Citation: Wang Yilin, Wang Minjie, Li Jing, Wei Zidong. Iron/nickel Alloy Nanoparticles Embedded in N-doped Porous Carbon for Robust Oxygen Evolution Reaction[J]. Acta Chimica Sinica, ;2019, 77(1): 84-89. doi: 10.6023/A18080357 shu

Iron/nickel Alloy Nanoparticles Embedded in N-doped Porous Carbon for Robust Oxygen Evolution Reaction

School of Chemistry and Chemical Engineering, Chongqing University, Chongqing 400044

Corresponding author: Li Jing, lijing@cqu.edu.cn Wei Zidong, zdwei@cqu.edu.cn
Received Date: 30 August 2018
Available Online: 27 January 2018
Fund Project: the National Key Research and Development Program of China 2016YFB0101202Project supported by the National Key Research and Development Program of China (No. 2016YFB0101202) and the National Natural Science Foundation of China (Nos. 91534205, 21436003)the National Natural Science Foundation of China 91534205the National Natural Science Foundation of China 21436003

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Hydrogen, a clean, efficient and sustainable energy, can be produced via electrochemical water splitting, during which two key processes, hydrogen evolution reaction (HER) and oxygen evolution reaction (OER), occur simultaneously at the two electrodes of an electrolytic cell. Nevertheless compared to the two-electron process of HER, OER, a four-electron process, is of the inherently kinetic hysteresis step, which can dramatically diminish the overall energy conversion efficiency. The highly active noble-metal-based catalyst RuO₂ is considered to be one of the most efficient state-of-the-art OER catalysts. However the high cost and element scarcity significantly hinder their practical applications. Thus it is particularly urgent to develop highly-active but low-cost non-noble-metal alternatives. Iron/nickel alloy based catalysts have been widely studied owing to their promising performances. In this work, we prepared iron/nickel alloy nanoparticles embedded in N-doped hierarchically porous carbon (Fe_0.64Ni_0.36@NC), by simultaneously adsorbing metal precursors and dopamine on surface of SiO₂ macroporous hard templates, and then annealing the system and etching the templates. In electrochemical measurements, Fe_0.64Ni_0.36@NC shows a superior OER activity in alkaline solution, which only needs an overpotential as low as 286 mV to deliver a current density of 10 mA·cm^-2, being significantly lower than the value of 380 mV for RuO₂. Besides, the catalyst displays no obvious activity decrease after 2000 cycles of continuous CV scanning, corresponding to an excellent durability. The observed nice performances of the alloy catalyst in alkaline solution can be ascribed to two critical structural features:(1) the macroporous structures made by stacking of SiO₂ microspheres own relatively thin layer of carbon framework, thus the embedded iron/nickel alloy particles can well activate the surrounding carbon layer to expose copious active sites; (2) the graphitized N-doped carbon layers well protect the alloy nanoparticles from corrosion, thus improving the durability of the catalysts. This work gave a nice design for the highly efficient non-noble-metal OER catalysts.
- N-doped porous carbon,
- iron/nickel alloys,
- oxygen evolution reaction
1. [1]
  Armaroli, N.; Balzani, V. Angew. Chem., Int. Ed. 2007, 46, 52. doi: 10.1002/(ISSN)1521-3773
2. [2]
  Ding, W.; Zhang, X.; Li, L.; Wei, Z. D. J. Electrochem. 2014, 20, 426 (in Chinese).
3. [3]
  Peng, L. S.; Wei, Z. D. Chinese J. Catal. 2018, 39, 1575 (in Chinese).
