Citation: Wang Kaikai, He Junhui. Fabrication and Study of Antibacterial/Antireflective Dual-functional Thin Films from Quaternary Ammonium Salt Modified Hollow Silica Nanospheres[J]. Acta Chimica Sinica, ;2018, 76(10): 807-812. doi: 10.6023/A18050201 shu

Fabrication and Study of Antibacterial/Antireflective Dual-functional Thin Films from Quaternary Ammonium Salt Modified Hollow Silica Nanospheres

Wang Kaikai ^a,b ,
He Junhui ^a,,

a.
Functional Nanomaterials Laboratory, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190
b.
University of Chinese Academy of Sciences, Beijing 100049

Corresponding author: He Junhui, jhhe@mail.ipc.ac.cn
Received Date: 15 May 2018
Available Online: 13 October 2018
Fund Project: the Science and Technology Commission of Beijing Municipality Z151100003315018the National Key Research and Development Program of China 2017YFA0207102the National Natural Science Foundation of China 21571182Project supported by the National Natural Science Foundation of China (No. 21571182), the National Key Research and Development Program of China (No. 2017YFA0207102) and the Science and Technology Commission of Beijing Municipality (No. Z151100003315018)

Figures(8)

Dual-functional thin films simultaneously demonstrating antireflective and antibacterial properties have important practical values in the fields of medicine and health. Unfortunately, related studies have so far been very limited. This work chose a quaternary ammonium salt with the longest carbon chain of C₁₈ as antibacterial agent, and used it to modify an acid-catalyzed silica sol via chemical bonding. The obtained quaternary ammonium salt modified acid-catalyzed silica sol (Q-ASNs) was subsequently mixed with a hollow silica nanospheres sol (HSNs) followed by stirring for 6 h to obtain a mixed sol. The volume percentage of Q-ASNs was varied as 3.1%, 4.9%, 6.7%, and 8.4%, respectively. In detail, Q-ASNs were synthesized as follows:1 mL tetraethyl orthosilicate (TEOS), 0.6 mL quaternary ammonium salt methanol solution (65 wt%), 13.6 mL ethanol, 0.45 mL water and 21 μL HCl were mixed followed by stirring at room temperature for 4 h and aging for at least one day. HSNs were prepared according to the following procedure:0.1 g poly(acrylic acid) (PAA) was dissolved in 4.5 mL ammonium hydroxide, and then it was mixed with 90 mL absolute ethanol under stirring. This was followed by the injection of 800 μL TEOS under vigorous magnetic stirring at room temperature in 40 min. After 10 h, a HSNs sol containing~30 nm hollow silica nanospheres formed. Before mixing Q-ASNs and HSNs, the HSNs were stirred in a ventilating cabinet for more than 24 h to remove ammonia. Antireflective/antibacterial dual-functional thin films were fabricated by dip-coating from the mixed sol of Q-ASNs and HSNs. The optical properties of the films were optimized by regulating the mixing ratio of the above-mentioned two sols. The optimal thin film coated glass substrate presented high transmittance (T_max=99.2%, T_ave=98.6%) in the visible wavelength range of 400~800 nm. The HSNs and the mixed sol were observed by transmission electron microscopy. The fabricated thin films were characterized by scanning electron microscopy, atomic force microscopy, transmission/reflection spectroscopy, X-ray photoelectron spectroscopy, and confocal laser scanning microscopy using a live/dead reagent. The current method is simple and easy for large-area coating without any high-temperature heat treatment, and is thus promising for practical applications.
