Citation: Li Cui, Zhang Qi, Fu Yao. Transition Metal Catalyzed Deoxydehydration of Alcohols[J]. Acta Chimica Sinica, ;2018, 76(7): 501-514. doi: 10.6023/A18040138 shu

Transition Metal Catalyzed Deoxydehydration of Alcohols

Li Cui ^a ,
Zhang Qi ^b ,
Fu Yao ^a,,

a.
Department of Chemistry, University of Science and Technology of China, Hefei 230026
b.
Institute of Industry & Equipment Technology, Hefei University of Technology, Hefei 230009

Corresponding author: Fu Yao, fuyao@ustc.edu.cn
Received Date: 9 April 2018
Available Online: 14 July 2018
Fund Project: Project supported by the National Natural Science Foundation of China (Nos. 21325208, 21572212, 21732006, 21702041), Ministry of Science and Technology of China (No. 2017YFA0303500), the Strategic Priority Research Program of the Chinese Academy of Sciences (No. XDB20000000), Fundamental Research Funds for the Central Universities, and Program for Changjiang Scholars and Innovative Research Team in Universitythe National Natural Science Foundation of China 21572212the National Natural Science Foundation of China 21325208the National Natural Science Foundation of China 21702041the Strategic Priority Research Program of the Chinese Academy of Sciences XDB20000000the National Natural Science Foundation of China 21732006Ministry of Science and Technology of China 2017YFA0303500

Figures(41)

In view of the depletion of fossil fuels, the development and utilization of environment-friendly and sustainable resources widely play an indispensable role in alleviating and resolving problems about resources and environment. Biomass could be utilized as biofuels and renewable platform chemicals. However, biomass-derived molecules are fairly oxygen-rich and hyperfunctionalized. Therefore, new synthetic routes for the regenerative production of chemicals, fuels, and energy from renewable biomass sources are currently investigated especially the routes of transforming high-oxygen-content biomassderived vicinal diols and poly vicinal alcohols into fuels and value-added chemicals. A range of reductive deoxygenation methods consisting of direct deoxygenation, pyrolysis, hydrogenolysis, decarbonylation, decarboxylation, hydrodeoxygenation, and deoxydehydration (DODH) are under investigation. In this review, we detail the recent-evolutionary and efficient strategies of transition metal-catalyzed DODH of vicinal diols into corresponding alkenes, including rhenium, molybdenum, vanadium, and ruthenium catalysts. Rhenium-catalyzed DODH reactions are very selective and active to provide high yields of olefin products, which keep important functionality in place as well as can be readily functionalized. Recent efforts in rhenium-mediated systems include the development of new rhenium catalysts, the application of cheaper and more available reductants, and growing mechanistic understandings owing to both theoretical and experimental studies. A new emerging trend within DODH is the development of heterogeneous rhenium-based catalysts which demonstrates their ability to rival and in some cases surpass their homogeneous counterparts. Furthermore, catalysts based on the transition metals molybdenum, vanadium and ruthenium show great potential as inexpensive alternatives to rhenium catalysts.
- deoxydehydration,
- transition metal,
- vicinal diol,
- olefin,
- biomass derivatives
1. [1]
  Chu, S.; Majumdar, A. Nature 2012, 488, 294. doi: 10.1038/nature11475
2. [2]
  Bruijnincx, P. C. A.; Weckhuysen, B. M. Angew. Chem. Int. Ed. 2013, 52, 11980. doi: 10.1002/anie.201305058
3. [3]
  Song, F.; Ding, Y.; Zhao, C. Acta Chim. Sinica 2014, 72, 133(in Chinese).
4. [4]
  Mohr, S. H.; Wang, J.; Ellem, G.; Ward, J.; Giurco, D. Fuel 2015, 141, 120. doi: 10.1016/j.fuel.2014.10.030
5. [5]
  Sheldon, R. A. Green Chem. 2017, 19, 18. doi: 10.1039/C6GC02157C
6. [6]
  Zhao, C.; Ma, Y.; Wang, Y.; Zhou, X.; Li, H.; Li, M.; Song, Y. Acta Chim. Sinica 2018, 76, 9(in Chinese).
