Citation: Jin Weize, Lu Guolin, Li Yongjun, Huang Xiaoyu. Recent Advances in Fluorine-containing Materials with Extreme Environment Resistance[J]. Acta Chimica Sinica, ;2018, 76(10): 739-748. doi: 10.6023/A18080340 shu

Recent Advances in Fluorine-containing Materials with Extreme Environment Resistance

Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032

Corresponding author: Huang Xiaoyu, xyhuang@sioc.ac.cn
Received Date: 17 August 2018
Available Online: 11 October 2018
Fund Project: Shanghai Scientific and Technological Innovation Project 17DZ1205400Project supported by the National Major Scientific Research Project (No. 2015CB931900), the National Science Fund for Distinguished Young Scholars (No. 51825304), the National Major Natural Science Foundation Project (No. 21632009), National Natural Science Foundation Project (Nos. 21674124, 51773222, 51773223), Special Science and Technology Pilot Program of Chinese Academy of Sciences (Class B) (No. XDB20000000), Shanghai Major Basic Research Project (No. 18JC1410600) and Shanghai Scientific and Technological Innovation Project (No. 17DZ1205400)the National Major Natural Science Foundation Project 21632009National Natural Science Foundation Project 51773222the National Science Fund for Distinguished Young Scholars 51825304National Natural Science Foundation Project 21674124Special Science and Technology Pilot Program of Chinese Academy of Sciences (Class B) XDB20000000National Natural Science Foundation Project 51773223Shanghai Major Basic Research Project 18JC1410600the National Major Scientific Research Project 2015CB931900

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The extreme environment resistance materials can be normally used under severe conditions (e.g. T ≤ -50℃ or T ≥ 200℃, 1000 h exposed to UV light etc.), which common hydrocarbon materials cannot tolerate. It was found that fluorine atoms can effectively enhance the extreme environment resistance property of materials. The reason why fluorine atoms have such ability is mainly due to two key factors:first, fluorine and carbon elements are in the same cycle of the periodic table, the electronegativity of fluorine is large (4.0) and its atomic radius is small; second, polarization of fluorine atom is extremely low. The C-F bond is the strongest chemical single bond (≥ 116 kcal/mol) in which the carbon atom participates. It is a short bond and highly polarized. This paper makes brief introduction to the development and present situation of fluorine-containing materials with extreme environment resistance. In the field of fluorination methods, the history of fluorine chemistry since 1970s, the researches on the formation and fracture of carbon-fluorine bond, the influence of fluorine on the formation of carbon-carbon bond and the related researches on polyfluoro-arylation methods are introduced. This paper also introduces the important results of fluorine-containing materials in lithium isotope extraction, thermo-stable fluoropolymers which can be applied in aviation, aerospace, automobile and other fields, as well as the preparation of high-performance fluorine-containing materials with low dielectric constant in electronic equipment and communication fields. In the future, how to further develop and optimize the fluorine-containing materials with extreme environment resistance and put the research results into large-scale use is the working direction for researchers.
- extreme environment resistance,
- fluorine-containing material,
- nanomaterial,
- polymer,
- synthesis
1. [1]
  Bai, C. L.; Liu, M. H. Angew. Chem., Int. Ed. 2013, 52, 2678. doi: 10.1002/anie.201210058
2. [2]
  Hiyama, T. ; Kanie, K. ; Kusumoto, T. ; Morizawa, Y. ; Shimizu, M. Organofluorine Compounds: Chemistry and Applications, Springer, New York, 2000, pp. 1~272.
3. [3]
  Uneyama, K. Organofluorine Chemistry, Blackwell, Oxford, 2006, pp. 1~337.
4. [4]
  Sharpless, K. B. Efficient Preparations of Fluorine Compounds, Wiley, Hoboken, 2013, pp. I~XI.
5. [5]
  Shibata, N.; Matsnev, A.; Cahard, D. Beilstein J. Org. Chem. 2010, 6, 65.
