, J. O.; Jang, W. J.; Jeon, K. W.; Lee, D. W.; Na, H. S.; Kim, H. M.; Lee, Y. L.; Yoo, S. Y.; Jeon, B. H.; Roh, H. S.; Ko, C. H. Appl. Catal. A Gen. 2018, 563, 163. doi: 10.1016/j.apcata.2018.07.005
27. [27]
  Shim, J. O.; Na, H. S.; Jha, A.; Jang, W. J.; Jeong, D. W.; Nah, I. W.; Jeon, B. H.; Roh, H. S. Chem. Eng. J. 2016, 306, 908. doi: 10.1016/j.cej.2016.08.030
28. [28]
  Liu, Y.; Xia, C. J.; Wang, Q.; Zhang, L.; Huang, A.; Ke, M.; Song, Z. Z. Catal. Sci. Technol. 2018, 8, 4916. doi: 10.1039/C8CY01420E
29. [29]
  Okamoto, Y.; Kubota, T.; Ohto, Y.; Nasu, S. J. Catal. 2000, 192, 412. doi: 10.1006/jcat.2000.2860
30. [30]
  Chandragiri, V. R.; Neelakanta, R. I.; Jaesool, S.; Dongseob, K.; , Yoo, K. Ceram. Int. 2018, 44, 12329. doi: 10.1016/j.ceramint.2018.04.020
31. [31]
  Yu, C.; Yang, P.; Tie, L.; Yang, S.; Dong, S.; Sun, J.; Sun, J. Appl. Surf. Sci. 2018, 455, 8. doi: 10.1016/j.apsusc.2018.04.201
32. [32]
  Mu, X. X.; Jiang, J. F.; Chao, F. F.; Lou, Y. B.; Chen, J. X. Dalton Trans. 2018, 47, 1895. doi: 10.1039/C7DT04477A
1. [1]
  Bing LIU , Huang ZHANG , Hongliang HAN , Changwen HU , Yinglei ZHANG . Visible light degradation of methylene blue from water by triangle Au@TiO₂ mesoporous catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 941-952. doi: 10.11862/CJIC.20230398
2. [2]
  Yu-Hang Li , Shuai Gao , Lu Zhang , Hanchun Chen , Chong-Chen Wang , Haodong Ji . Insights on selective Pb adsorption via O 2p orbit in UiO-66 containing rich-zirconium vacancies. Chinese Chemical Letters, 2024, 35(8): 109894-. doi: 10.1016/j.cclet.2024.109894
3. [3]
  Yurong Tang , Yunren Shi , Yi Xu , Bo Qin , Yanqin Xu , Yunfei Cai . Innovative Experiment and Course Transformation Practice of Visible-Light-Mediated Photocatalytic Synthesis of Isoquinolinone. University Chemistry, 2024, 39(5): 296-306. doi: 10.3866/PKU.DXHX202311087
4. [4]
  Ruowen Liang , Chao Zhang , Guiyang Yan . Enhancing CO2 cycloaddition through ligand functionalization: A case study of UiO-66 metal-organic frameworks. Chinese Journal of Structural Chemistry, 2024, 43(2): 100211-100211. doi: 10.1016/j.cjsc.2023.100211
5. [5]
  Bo YANG , Gongxuan LÜ , Jiantai MA . Nickel phosphide modified phosphorus doped gallium oxide for visible light photocatalytic water splitting to hydrogen. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 736-750. doi: 10.11862/CJIC.20230346
6. [6]
  Ruolin CHENG , Haoran WANG , Jing REN , Yingying MA , Huagen LIANG . Efficient photocatalytic CO₂ cycloaddition over W₁₈O₄₉/NH₂-UiO-66 composite catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 523-532. doi: 10.11862/CJIC.20230349
7. [7]
  Zhanggui DUAN , Yi PEI , Shanshan ZHENG , Zhaoyang WANG , Yongguang WANG , Junjie WANG , Yang HU , Chunxin LÜ , Wei ZHONG . Preparation of UiO-66-NH₂ supported copper catalyst and its catalytic activity on alcohol oxidation. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 496-506. doi: 10.11862/CJIC.20230317
8. [8]
  Jie Li , Huida Qian , Deyang Pan , Wenjing Wang , Daliang Zhu , Zhongxue Fang . Efficient Synthesis of Anethaldehyde Induced by Visible Light. University Chemistry, 2024, 39(4): 343-350. doi: 10.3866/PKU.DXHX202310076
9. [9]
  Yangrui Xu , Yewei Ren , Xinlin Liu , Hongping Li , Ziyang Lu . 具有高传质和亲和表面的NH₂-UIO-66基疏水多孔液体用于增强CO₂光还原. Acta Physico-Chimica Sinica, 2024, 40(11): 2403032-. doi: 10.3866/PKU.WHXB202403032
10. [10]
