Citation: Luo Jianxin, Yan Wenhai, Ma Qing, Zhang Chunyan, Fang Yiquan, Zhang Xucheng, Wang Changchun. Study on High Activity Monodispersed Sulfonated Porous Polystyrene Microspheres for Preparation of Biodiesel[J]. Acta Chimica Sinica, ;2019, 77(1): 54-59. doi: 10.6023/A18080335 shu

Study on High Activity Monodispersed Sulfonated Porous Polystyrene Microspheres for Preparation of Biodiesel

a.
Department of Materials and Chemical Engineering, Hunan Institute of Technology, Hengyang 421002
b.
State Key Laboratory of Molecular Engineering of Polymers, Department of Macromolecular Science, Fudan University, Shanghai 200433

Corresponding author: Zhang Chunyan, chinachunyan@126.com Wang Changchun, ccwang@fudan.edu.cn
Received Date: 15 August 2018
Available Online: 8 January 2018
Fund Project: the Construct Program of the Key Discipline in Hunan Province Xiang Jiao Fa No. [2011]76the National College Students' Innovation and Entrepreneurship Training Program Project Jiao Gao Si No. [2017]40the National Natural Science Foundation of China 21802039Hunan Province College Students' Research Learning and Innovative Experiment Project Xiang Jiao Tong Nos. [2018]255Project supported by the National Natural Science Foundation of China (No. 21802039), the National College Students' Innovation and Entrepreneurship Training Program Project (Jiao Gao Si No. [2017]40), Hunan Province College Students' Research Learning and Innovative Experiment Project (Xiang Jiao Tong Nos. [2017]205, [2018]255) and the Construct Program of the Key Discipline in Hunan Province (Xiang Jiao Fa No. [2011]76)Hunan Province College Students' Research Learning and Innovative Experiment Project Xiang Jiao Tong Nos. [2017]205

Figures(5)