- antireflective,
- antibacterial,
- quaternary ammonium salt,
- hollow silica nanospheres,
- thin film
1. [1]
  Yao, L.; He, J. Prog. Mater. Sci. 2014, 61, 94. doi: 10.1016/j.pmatsci.2013.12.003
2. [2]
  Xu, L.; He, J. J. Mater. Chem. C 2013, 1, 4655. doi: 10.1039/c3tc30734d
3. [3]
  Li, T.; He, J. J. Mater. Chem. C 2016, 4, 5342. doi: 10.1039/C6TC01540A
4. [4]
  Zhang, J.; Yu, J. Chin. J. Chem. 2017, 36, 51.
5. [5]
  Sun, H.; He, Q.; Yin, S.; Xu, K. Chin. J. Chem. 2017, 35, 1627. doi: 10.1002/cjoc.v35.10
6. [6]
  Raut, H. K.; Ganesh, V. A.; Nair, A. S.; Ramakrishna, S. Energy Environ. Sci. 2011, 4, 3779. doi: 10.1039/c1ee01297e
7. [7]
  Moghal, J.; Kobler, J.; Sauer, J.; Best, J.; Gardener, M.; Watt, A. A.; Wakefield, G. ACS Appl. Mater. Interfaces 2012, 4, 854. doi: 10.1021/am201494m
8. [8]
  Yao, L.; He, J. J. Mater. Chem. A 2014, 2, 6994. doi: 10.1039/c3ta15363k
9. [9]
  Tao, C.; Yan, H.; Yuan, X.; Yin, Q.; Zhu, J.; Ni, W.; Yan, L.; Zhang, L. Colloids Surf., A 2016, 509, 307. doi: 10.1016/j.colsurfa.2016.08.055
10. [10]
  Xu, L.; Geng, Z.; He, J.; Zhou, G. ACS Appl. Mater. Interfaces 2014, 6(12), 9029. doi: 10.1021/am5016777
11. [11]
  Zhang, J.; Lan, P.; Li, J.; Xu, H.; Wang, Q.; Zhang, X.; Zheng, L.; Lu, Y.; Dai, N.; Song, W. J. Sol-Gel Sci. Technol. 2014, 71, 267. doi: 10.1007/s10971-014-3364-y
12. [12]
  Cloutier, M.; Mantovani, D.; Rosei, F. Trends Biotechnol. 2015, 33, 637. doi: 10.1016/j.tibtech.2015.09.002
13. [13]
  Kiedrowski, L. M.; Perisetti, A.; Loock, M. H.; Khaitsa, M. L.; Guerrero, D. M. Am. J. Infect. Control 2013, 41, 1136. doi: 10.1016/j.ajic.2013.01.030
14. [14]
  Wang, X.; Shi, L.; Zhang, J.; Cheng, J.; Wang, X. RSC Adv. 2017, 7, 31502. doi: 10.1039/C7RA04353H
15. [15]
  Shao, H.; Meng, W.-D.; Qing, F.-L. J. Fluorine Chem. 2004, 125, 721. doi: 10.1016/j.jfluchem.2003.12.008
16. [16]
  Liu, C. X.; Zhang, D. R.; He, Y.; Zhao, X. S.; Bai, R. J. Membr. Sci. 2010, 346, 121. doi: 10.1016/j.memsci.2009.09.028
17. [17]
  Li, L.; Chi, X.; Yan, J.; Zhao, Z. Chin. J. Org. Chem. 2018, 38, 955.
18. [18]
  Asri, L. A. T. W.; Crismaru, M.; Roest, S.; Chen, Y.; Ivashenko, O.; Rudolf, P.; Tiller, J. C.; van der Mei, H. C.; Loontjens, T. J. A.; Busscher, H. J. Adv. Funct. Mater. 2014, 24, 346. doi: 10.1002/adfm.v24.3
19. [19]
  Gottenbosa, B.; Mei, H. C. V.; Klatterb, F.; Nieuwenhuisb, P.; Busscher, H. J. Biomaterials 2002, 23, 1417. doi: 10.1016/S0142-9612(01)00263-0
20. [20]
  Nishihara, T.; Okamoto, T.; Nishiyama, N. J. Appl. Microbiol. 2000, 88, 641. doi: 10.1046/j.1365-2672.2000.01007.x
21. [21]
  Laopaiboon, L.; Hall, S. J.; Smith, R. N. J. Appl. Microbiol. 2002, 93, 1051. doi: 10.1046/j.1365-2672.2002.01785.x
22. [22]
  Kim, S.; Jung, U. T.; Kim, S. K.; Lee, J. H.; Choi, H. S.; Kim, C. S.; Jeong, M. Y. ACS Appl. Mater. Interfaces 2015, 7, 326. doi: 10.1021/am506254r
23. [23]
  Zhou, H.; Li, J.; Bao, S.; Li, J.; Liu, X.; Jin, P. Appl. Surf. Sci. 2016, 363, 532. doi: 10.1016/j.apsusc.2015.12.045
24. [24]
  Wang, K.; He, J. ACS Appl. Mater. Interfaces 2018, 10, 11189. doi: 10.1021/acsami.8b00192
25. [25]
  Zhang, Q.; Liu, H.; Zhan, X.; Chen, F.; Yan, J.; Tang, H. RSC Adv. 2015, 5, 77508. doi: 10.1039/C5RA12945A