6. [6]
  Hintermann, L.; Togni, A. Angew. Chem., Int. Ed. 2000, 39, 4359. doi: 10.1002/(ISSN)1521-3773
7. [7]
  Chen, Q. Y.; Duan, J. X. Tetrahedron Lett. 1993, 34, 4241. doi: 10.1016/S0040-4039(00)60538-5
8. [8]
  Su, D. B.; Duan, J. X.; Chen, Q. Y. Tetrahedron Lett. 1991, 32, 7689. doi: 10.1016/0040-4039(91)80566-O
9. [9]
  Grushin, V. V. Acc. Chem. Res. 2010, 43, 160. doi: 10.1021/ar9001763
10. [10]
  Cho, E. J.; Senecal, T. D.; Kinzel, T.; Zhang, Y.; Watson, D. A.; Buchwald, S. L. Science 2010, 328, 1679. doi: 10.1126/science.1190524
11. [11]
  Wang, X. S.; Mei, T. S.; Yu, J. Q. J. Am. Chem. Soc. 2009, 131, 7520. doi: 10.1021/ja901352k
12. [12]
  Hull, K. L.; Anani, W. Q.; Sanford, M. S. J. Am. Chem. Soc. 2006, 128, 7134. doi: 10.1021/ja061943k
13. [13]
  Furuya, T.; Kuttruff, C. A.; Ritter, T. Curr. Opin. Drug Discov. Devel. 2008, 11, 803.
14. [14]
  Tang, P.; Furuya, T.; Ritter, T. J. Am. Chem. Soc. 2010, 132, 12150. doi: 10.1021/ja105834t
15. [15]
  Sun, H.; Dimagno, S. G. Angew. Chem., Int. Ed. 2006, 45, 2720. doi: 10.1002/(ISSN)1521-3773
16. [16]
  Anbarasan, P.; Neumann, H.; Beller, M. Angew. Chem., Int. Ed. 2010, 49, 2219. doi: 10.1002/anie.v49:12
17. [17]
  Barker, T. J.; Boger, D. L. J. Am. Chem. Soc. 2012, 134, 13588. doi: 10.1021/ja3063716
18. [18]
  Liu, W.; Huang, X. Y.; Cheng, M. J.; Nielsen, R. J.; William, A. G. I.; Groves, J. T. Science 2012, 337, 1322. doi: 10.1126/science.1222327
19. [19]
  Yin, F.; Wang, Z.; Li, Z., Li, C. J. Am. Chem. Soc. 2012, 134, 10401. doi: 10.1021/ja3048255
20. [20]
  Chen, H.; Wang, X.; Guo, M.; Zhao, W.; Tang, X.; Wang, G. Org. Chem. Front. 2017, 4, 2403. doi: 10.1039/C7QO00611J
21. [21]
  Zhou, N.; Xu, P.; Li, W.; Cheng, Y.; Zhu, C. Acta Chim. Sinica 2017, 75, 60(in Chinese).
22. [22]
  Amii, H.; Uneyana, K. Chem. Rev. 2009, 109, 2119. doi: 10.1021/cr800388c
23. [23]
  Aizenberg, M.; Milstein, D. Science 1994, 265, 359. doi: 10.1126/science.265.5170.359
24. [24]
  Peterson, A. A.; McNeill, K. Organometallics 2006, 25, 4938. doi: 10.1021/om0607292
25. [25]
  Ishii, Y.; Chatani, N.; Yorimitsu, S.; Murai, S. Chem. Lett. 1998, 27, 157. doi: 10.1246/cl.1998.157
26. [26]
  Bohm, V. P. W.; Gstottmayr, C. W. K.; Weskamp, T.; Herrmann, W. A. Angew. Chem., Int. Ed. 2001, 40, 3387. doi: 10.1002/(ISSN)1521-3773
27. [27]
  Braun, T.; Perutz, R. N.; Sladek, M. I. Chem. Commun. 2001, 21, 2254.
28. [28]
  Mongin, F.; Mojovic, L.; Guillamet, B.; Trecourt, C. F.; Queguiner, G. J. Org. Chem. 2002, 67, 8991. doi: 10.1021/jo026136s
29. [29]
  Schaub, T.; Backes, M.; Radius, U. J. Am. Chem. Soc. 2006, 128, 15964. doi: 10.1021/ja064068b
30. [30]
  Widdowson, D. A.; Wilhelm, R. Chem. Commun. 2000, 1, 2211.
31. [31]
  Kim, Y.; Yu, S. J. Am. Chem. Soc. 2003, 125, 1696. doi: 10.1021/ja028966t
32. [32]
  Cargill, M. R.; Sanford, G.; Tadeusiak, A. J.; Yufit, D. S.; Howard, J. A.; Kilickiran, P.; Nelles, G. J. Org. Chem. 2010, 75, 5860. doi: 10.1021/jo100877j
33. [33]
  Mikami, K.; Miyamoto, T.; Hatano, M. Chem. Commun. 2004, 2082.