Sulfonated porous polystyrene microspheres as heterogeneous catalyst for preparation of biodiesel were prepared by a facile two-step synthesis process in this work. Firstly, monodisperse porous cross-linked polystyrene microspheres were prepared by reflux-precipitation polymerization, in which different ratio of styrene (St) and divinylbenzene (DVB) were used as monomer and cross-linker, respectively. Then the obtained polystyrene microspheres were sulfonated by chlorosulfonic acid. The structure and composition of the related polystyrene microspheres were characterized by FT-IR, X-ray photoelectron spectroscopy, elemental analysis, thermogravimetric analysis, Brunauer-Emmett-Teller (BET) surface area analysis, transmission electron microscope, particle size and zeta potential analysis. In order to adjust the sulfonated degree and acid density, the reaction parameters such as solvent dosage, swelling time, amount of chlorinated sulfonic acid, sulfonated temperature and sulfonated time were investigated carefully. The optimum conditions for the sulfonated reaction are as follows:0.5 g of cross-linked polystyrene microspheres was swollen with 5 mL of CCl₄, and then sulfonated with 0.3 mL of chlorosulfonic acid at 50℃ for 75 min. In addition, the effect of crosslinking degree on the specific surface area and acid density of the sulfonated polystyrene microspheres were also studied. The as-prepared sulfonated polystyrene microspheres exhibited high acid density (2.611 mmol·g^-1), good thermal stability (up to about 200℃) and appropriate specific surface area. The sulfonated porous polystyrene microspheres as catalyst were applied in the esterification reaction of oleic acid and methanol. Our experimental results showed that the functional particles possessed very high catalytic activity, which was much higher than polystyrene ion exchange resin (Ameberlyst-15) and close to concentrated sulfuric acid. The catalytic activity still maintained 92% of the initial activity after 3 runs of recycling use, and the shedding of sulfonic acid groups was almost negligible. This paper demonstrates a simple, green and controllable strategy to develop sulfonated porous polystyrene microspheres with high catalytic activity and good durability for preparation of biodiesel.
- reflux-precipitation polymerization,
- polystyrene microsphere,
- sulfonated reaction,
- biodiesel
1. [1]
  Pirola, C.; Bianchi, C. L.; Boffito, D. C.; Carvoli, G.; Ragaini, V. Ind. Eng. Chem. Res. 2010, 49, 4601. doi: 10.1021/ie901980c
2. [2]
  Cheng, J.; Qiu, Y.; Huang, R.; Yang, W.; Zhou, J.; Cen, K. Bioresour. Technol. 2016, 221, 344. doi: 10.1016/j.biortech.2016.09.064
3. [3]
  Shu, Q.; Hou, X. P.; Tang, G. Q.; Liu, F. S.; Yuan, H.; Xu, B. Q.; Zhang, C. X.; Wang, J. F. Chin. J. Inorg. Chem. 2016, 32, 1791.
4. [4]
  Liu, F. J.; Huang, K.; Zheng, A. M.; Xiao, F. S.; Dai, S. ACS Catal. 2018, 8, 372. doi: 10.1021/acscatal.7b03369
5. [5]
  Lee, A. F.; Bennett, J. A.; Manayil, J. C.; Wilson, K. Chem. Soc. Rev. 2014, 43, 7887. doi: 10.1039/C4CS00189C
6. [6]
  De, S.; Dutta, S.; Saha, B. Catal. Sci. Technol. 2016, 6, 7364. doi: 10.1039/C6CY01370H
7. [7]
  Gupta, P.; Paul, S. Catal. Today 2014, 236, 153. doi: 10.1016/j.cattod.2014.04.010
8. [8]
  Lian, Y. F.; Yan, L. L.; Wang, Y.; Qi, X. H. Acta Chim. Sinica 2014, 72, 502.
9. [9]
  Akiyama, G.; Matsuda, R.; Sato, H.; Takata, M.; Kitagawa, S. Adv. Mater. 2011, 23, 3294. doi: 10.1002/adma.201101356
10. [10]
  Wang, Z. Q.; Liu, H. Y.; Cui, H. L.; Zhang, M. H.; Zhang, Z. B. Ind. Eng. Chem. Res. 2015, 54, 7219. doi: 10.1021/acs.iecr.5b01408
11. [11]
  Yu, F.; Smet, M.; Dehaen, W.; Sels, B. F. Chem. Commun. 2016, 52, 2756. doi: 10.1039/C5CC08742B
12. [12]
  Liu, F. J.; Kong, W. P.; Qi, C. Z.; Zhu, L. F.; Xiao, F. S. ACS Catal. 2012, 2, 565. doi: 10.1021/cs200613p
13. [13]
  Zhang, X. M.; Zhao, Y. P.; Xu, S. T.; Yang, Y.; Liu, J.; Wei, Y. X.; Yang, Q. H. Nat. Commun. 2014, 5, 3170. doi: 10.1038/ncomms4170
14. [14]
  Jin, S.; Pan, Y.; Wang, C. C. Acta Chim. Sinica 2013, 71, 1500.
15. [15]
  Zhou, R.; Wei, R. Q.; Liu, X. N.; Lin, X. J. Chem. Ind. Eng. 2010, 61, 1047.
16. [16]
  Ma, H.; Li, J. B.; Liu, W. W.; Cheng, B. J.; Cao, X. Y.; Mao, J. D.; Zhu, S. W. J. Agric. Food Chem. 2014, 62, 5345. doi: 10.1021/jf500490m
17. [17]
  Gao, Z. H.; Tang, S. K.; Cui, X. L.; Tian, S. J.; Zhang, M. H. Fuel 2015, 140, 669. doi: 10.1016/j.fuel.2014.10.012
18. [18]
  Yu, H. W.; Niu, S. L.; Lu, C. M.; Li, J.; Yang, Y. Z. Fuel 2017, 208, 101. doi: 10.1016/j.fuel.2017.06.122
19. [19]
  Yang, Q.; Pan, X. J. ACS Sustainable Chem. Eng. 2016, 4, 4824. doi: 10.1021/acssuschemeng.6b01102
20. [20]
  Shu, Q.; Hou, X. P.; Zhu, L. H.; Shen, B. P.; Ma, F.; Wang, J. F. J. Fuel Chem. Technol. 2016, 44, 209. doi: 10.3969/j.issn.0253-2409.2016.02.011
21. [21]
  Li, M.; Chen, D. Y.; Zhu, X. F. Chin. J. Catal. 2013, 34, 1674. doi: 10.1016/S1872-2067(12)60634-2
1. [1]
  Chengqian Mao , Yanghan Chen , Haotong Bai , Junru Huang , Junpeng Zhuang . Photodimerization of Styrylpyridinium Salt and Its Application in Silk Screen Printing. University Chemistry, 2024, 39(5): 354-362. doi: 10.3866/PKU.DXHX202312014