26. [26]
  Andreu, N.; Flahaut, D.; Dedryvère, R.; Minvielle, M.; Martinez, H.; Gonbeau, D. ACS Appl. Mater. Interfaces 2015, 7, 6629. doi: 10.1021/am5089764
27. [27]
  Zhang, X.; Lan, P.; Lu, Y.; Li, J.; Xu, H.; Zhang, J.; Lee, Y.; Rhee, J. Y.; Choy, K. L.; Song, W. ACS Appl. Mater. Interfaces 2014, 6, 1415. doi: 10.1021/am405258d
28. [28]
  Zhang, X.; He, J. Chem. Commun. (Camb) 2015, 51, 12661. doi: 10.1039/C5CC04465K
29. [29]
  Knetsch, M. L. W.; Koole, L. H. Polymer 2011, 3, 340. doi: 10.3390/polym3010340
30. [30]
  Majumdar, P.; Lee, E.; Gubbins, N.; Christianson, D. A.; Stafslien, S. J.; Daniels, J.; VanderWal, L.; Bahr, J.; Chisholm, B. J. J. Comb. Chem. 2009, 11, 1115. doi: 10.1021/cc900114e
31. [31]
  Kugler, R.; Bouloussa, O.; Rondelez, F. Microbiology 2005, 151, 1341. doi: 10.1099/mic.0.27526-0
1. [1]
  Shipeng WANG , Shangyu XIE , Luxian LIANG , Xuehong WANG , Jie WEI , Deqiang WANG . Piezoelectric effect of Mn, Bi co-doped sodium niobate for promoting cell proliferation and bacteriostasis. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1919-1931. doi: 10.11862/CJIC.20240094
2. [2]
  Wendian XIE , Yuehua LONG , Jianyang XIE , Liqun XING , Shixiong SHE , Yan YANG , Zhihao HUANG . Preparation and ion separation performance of oligoether chains enriched covalent organic framework membrane. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1528-1536. doi: 10.11862/CJIC.20240050
3. [3]
  Jiaxin Su , Jiaqi Zhang , Shuming Chai , Yankun Wang , Sibo Wang , Yuanxing Fang . Optimizing Poly(heptazine imide) Photoanodes Using Binary Molten Salt Synthesis for Water Oxidation Reaction. Acta Physico-Chimica Sinica, 2024, 40(12): 2408012-. doi: 10.3866/PKU.WHXB202408012
4. [4]
  Xiaoning TANG , Shu XIA , Jie LEI , Xingfu YANG , Qiuyang LUO , Junnan LIU , An XUE . Fluorine-doped MnO₂ with oxygen vacancy for stabilizing Zn-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1671-1678. doi: 10.11862/CJIC.20240149
5. [5]
  Zhiquan Zhang , Baker Rhimi , Zheyang Liu , Min Zhou , Guowei Deng , Wei Wei , Liang Mao , Huaming Li , Zhifeng Jiang . Insights into the Development of Copper-based Photocatalysts for CO₂ Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2406029-. doi: 10.3866/PKU.WHXB202406029
6. [6]
  Caixia Lin , Zhaojiang Shi , Yi Yu , Jianfeng Yan , Keyin Ye , Yaofeng Yuan . Ideological and Political Design for the Electrochemical Synthesis of Benzoxathiazine Dioxide Experiment. University Chemistry, 2024, 39(2): 61-66. doi: 10.3866/PKU.DXHX202309005
7. [7]
  Guimin ZHANG , Wenjuan MA , Wenqiang DING , Zhengyi FU . Synthesis and catalytic properties of hollow AgPd bimetallic nanospheres. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 963-971. doi: 10.11862/CJIC.20230293
8. [8]
  Yuhao SUN , Qingzhe DONG , Lei ZHAO , Xiaodan JIANG , Hailing GUO , Xianglong MENG , Yongmei GUO . Synthesis and antibacterial properties of silver-loaded sod-based zeolite. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 761-770. doi: 10.11862/CJIC.20230169
9. [9]
  Dong-Bing Cheng , Junxin Duan , Haiyu Gao . Experimental Teaching Design on Chitosan Extraction and Preparation of Antibacterial Gel. University Chemistry, 2024, 39(2): 330-339. doi: 10.3866/PKU.DXHX202308053
10. [10]