4. [4]
  Villa, I.; Villa, C.; Monguzzi, A.; Babin, V.; Tervoort, E.; Nikl, M.; Niederberger, M.; Torrente, Y.; Vedda, A.; Lauria, A. Nanoscale 2018, 10, 7933. doi: 10.1039/C8NR00724A
5. [5]
  Zhang, C.; Zhang, M. R.; Shi, H. Y.; Wang, J. P.; Niu, J. Y. Chem. Commun. 2018, 54, 5458. doi: 10.1039/C8CC01622D
6. [6]
  Guo, Y.; Yao, Y.; Li, H.; He, L. L.; Yang, Z. Z.; Zhao, D. X. Acta Chim. Sinica 2017, 75, 903 (in Chinese). doi: 10.3866/PKU.WHXB201702091
7. [7]
  Zuo, L. X.; Jiang, L.; Zhu, J. J. Chin. J. Chem. 2017, 35, 969. doi: 10.1002/cjoc.v35.6
8. [8]
  Zou, X.; Zhang, Y. Chem. Soc. Rev. 2015, 44, 5148. doi: 10.1039/C4CS00448E
9. [9]
  Wang, S. L.; Wang, L. P.; Zhang, Z. H. Acta Phys.-Chim. Sin.2013, 29, 981 (in Chinese). doi: 10.3866/PKU.WHXB201303071
10. [10]
  Wang, J.; Wei, Z. D. Acta Phys.-Chim. Sin. 2017, 33, 886 (in Chinese). doi: 10.3866/PKU.WHXB201702092
11. [11]
  Peng, L. S.; Wei, Z. D. Prog. Chem. 2018, 30, 14 (in Chinese). doi: 10.7536/PC170912
12. [12]
  Luo, J. L. Acta Phys.-Chim. Sin. 2018, 34, 7 (in Chinese). doi: 10.3866/PKU.WHXB201707051
13. [13]
  Zhang, Y.; Shimoda, K.; Miyaoka, H. Int. J. Hydrogen Energy 2010, 35, 12405. doi: 10.1016/j.ijhydene.2010.08.018
14. [14]
  Hinnemann, B.; Moses, P. G.; Bonde, J.; Jorgensen, K. P.; Nielsen, J. H. J. Am. Chem. Soc. 2005, 127, 5308. doi: 10.1021/ja0504690
15. [15]
  Lee, Y.; Jin, S.; May, K. J.; Perry, E. E.; Yang, S. H. J. Phys. Chem. Lett. 2012, 3, 399. doi: 10.1021/jz2016507
16. [16]
  Over, H. Chem. Rev. 2012, 43, 3356.
17. [17]
  Liu, T. T.; Xie, L. S.; Yang, J. H.; Kong, R. M.; Sun, X. P.; Chen, L. ChemElectroChem 2017, 4, 1840. doi: 10.1002/celc.v4.8
18. [18]
  Fang, Y. H.; Liu, Z. P. J. Am. Chem. Soc. 2010, 132, 18214. doi: 10.1021/ja1069272
19. [19]
  Fang, Z.; Peng, L.; Zhu, Y.; Yan, C.; Wang, S.; Kalyani, P.; Wu, X.; Yu, G. ACS Nano 2017, 11, 9550. doi: 10.1021/acsnano.7b05481
20. [20]
  Feng, J. X.; Xu, H.; Dong, Y. T.; Ye, S. H.; Tong, Y. X.; Li, G. R. Angew. Chem., Int. Ed. 2016, 128, 3758. doi: 10.1002/ange.201511447
21. [21]
  Ji, Y. Y.; Li, Y.; Ren, X.; Cui, G. W.; Xiong, X. L.; Sun, X. P. ACS Sustain. Chem. Eng. 2018, 6, 9555. doi: 10.1021/acssuschemeng.8b01841
22. [22]
  Yang, J.; Zhu, G.; Liu, Y.; Xia, J.; Ji, Z.; Shen, X. Adv. Funct. Mater. 2016, 26, 4712. doi: 10.1002/adfm.v26.26
23. [23]
  Gao, M.; Sheng, W.; Zhuang, Z.; Fang, Q.; Gu, S.; Jiang, J.; Yan, Y. J. Am. Chem. Soc. 2014, 136, 7077. doi: 10.1021/ja502128j
24. [24]
  Chuan, T. Y.; Chun, Z. H. Chem. Commun. 2016, 52, 11591. doi: 10.1039/C6CC05699G
25. [25]
  Hoare, J. P.; Schuldiner, S. J. Phys. Chem. 2002, 62, 229.
26. [26]
  Tang, T.; Jiang, W. J.; Niu, S.; Liu, N.; Luo, H.; Chen, Y. Y.; Jin, S. F.; Gao, F.; Wan, L. J. J. Am. Chem. Soc. 2017, 139, 8320. doi: 10.1021/jacs.7b03507
27. [27]
  Li, F. L.; Shao, Q.; Huang, X.; Lang, J. P. Angew. Chem., Int. Ed. 2018, 57, 1888. doi: 10.1002/anie.201711376
28. [28]
  Chemelewski, W. D.; Rosenstock, J. R.; Mullins, C. B. J. Mater. Chem. 2014, 2, 14957. doi: 10.1039/C4TA03078H
29. [29]
  He, Y. H.; Xu, J. M.; Wang, N. Chem. Eng. Prog. 2016, 35, 2057 (in Chinese).