7. [7]
  Corma, A.; Iborra, S.; Velty, A. Chem. Rev. 2007, 107, 2411. doi: 10.1021/cr050989d
8. [8]
  Alonso, D. M.; Bond, J. Q.; Dumesic, J. A. Green Chem. 2010, 12, 1493. doi: 10.1039/c004654j
9. [9]
  Besson, M.; Gallezot, P.; Pinel, C. Chem. Rev. 2014, 114, 1827. doi: 10.1021/cr4002269
10. [10]
  Wang, Y.; Hu, M.; Wang, Y.; Qin, Y.; Chen, H.; Zeng, L.; Lei, J.; Huang, X.; He, L.; Zhang, R.; Wu, Z. Acta Chim. Sinica 2016, 74, 356(in Chinese).
11. [11]
  Ding, S.; Ge, Q.; Zhu, X. Acta Chim. Sinica 2017, 75, 439(in Chinese).
12. [12]
  Wang, H.; Zhao, Y.; Wang, C.; Fu, Y.; Guo, Q. Acta Chim. Sinica 2009, 67, 893(in Chinese).
13. [13]
  Jiang, Y.; Yu, H.; Fu, Y. Acta Chim. Sinica 2013, 71, 1611(in Chinese).
14. [14]
  Lian, Y.; Yan, L.; Wang, Y.; Qi, X. Acta Chim. Sinica 2014, 72, 502(in Chinese).
15. [15]
  Zhang, X.; Wilson, K.; Lee, A. F. Chem. Rev. 2016, 116, 12328. doi: 10.1021/acs.chemrev.6b00311
16. [16]
  Liu, X.; Yan, L.; Fu, Y. Acta Chim. Sinica 2017, 75, 788(in Chinese).
17. [17]
  Pagliaro, M.; Ciriminna, R.; Kimura, H.; Rossi, M.; Della Pina, C. Angew. Chem. Int. Ed. 2007, 46, 4434. doi: 10.1002/(ISSN)1521-3773
18. [18]
  Vennestrøm, P. N. R.; Osmundsen, C. M.; Christensen, C. H.; Taarning, E. Angew. Chem. Int. Ed. 2011, 50, 10502. doi: 10.1002/anie.201102117
19. [19]
  Serrano-Ruiz, J. C.; Luque, R.; Sepúlveda-Escribano, A. Chem. Soc. Rev. 2011, 40, 5266. doi: 10.1039/c1cs15131b
20. [20]
  Gallezot, P. Chem. Soc. Rev. 2012, 41, 1538. doi: 10.1039/C1CS15147A
21. [21]
  Sullivan, R. J.; Latifi, E.; Chung, B. K.-M.; Soldatov, D. V.; Schlaf, M. Chem. Rev. 2014, 114, 1827. doi: 10.1021/cr4002269
22. [22]
  Yan, L.; Pang, H.; Huang, Y.; Fu, Y. Acta Chim. Sinica 2014, 72, 1005(in Chinese).
23. [23]
  Li, J.; Huang, Y.; Guo, Q.; Fu, Y. Acta Chim. Sinica 2014, 72, 1223(in Chinese).