34. [34]
  Douvris, C.; Ozerov, O. V. Science 2008, 321, 1188. doi: 10.1126/science.1159979
35. [35]
  Grushin, V. V.; Marshall, W. J. J. Am. Chem. Soc. 2006, 128, 12644. doi: 10.1021/ja064935c
36. [36]
  Grushin, V. V.; Marshall, W. J. J. Am. Chem. Soc. 2006, 128, 19880.
37. [37]
  Watson, D. A.; Su, M.; Teverovskiy, G.; Zhang, Y.; García-Fortanet, J.; Kinzel, T.; Buchwald, S. L. Science 2009, 325, 1661. doi: 10.1126/science.1178239
38. [38]
  Chu, L. L.; Qing, F. L. J. Am. Chem. Soc. 2010, 132, 7262. doi: 10.1021/ja102175w
39. [39]
  Chu, L. L.; Qing, F. L. Org. Lett. 2010, 12, 5060. doi: 10.1021/ol1023135
40. [40]
  Liu, T. F.; Shen, Q. L. Org. Lett. 2011, 13, 2342. doi: 10.1021/ol2005903
41. [41]
  Liu, T. F.; Shao, X. X.; Wu, Y. M.; Shen, Q. L. Angew. Chem., Int. Ed. 2012, 51, 540. doi: 10.1002/anie.201106673
42. [42]
  Prakash, G. K. S.; Hu, J. B. Acc. Chem. Res. 2007, 40, 921. doi: 10.1021/ar700149s
43. [43]
  Zhao, Y. C.; Huang, W. Z.; Zhu, L. G.; Hu, J. B. Org. Lett. 2010, 12, 1444. doi: 10.1021/ol100090r
44. [44]
  Zhou, Q. H.; Ruffoni, A.; Gianatassio, R.; Fujiwara, Y.; Sella, E.; Shabat, D.; Baran, P. S. Angew. Chem., Int. Ed. 2013, 52, 3949. doi: 10.1002/anie.v52.14
45. [45]
  Rong, J.; Ni, C.; Wang, Y.; Kuang, C.; Gu, Y.; Hu, J. Acta Chim. Sinica 2017, 75, 105(in Chinese).
46. [46]
  Lafrance, M.; Rowley, C. N.; Woo, T. K.; Fagnou, K. J. Am. Chem. Soc. 2006, 128, 8754. doi: 10.1021/ja062509l
47. [47]
  Do, H. Q.; Daugulis, O. J. Am. Chem. Soc. 2008, 130, 1128. doi: 10.1021/ja077862l
48. [48]
  He, C. Y.; Fan, S. L.; Zhang, X. G. J. Am. Chem. Soc. 2010, 132, 12850. doi: 10.1021/ja106046p
49. [49]
  Zhang, X. G.; Fan, S. L.; He, C. Y.; Wan, X.; Min, Q. Q.; Yang, J.; Jiang, Z. X. J. Am. Chem. Soc. 2010, 132, 4506. doi: 10.1021/ja908434e
50. [50]
  Zeng, Y. W.; Zhang, L. J.; Zhao, Y. C.; Ni, C. F.; Zhao, J. W.; Hu, J. B. J. Am. Chem. Soc. 2013, 135, 2955. doi: 10.1021/ja312711c
51. [51]
  Wang, X.; Xu, Y.; Mo, F.; Ji, G. J.; Qiu, D.; Feng, J. J.; Ye, Y. X.; Zhang, S. N.; Zhang, Y.; Wang, J. B. J. Am. Chem. Soc. 2013, 135, 10330. doi: 10.1021/ja4056239
52. [52]
  Dai, J. J.; Fang, C.; Xiao, B.; Yi, J.; Xu, J.; Liu, Z. J.; Lu, X.; Liu, L.; Fu, Y. J. Am. Chem. Soc. 2013, 135, 8436. doi: 10.1021/ja404217t
53. [53]
  Lewis, G. N.; Macdonald, R. T. J. Am. Chem. Soc. 1936, 58, 2519. doi: 10.1021/ja01303a045
54. [54]
  Jeon, Y. S.; Jang, N. H.; Kang, B. M.; Jeon, Y. S.; Kim, C. S.; Chio, K. Y.; Ryu, H. Bull. Korean Chem. Soc. 2007, 28, 451. doi: 10.5012/bkcs.2007.28.3.451
55. [55]
  Kim, D. W. J. Radioanal. Nucl. Chem. 2002, 252, 559. doi: 10.1023/A:1015815123149
56. [56]
  Takahashi, H.; Zhang, Y. H.; Miyajima, T.; Oi, T. J. Mater. Chem. 2006, 16, 1462. doi: 10.1039/B514857J
57. [57]
  Kim, D. W.; Kang, B. M.; Jeon, B. K.; Joen, Y. S. J. Radioanal. Nucl. Chem. 2003, 256, 81. doi: 10.1023/A:1023352126261
58. [58]
  Araki, H.; Umeda, M.; Enokida, Y.; Yamamoto, I. Fusion. Eng. Des. 1998, 39, 1009.