30. [30]
  Landon, J.; Demeter, E.; İnoğlu, N.; Keturakis, C.; Wachs, I. E.; Frenkel, A. I. ACS Catal. 2012, 2, 1793. doi: 10.1021/cs3002644
31. [31]
  Gong, M.; Li, Y.; Wang, H.; Liang, Y.; Wu, J. Z.; Zhou, J.; Wang, J.; Regier, T.; Wei, F. J. Am. Chem. Soc. 2013, 135, 8452. doi: 10.1021/ja4027715
32. [32]
  Trotochaud, L.; Young, S. L.; Ranney, J. K. J. Am. Chem. Soc. 2014, 136, 6744. doi: 10.1021/ja502379c
33. [33]
  Smith, A. M.; Trotochaud, L.; Burke, M. S.; Boettcher, S. W. Chem. Commun. 2015, 51, 5261. doi: 10.1039/C4CC08670H
34. [34]
  Yang, Y.; Zhuang, L.; Lin, R.; Li, M.; Xu, X.; Rufford, T. E.; Zhu, Z. J. Power Sources 2017, 349, 68. doi: 10.1016/j.jpowsour.2017.03.028
35. [35]
  Liang, Y.; Liu, Q.; Asiri, A. M.; Sun, X.; He, Y. Int. J. Hydrogen Energy 2015, 40, 13258. doi: 10.1016/j.ijhydene.2015.07.165
36. [36]
  Zhao, Y.; Chen, S.; Sun, B.; Su, D.; Huang, X.; Liu, H.; Yan, Y.; Sun, K.; Wang, G. Sci. Rep. 2015, 5, 7629. doi: 10.1038/srep07629
37. [37]
  Ma, T. Y.; Dai, S.; Jaroniec, M.; Qiao, S. Z. J. Am. Chem. Soc. 2014, 136, 13925. doi: 10.1021/ja5082553
38. [38]
  Yang, Y.; Lin, Z.; Gao, S.; Su, J.; Lun, Z.; Xia, G. ACS Catal. 2017, 7, 469. doi: 10.1021/acscatal.6b02573
39. [39]
  Tavakkoli, M.; Kallio, T.; Reynaud, O.; Nasibulin, A. G.; Johans, C.; Sainio, J.; Jiang, H.; Kauppinen, E. I.; Laasonen, K. Angew. Chem., Int. Ed. 2015, 54, 4535. doi: 10.1002/anie.201411450
40. [40]
  Tao, Z.; Wang, T.; Wang, X.; Zheng, J.; Li, X. ACS Appl. Mater. Interfaces 2016, 8, 35390. doi: 10.1021/acsami.6b13411
41. [41]
  Liu, Z.; Sun, F.; Gu, L.; Chen, G.; Shang, T.; Liu, J.; Le, Z.; Li, X.; Wu, H. B.; Lu, Y. Adv. Energy Mater. 2017, 7, 1701154. doi: 10.1002/aenm.201701154
42. [42]
  Guo, Y.; Liu, Y.; Qi, J. J.; Li, H.; He, L. L. Acta Chim. Sinica 2017, 75, 914 (in Chinese).
43. [43]
  Bao, J. Z.; Wang, S. L. Acta Phys.-Chim. Sin. 2011, 27, 2849 (in Chinese). doi: 10.3866/PKU.WHXB20112849
44. [44]
  Yang, Q. Q.; Liu, L.; Xiao, L.; Wang, M. J.; Li, J.; Wei, Z. D. J. Mater. Chem. A 2018, 6, 14752. doi: 10.1039/C8TA03604G
45. [45]
  Ma, Y. D.; Dai, X. P.; Liu, M. Z.; Zhang, X. ACS Appl. Mater. Interfaces 2016, 8, 34396. doi: 10.1021/acsami.6b11821
46. [46]
  Wu, Y.; Chen, M.; Han, Y.; Luo, H.; Su, X.; Zhang, M. T.; Lin, X.; Sun, J.; Wang, L.; Deng, L.; Zhang, W.; Cao, R. Angew. Chem., Int. Ed. 2015, 54, 4870. doi: 10.1002/anie.201412389
47. [47]
  Zhang, B.; Xiao, C.; Xie, S.; Liang, J.; Chen, X.; Tang, Y. Chem. Mater. 2016, 28, 6934. doi: 10.1021/acs.chemmater.6b02610
48. [48]
  Han, X.; Yu, C.; Zhou, S.; Zhao, C.; Huang, H.; Yang, J.; Liu, Z.; Zhao, J.; Qiu, J. Adv. Energy Mater. 2017, 7, 1602148. doi: 10.1002/aenm.201602148
49. [49]
  Wu, G.; Li, N.; Dai, C. S.; Zhou, D. R. Chinese J. Catal. 2004, 25, 319 (in Chinese). doi: 10.3321/j.issn:0253-9837.2004.04.016
50. [50]
  Stöber, W.; Fink, A.; Bohn, E. J. Colloid Interface Sci. 1968, 26, 62. doi: 10.1016/0021-9797(68)90272-5
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