24. [24]
  Zhao, Y.; Deng, L.; Liao, B.; Fu, Y.; Guo, Q. Energy Fuels 2010, 24, 5735. doi: 10.1021/ef100896q
25. [25]
  Zhao, Y.; Fu, Y.; Guo, Q. Bioresour. Technol. 2012, 114, 740. doi: 10.1016/j.biortech.2012.03.057
26. [26]
  Zhao, Y.; Pan, T.; Zuo, Y.; Guo, Q.; Fu, Y. Bioresour. Technol. 2013, 147, 37. doi: 10.1016/j.biortech.2013.07.068
27. [27]
  Xu, L.; Zhang, Y.; Fu, Y. Energy Technol. 2016, 4, 1. doi: 10.1002/ente.201500354
28. [28]
  Lai, D.; Deng, L.; Guo, Q.; Fu, Y. Energy Environ. Sci. 2011, 4, 3552. doi: 10.1039/c1ee01526e
29. [29]
  Zuo, Y.; Zhang, Y.; Fu, Y. ChemCatChem 2014, 6, 753. doi: 10.1002/cctc.201300956
30. [30]
  Ruppert, A. M.; Weinberg, K.; Palkovits, R. Angew. Chem. Int. Ed. 2012, 51, 2564. doi: 10.1002/anie.201105125
31. [31]
  Maetani, S.; Fukuyama, T.; Suzuki, N.; Ishihara, D.; Ryu, I. Chem. Commun. 2012, 48, 2552. doi: 10.1039/c2cc18093f
32. [32]
  Huang, Y.; Yang, Z.; Chen, M.; Dai, J.; Guo, Q.; Fu, Y. ChemSusChem 2013, 6, 1348. doi: 10.1002/cssc.201300190
33. [33]
  Saidi, M.; Samimi, F.; Karimipourfard, D.; Nimmanwudipong, T.; Gates, B. C.; Rahimpou, M. R. Energy Environ. Sci. 2014, 7, 103. doi: 10.1039/C3EE43081B
34. [34]
  Chen, M.; Huang, Y.; Pang, H.; Liu, X.; Fu, Y. Green Chem. 2015, 17, 1710. doi: 10.1039/C4GC01992J
35. [35]
  Xu, G.; Guo, J.; Qu, Y.; Zhang, Y.; Fu, Y.; Guo, Q. Green Chem. 2016, 18, 5510. doi: 10.1039/C6GC01097K
36. [36]
  Li, J.; Liu, J.; Liu, H.; Xu, G.; Zhang, J.; Liu, J.; Zhou, G.; Li, Q.; Xu, Z.; Fu, Y. ChemSusChem 2017, 10, 1436. doi: 10.1002/cssc.v10.7
37. [37]
  Liu, X.; Jia, W.; Xu, G.; Zhang, Y.; Fu, Y. ACS Sustainable Chem. Eng. 2017, 5, 8594. doi: 10.1021/acssuschemeng.7b01047
38. [38]
  Korstanje, T. J.; Klein Gebbink, R. J. M. Top. Organomet. Chem. 2012, 39, 129. doi: 10.1007/978-3-642-28288-1
39. [39]
  Dutta, S. ChemSusChem 2012, 5, 2125. doi: 10.1002/cssc.v5.11
40. [40]
  Metzger, J. O. ChemCatChem 2013, 5, 680. doi: 10.1002/cctc.201200796
41. [41]
  Boucher-Jacobs, C.; Nicholas, K. M. Top. Curr. Chem. 2014, 353, 163. doi: 10.1007/978-3-319-08654-5
42. [42]
  Mika, L. T.; Cséfalvay, E.; Horváth, I. T. Catal. Today 2015, 247, 33. doi: 10.1016/j.cattod.2014.10.043
43. [43]
  Harms, R. G.; Herrmann, W. A.; Kühn, F. E. Coord. Chem. Rev. 2015, 296, 1. doi: 10.1016/j.ccr.2015.03.015
44. [44]
  Nicholas, K. M. J. Org. Chem. 2015, 80, 6943. doi: 10.1021/acs.joc.5b00982
45. [45]
  Makshina, E. V.; Dusselier, M.; Janssens, W.; Jan Degreve, J.; Jacobs, P. A.; Sels, B. F. Chem. Soc. Rev. 2014, 43, 7917. doi: 10.1039/C4CS00105B
46. [46]
  Raju, S.; Moret, M. E.; Klein Gebbink, R. J. M. ACS Catal. 2015, 5, 281. doi: 10.1021/cs501511x
47. [47]
  Mao, G. L.; Jia, B.; Wang, C. Y. Chin. J. Org. Chem. 2015, 35, 284(in Chinese).
48. [48]
  Dethlefsen, J. R.; Fristrup, P. ChemSusChem 2015, 8, 767. doi: 10.1002/cssc.v8.5
49. [49]
  Petersen, A. R.; Fristrup, P. Chem.-Eur. J. 2017, 23, 10235. doi: 10.1002/chem.v23.43
50. [50]
  Romao, C. C.; Kuhn, F. E.; Herrmann, W. A. Chem. Rev. 1997, 97, 3197. doi: 10.1021/cr9703212
51. [51]
  Herrmann, W. A.; Kühn, F. E. Acc. Chem. Res. 1997, 30, 169. doi: 10.1021/ar9601398
52. [52]
  Wang, F.; Gao, K.; Wang, C. Acta Chim. Sinica 2007, 65, 2211(in Chinese).