  Xinyuan Shi , Chenyangjiang , Changyu Zhai , Xuemei Lu , Jia Li , Zhu Mao . Preparation and Photoelectric Performance Characterization of Perovskite CsPbBr₃ Thin Films. University Chemistry, 2024, 39(6): 383-389. doi: 10.3866/PKU.DXHX202312019
11. [11]
  Bao Jia , Yunzhe Ke , Shiyue Sun , Dongxue Yu , Ying Liu , Shuaishuai Ding . Innovative Experimental Teaching for the Preparation and Modification of Conductive Organic Polymer Thin Films in Undergraduate Courses. University Chemistry, 2024, 39(10): 271-282. doi: 10.12461/PKU.DXHX202404121
12. [12]
  Jingjie Tang , Luying Xie , Jiayu Liu , Shangyu Shi , Xinyu Sun , Jiayang Lin , Qikun Yang , Chuan'ang Yu , Zecheng Wang , Yingying Wang , Zengyang Xie . Efficient Rapid Synthesis and Antibacterial Activities of Tosylhydrazones: A Recommended Innovative Chemistry Experiment for Undergraduate Medical University. University Chemistry, 2024, 39(3): 316-326. doi: 10.3866/PKU.DXHX202309091
13. [13]
  Hongyun Liu , Jiarun Li , Xinyi Li , Zhe Liu , Jiaxuan Li , Cong Xiao . Course Ideological and Political Design of a Comprehensive Chemistry Experiment: Constructing a Visual Molecular Logic System Based on Intelligent Hydrogel Film Electrodes. University Chemistry, 2024, 39(2): 227-233. doi: 10.3866/PKU.DXHX202309070
14. [14]
  Jiaxing Cai , Wendi Xu , Haoqiang Chi , Qian Liu , Wa Gao , Li Shi , Jingxiang Low , Zhigang Zou , Yong Zhou . 具有0D/2D界面的InOOH/ZnIn₂S₄空心球S型异质结用于增强光催化CO₂转化性能. Acta Physico-Chimica Sinica, 2024, 40(11): 2407002-. doi: 10.3866/PKU.WHXB202407002
15. [15]
  Lijuan Wang , Yuping Ning , Jian Li , Sha Luo , Xiongfei Luo , Ruiwen Wang . Enhancing the Advanced Nature of Natural Product Chemistry Laboratory Courses with New Research Findings: A Case Study of the Application of Berberine Hydrochloride in Photodynamic Antimicrobial Films. University Chemistry, 2024, 39(11): 241-250. doi: 10.12461/PKU.DXHX202403017
16. [16]
  Weina Wang , Fengyi Liu , Wenliang Wang . “Extracting Commonality, Delving into Typicals, Deriving Individuality”: Constructing a Knowledge Graph of Crystal Structures. University Chemistry, 2024, 39(3): 36-42. doi: 10.3866/PKU.DXHX202308029
17. [17]
  Wei Gao , Jinyue Yang , Wenwei Zhang . Practice and Exploration of Promoting the “Double Reduction” Work with Popular Science Resources in Universities. University Chemistry, 2024, 39(9): 385-391. doi: 10.3866/PKU.DXHX202311008
18. [18]
  Xue Qi , Zhihui Wen , Xiaohang Qiu . Design of Chemistry Popular Science Courses for Primary and Secondary School Students across Various Ages under the “Double Reduction” Policy: A Case Study of Nankai University’s Chemistry Science Popularization Base. University Chemistry, 2024, 39(9): 392-400. doi: 10.3866/PKU.DXHX202310070
19. [19]
  Peng GENG , Guangcan XIANG , Wen ZHANG , Haichuang LAN , Shuzhang XIAO . Hollow copper sulfide loaded protoporphyrin for photothermal-sonodynamic therapy of cancer cells. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1903-1910. doi: 10.11862/CJIC.20240155
20. [20]
  Xiutao Xu , Chunfeng Shao , Jinfeng Zhang , Zhongliao Wang , Kai Dai . Rational Design of S-Scheme CeO₂/Bi₂MoO₆ Microsphere Heterojunction for Efficient Photocatalytic CO₂ Reduction. Acta Physico-Chimica Sinica, 2024, 40(10): 2309031-. doi: 10.3866/PKU.WHXB202309031

Get Citation

PDF

XML

Metrics

PDF Downloads(10)
Abstract views(1139)
HTML views(204)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142