59. [59]
  Otake, K.; Suzuki, T.; Kim, H. J.; Nomura, M.; Fujii, Y. J. Nucl. Sci. Technol. 2006, 43, 419. doi: 10.1080/18811248.2006.9711115
60. [60]
  Black, J. R.; Umeda, G.; Dunn, B.; Mcdonough, W. F.; Kavner, A. J. Am. Chem. Soc. 2009, 131, 9904. doi: 10.1021/ja903926x
61. [61]
  Saleem, M.; Hussain, S.; Rafiq, M.; Baig, M. A. J. Appl. Phys. 2006, 100, 053111-1.
62. [62]
  Olivares, I. E.; Duarte, A. E.; Saravia, E. A.; Duarte, F. J. Appl. Opt. 2002, 41, 2973. doi: 10.1364/AO.41.002973
63. [63]
  Shanghai Institute of Organic Chemistry, CAS. ZL2012104371552, 2012.
64. [64]
  Hu, J. B. ; Zhang, W. ; Zheng, W. Q. ; Chen, G. H. ; Shi, X. ; Xu, Y. C. ; Lv, H. G. ; Yuan, C. Y. ZL201310239535X, 2013.
65. [65]
  Hu, J. B. ; Zhang, W. ; Zheng, W. Q. ; Shi, X. ; Xu, Y. C. ; Lv, H. G. ; Yuan, C. Y. ZL2013102395326, 2013.
66. [66]
  Shanghai Institute of Organic Chemistry, CAS. PCT/CN2013/075340, 2013.
67. [67]
  Hu, J. B. ; Zhang, W. ; Zheng, W. Q. ; Chen, G. H. ; Shi, X. ; Xu, Y. C. ; Lv, H. G. ; Yuan, C. Y. PCT/CN2014/074304, 2014.
68. [68]
  Hu, J. B. ; Zhang, W. ; Xu, Y. C. ; Gu, H. X. CN2017103408158, 2017.
69. [69]
  Hu, J. B. ; Zhang, W. ; Zhang, L. J. CN2017103398796, 2017.
70. [70]
  Hu, J. B. ; Zhang, W. ; Gu, H. X. Zheng, W. Q. CN2017103398917, 2017.
71. [71]
  Hu, J. B. ; Zhang, W. ; Zheng, W. Q. Xu, Y. C. CN2017103398936, 2017.
72. [72]
  Mahl, A.; Lim, A.; Latta, J.; Yemam, H. A.; Greife, U.; Sellinger, A. Nucl. Instrum. Methods Phys. Res. A 2018, 884, 113. doi: 10.1016/j.nima.2017.11.091
73. [73]
  Babb, D. A.; Ezzell, B. R.; Clement, K. S.; Richey, W. F.; Kennedy, A. P. J. Polym. Sci. Polym. Chem. 1993, 31, 3465. doi: 10.1002/pola.1993.080311336
74. [74]
  Zhu, Y. Q.; Huang, Y. G.; Meng, W. D.; Li, H.; Qing, F. L. Polymer 2006, 47, 6272. doi: 10.1016/j.polymer.2006.06.066
75. [75]
  Yao, R. X.; Kong, L.; Yin, Z. S.; Qing, F. L. J. Fluorine Chem. 2008, 129, 1003. doi: 10.1016/j.jfluchem.2008.04.012
76. [76]
  Li, Y. J.; Chen, S.; Zhang, S.; Li, Q. N.; Lu, G. L.; Li, W. X.; Liu, H.; Huang, X. Y. Polymer 2009, 50, 5192. doi: 10.1016/j.polymer.2009.09.018
77. [77]
  Wang, Q.; Yu, X.; Jin, J.; Wu, Y.; Liang, Y. Chin. J. Chem. 2018, 36, 223. doi: 10.1002/cjoc.v36.3
78. [78]
  Watanabe, Y.; Shibasaki, Y.; Ando, S.; Ueda, M. Polym J. 2006, 38, 79. doi: 10.1295/polymj.38.79
79. [79]
  Towery, D.; Fury, M. A. J. Electron. Mater. 1998, 27, 1088. doi: 10.1007/s11664-998-0142-z
80. [80]
  Tsuchiya, K.; Shibasaki, Y.; Aoyagi, M.; Ueda, M. Macromolecules 2006, 39, 3964. doi: 10.1021/ma0521607
81. [81]