  Yuan Zhang , Shenghao Gong , A.R. Mahammed Shaheer , Rong Cao , Tianfu Liu . Plasmon-enhanced photocatalytic oxidative coupling of amines in the air using a delicate Ag nanowire@NH₂-UiO-66 core-shell nanostructures. Chinese Chemical Letters, 2024, 35(4): 108587-. doi: 10.1016/j.cclet.2023.108587
11. [11]
  Zhen Yao , Bing Lin , Youping Tian , Tao Li , Wenhui Zhang , Xiongwei Liu , Wude Yang . Visible-Light-Mediated One-Pot Synthesis of Secondary Amines and Mechanistic Exploration. University Chemistry, 2024, 39(5): 201-208. doi: 10.3866/PKU.DXHX202311033
12. [12]
  Qiang ZHAO , Zhinan GUO , Shuying LI , Junli WANG , Zuopeng LI , Zhifang JIA , Kewei WANG , Yong GUO . Cu₂O/Bi₂MoO₆ Z-type heterojunction: Construction and photocatalytic degradation properties. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 885-894. doi: 10.11862/CJIC.20230435
13. [13]
  Guangming YIN , Huaiyao WANG , Jianhua ZHENG , Xinyue DONG , Jian LI , Yi'nan SUN , Yiming GAO , Bingbing WANG . Preparation and photocatalytic degradation performance of Ag/protonated g-C₃N₄ nanorod materials. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1491-1500. doi: 10.11862/CJIC.20240086
14. [14]
  Shijie Li , Ke Rong , Xiaoqin Wang , Chuqi Shen , Fang Yang , Qinghong Zhang . Design of Carbon Quantum Dots/CdS/Ta₃N₅ S-Scheme Heterojunction Nanofibers for Efficient Photocatalytic Antibiotic Removal. Acta Physico-Chimica Sinica, 2024, 40(12): 2403005-. doi: 10.3866/PKU.WHXB202403005
15. [15]
  Hongbo Zhang , Yihong Tang , Suxia Zhang , Yuanting Li . Electrochemical Monitoring of Photocatalytic Degradation of Phenol Pollutants: A Recommended Comprehensive Analytical Chemistry Experiment. University Chemistry, 2024, 39(6): 326-333. doi: 10.3866/PKU.DXHX202310013
16. [16]
  Yujia LI , Tianyu WANG , Fuxue WANG , Chongchen WANG . Direct Z-scheme MIL-100(Fe)/BiOBr heterojunctions: Construction and photo-Fenton degradation for sulfamethoxazole. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 481-495. doi: 10.11862/CJIC.20230314
17. [17]
  Kexin Dong , Chuqi Shen , Ruyu Yan , Yanping Liu , Chunqiang Zhuang , Shijie Li . Integration of Plasmonic Effect and S-Scheme Heterojunction into Ag/Ag₃PO₄/C₃N₅ Photocatalyst for Boosted Photocatalytic Levofloxacin Degradation. Acta Physico-Chimica Sinica, 2024, 40(10): 2310013-. doi: 10.3866/PKU.WHXB202310013
18. [18]
  Shiqi Peng , Yongfang Rao , Tan Li , Yufei Zhang , Jun-ji Cao , Shuncheng Lee , Yu Huang . Regulating the electronic structure of Ir single atoms by ZrO₂ nanoparticles for enhanced catalytic oxidation of formaldehyde at room temperature. Chinese Chemical Letters, 2024, 35(7): 109219-. doi: 10.1016/j.cclet.2023.109219
19. [19]
  Kun WANG , Wenrui LIU , Peng JIANG , Yuhang SONG , Lihua CHEN , Zhao DENG . Hierarchical hollow structured BiOBr-Pt catalysts for photocatalytic CO₂ reduction. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1270-1278. doi: 10.11862/CJIC.20240037
20. [20]
  Lijuan Liu , Xionglei Wang . Preparation of Hydrogels from Waste Thermosetting Unsaturated Polyester Resin by Controllable Catalytic Degradation: A Comprehensive Chemical Experiment. University Chemistry, 2024, 39(11): 313-318. doi: 10.12461/PKU.DXHX202403060

Get Citation

PDF

XML

Metrics

PDF Downloads(69)
Abstract views(4764)
HTML views(1530)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Preparation and Photocatalytic Activity of Fe-ZrO2 Composites from UiO-66 Precursor under Visible Light Irritation

Metrics

通讯作者: 陈斌, bchen63@163.com

Preparation and Photocatalytic Activity of Fe-ZrO₂ Composites from UiO-66 Precursor under Visible Light Irritation