2. [2]
  Xiutao Xu , Chunfeng Shao , Jinfeng Zhang , Zhongliao Wang , Kai Dai . Rational Design of S-Scheme CeO₂/Bi₂MoO₆ Microsphere Heterojunction for Efficient Photocatalytic CO₂ Reduction. Acta Physico-Chimica Sinica, 2024, 40(10): 2309031-. doi: 10.3866/PKU.WHXB202309031
3. [3]
  Haitang WANG , Yanni LING , Xiaqing MA , Yuxin CHEN , Rui ZHANG , Keyi WANG , Ying ZHANG , Wenmin WANG . Construction, crystal structures, and biological activities of two Ln^Ⅲ₃ complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1474-1482. doi: 10.11862/CJIC.20240188
4. [4]
  Xiaowei TANG , Shiquan XIAO , Jingwen SUN , Yu ZHU , Xiaoting CHEN , Haiyan ZHANG . A zinc complex for the detection of anthrax biomarker. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1850-1860. doi: 10.11862/CJIC.20240173
5. [5]
  Jianfeng Yan , Yating Xiao , Xin Zuo , Caixia Lin , Yaofeng Yuan . Comprehensive Chemistry Experimental Design of Ferrocenylphenyl Derivatives. University Chemistry, 2024, 39(4): 329-337. doi: 10.3866/PKU.DXHX202310005
6. [6]
  Zhibei Qu , Changxin Wang , Lei Li , Jiaze Li , Jun Zhang . Organoid-on-a-Chip for Drug Screening and the Inherent Biochemistry Principles. University Chemistry, 2024, 39(7): 278-286. doi: 10.3866/PKU.DXHX202311039
7. [7]
  Dan Li , Hui Xin , Xiaofeng Yi . Comprehensive Experimental Design on Ni-based Catalyst for Biofuel Production. University Chemistry, 2024, 39(8): 204-211. doi: 10.3866/PKU.DXHX202312046
8. [8]
  Yang Liu , Peng Chen , Lei Liu . Chemistry “101 Plan”: Design and Construction of Chemical Biology Textbook. University Chemistry, 2024, 39(10): 45-51. doi: 10.12461/PKU.DXHX202407085
9. [9]
  Tianyu Feng , Guifang Jia , Peng Zou , Jun Huang , Zhanxia Lü , Zhen Gao , Chu Wang . Construction of the Chemistry Biology Experiment Course in the Chemistry “101 Program”. University Chemistry, 2024, 39(10): 69-77. doi: 10.12461/PKU.DXHX202409002
10. [10]
  Xinyi Hong , Tailing Xue , Zhou Xu , Enrong Xie , Mingkai Wu , Qingqing Wang , Lina Wu . Non-Site-Specific Fluorescent Labeling of Proteins as a Chemical Biology Experiment. University Chemistry, 2024, 39(4): 351-360. doi: 10.3866/PKU.DXHX202310010
11. [11]
  Xin MA , Ya SUN , Na SUN , Qian KANG , Jiajia ZHANG , Ruitao ZHU , Xiaoli GAO . A Tb₂ complex based on polydentate Schiff base: Crystal structure, fluorescence properties, and biological activity. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1347-1356. doi: 10.11862/CJIC.20230357
12. [12]
  Jinlong YAN , Weina WU , Yuan WANG . A simple Schiff base probe for the fluorescent turn-on detection of hypochlorite and its biological imaging application. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1653-1660. doi: 10.11862/CJIC.20240154
13. [13]
  Yurong Tang , Yunren Shi , Yi Xu , Bo Qin , Yanqin Xu , Yunfei Cai . Innovative Experiment and Course Transformation Practice of Visible-Light-Mediated Photocatalytic Synthesis of Isoquinolinone. University Chemistry, 2024, 39(5): 296-306. doi: 10.3866/PKU.DXHX202311087
14. [14]
  Ming Li , Zhaoyin Li , Mengzhu Liu , Shaoxiang Luo . Unveiling the Artistry of Mordant Dyeing: The Coordination Chemistry Beneath. University Chemistry, 2024, 39(5): 258-265. doi: 10.3866/PKU.DXHX202311085
15. [15]
  Tiejun Su . The Construction and Application of the Calculation Formula for Endpoint Error in Precipitation Titration: A Case Study of the Mohr Method. University Chemistry, 2024, 39(11): 384-387. doi: 10.12461/PKU.DXHX202402039
16. [16]
  Siyu HOU , Weiyao LI , Jiadong LIU , Fei WANG , Wensi LIU , Jing YANG , Ying ZHANG . Preparation and catalytic performance of magnetic nano iron oxide by oxidation co-precipitation method. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1577-1582. doi: 10.11862/CJIC.20230469
17. [17]
  Yonghui ZHOU , Rujun HUANG , Dongchao YAO , Aiwei ZHANG , Yuhang SUN , Zhujun CHEN , Baisong ZHU , Youxuan ZHENG . Synthesis and photoelectric properties of fluorescence materials with electron donor-acceptor structures based on quinoxaline and pyridinopyrazine, carbazole, and diphenylamine derivatives. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 701-712. doi: 10.11862/CJIC.20230373
18. [18]
  Luhong Chen , Yan Zhang . Chem&Bio Interdisciplinary Graduates Training in Nanjing University Promoted by Chemistry and Biomedicine Innovation Center. University Chemistry, 2024, 39(6): 12-16. doi: 10.3866/PKU.DXHX202311089
19. [19]
  Jiajia Li , Xiangyu Zhang , Zhihan Yuan , Zhengyang Qian , Jian Zhu . 3D Printing Based on Photo-Induced Reversible Addition-Fragmentation Chain Transfer Polymerization. University Chemistry, 2024, 39(5): 11-19. doi: 10.3866/PKU.DXHX202309073
20. [20]
  Zijian Zhao , Yanxin Shi , Shicheng Li , Wenhong Ruan , Fang Zhu , Jijun Jiang . A New Exploration of the Preparation of Polyacrylic Acid by Free Radical Polymerization Based on the Concept of Green Chemistry. University Chemistry, 2024, 39(5): 315-324. doi: 10.3866/PKU.DXHX202311094

Get Citation

PDF

XML

Metrics

PDF Downloads(10)
Abstract views(971)
HTML views(192)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142