  Niu, Y. M.; Zhu, X. L.; Liu, L. Z.; Zhang, Y.; Wang, G. B.; Jiang, Z. H. React. Funct. Polym. 2006, 66, 559. doi: 10.1016/j.reactfunctpolym.2005.10.009
82. [82]
  Dang, T. D.; Mather, P. T.; Alexander, M. D.; Grayson, C. J.; Houtz, M. D.; Spry, R. J.; Arnold, F. E. J. Polym. Sci. Polym. Chem. 2000, 38, 1991. doi: 10.1002/(ISSN)1099-0518
83. [83]
  Fukukawa, K.; Shibasakl, Y.; Ueda, M. Macromolecules 2004, 37, 8256. doi: 10.1021/ma049063i
84. [84]
  Su, Y. C.; Chang, F. C. Polymer 2003, 44, 7989. doi: 10.1016/j.polymer.2003.10.026
85. [85]
  Sharangpani, R.; Singh, R. Rev. Sci. Instrum. 1997, 68, 1564. doi: 10.1063/1.1147926
86. [86]
  Rosenmeyer, C. T.; Wu, H. MRS Proceedings 1996, 427, 463. doi: 10.1557/PROC-427-463
87. [87]
  Luo, Y. J.; Jin, K. K.; He, C. Q.; Wang, J. J.; Sun, J.; He, F. K.; Zhou, J. F.; Wang, Y. Q.; Fang, Q. Macromolecules 2016, 49, 7314. doi: 10.1021/acs.macromol.6b01678
88. [88]
  Wang, J. J.; Sun, J.; Zhou, J. F.; Jin, K. K.; Fang, Q. ACS Appl. Mater. Interfaces 2017, 9, 12782. doi: 10.1021/acsami.7b01415
89. [89]
  Wang, J. J.; Zhou, J. F.; Jin, K. K.; Wang, L.; Sun, J.; Fang, Q. Macromolecules 2017, 50, 9394. doi: 10.1021/acs.macromol.7b02000
90. [90]
  Zhao, Z.; Ni, H.; Han, Z.; Jiang, T.; Xu, Y.; Lu, X.; Ye, P. ACS Appl. Mater. Interfaces 2013, 5, 7808. doi: 10.1021/am401568b
91. [91]
  Cheng, Y. Acta Polym. Sinica 2017, 8, 1234.
92. [92]
  Jha, S. K.; Mishra, V. K.; Sharma, D. K.; Damodaran, T. Rev. Environ. Contam. Toxicol. 2011, 211, 121.
93. [93]
  Lau, C.; Butenhoff, J. L.; Rogers, J. M. Toxicol. Appl. Pharm. 2004, 198, 231. doi: 10.1016/j.taap.2003.11.031
94. [94]
  Dewitt, J. C.; Shnyra, A.; Badr, M. Z.; Loveless, S. E.; Hoban, D.; Frame, S. R.; Cunard, R.; Anderson, S. E.; Meade, B. J.; Peden-Adams, M. M.; Luebke, R. W.; Luster, M. I. Crit. Rev. Toxicol. 2009, 39, 76. doi: 10.1080/10408440802209804
95. [95]
  Younglai, E. V.; Wu, Y. J.; Foster, W. G. Curr. Pharm. Design 2007, 13, 3005. doi: 10.2174/138161207782110499
96. [96]
  Yao, W. Q.; Li, Y. J.; Huang, X. Y. Polymer 2014, 55, 6197. doi: 10.1016/j.polymer.2014.09.036
97. [97]
  Tong, L.; Shen, Z.; Zhang, S.; Li, Y. J.; Lu, G. L.; Huang, X. Y. Polymer 2008, 49, 4534. doi: 10.1016/j.polymer.2008.08.033
98. [98]
  Wang, X.; Cheng, W. G.; Yang, Q. Y.; Niu, H. Y.; Liu, Q.; Liu, Y.; Gao, M.; Xu, M.; Xu, A.; Liu, S. J.; Huang, X. Y.; Du, Y. G. J. Environ. Sci. 2018, 69, 217. doi: 10.1016/j.jes.2017.10.014
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2. [2]
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沈阳化工大学材料科学与工程学院沈阳 110142