53. [53]
  Chen, J.; Du, X.; Yu, T.; Zeng, Y.; Zhang, X.; Li, Y. Acta Chim. Sinica 2016, 74, 523(in Chinese).
54. [54]
  Abu-Omar, M. M.; Appelman, E. H.; Espenson, J. H. Inorg. Chem. 1996, 35, 7751. doi: 10.1021/ic960701q
55. [55]
  Gable, K. P. Adv. Organomet. Chem. 1997, 41, 127. doi: 10.1016/S0065-3055(08)60438-4
56. [56]
  Espenson, J. H. Adv. Inorg. Chem. 2003, 54, 157. doi: 10.1016/S0898-8838(03)54003-X
57. [57]
  Kühn, F. E.; Scherbaum, A.; Herrmann, W. A. J. Organomet. Chem. 2004, 689, 4149. doi: 10.1016/j.jorganchem.2004.08.018
58. [58]
  Korstanje, T. J.; Jastrzebski, J. T. B. H.; Klein Gebbink, R. J. M. Chem.-Eur. J. 2013, 19, 13224. doi: 10.1002/chem.v19.39
59. [59]
  Korstanje, T. J.; de Waard, E. F.; Jastrzebski, J. T. B. H.; Klein Gebbink, R. J. M. ACS Catal. 2012, 2, 2173. doi: 10.1021/cs300455w
60. [60]
  Herrmann, W. A.; Marz, D.; Herdtweck, E.; Schiifer, A.; Wagner, W.; Kneuper, H. J. Angew. Chem. Int. Ed. 1987, 26, 462. doi: 10.1002/(ISSN)1521-3773
61. [61]
  Gable, K. P.; Phan, T. N. J. Am. Chem. Soc. 1994, 116, 833. doi: 10.1021/ja00082a002
62. [62]
  Gable, K. P. Organometallics 1994, 13, 2486. doi: 10.1021/om00018a048
63. [63]
  Cook, G. K.; Andrews, M. A. J. Am. Chem. Soc. 1996, 118, 9448. doi: 10.1021/ja9620604
64. [64]
  Gable, K. P. ; Ross, B. ACS Symposium Series, Vol. 921, Eds. : Bozell, J. J. ; Patel, M. K. American Chemical Society, Washington, DC, 2006, Chapter 11.
65. [65]
  Bergman, R. G.; Cundari, T. R.; Gillespie, A. M.; Gunnoe, T. B.; Harman, W. D.; Klinckman, T. R.; Temple, M. D.; White, D. P. Organometallics 2003, 22, 2331. doi: 10.1021/om021048j
66. [66]
  Raju, S.; Jastrzebski, J. T. B. H.; Lutz, M.; Klein Gebbink, R. J. M. ChemSusChem 2013, 6, 1673. doi: 10.1002/cssc.201300364
67. [67]
  Raju, S.; Jastrzebski, J. T. B. H.; Lutz, M.; Witteman, L.; Dethlefsen, J. R.; Fristrup, P.; Moret, M. E.; Klein Gebbink, R. J. M. Inorg. Chem. 2015, 54, 11031. doi: 10.1021/acs.inorgchem.5b02366
68. [68]
  Raju, S.; van Slagmaat, C. A. M. R.; Li, J.; Lutz, M.; Jastrzebski, J. T. B. H.; Moret, M. E.; Klein Gebbink, R. J. M. Organometallics 2016, 35, 2178. doi: 10.1021/acs.organomet.6b00120
69. [69]
  Yanagi, T.; Suzuki, H.; Oishi, M. Chem. Lett. 2013, 42, 1403. doi: 10.1246/cl.130699
70. [70]
  Shimogawa, R.; Takao, T.; Suzuki, H. Organometallics 2014, 33, 289. doi: 10.1021/om401035y
71. [71]
  Sun, H. M.; Hu, C.; Hao, Z. M.; Zuo, Y. J.; Wang, T. C.; Zhong, C. M. Chin. J. Org. Chem. 2015, 35, 1904(in Chinese).
72. [72]
  Hillea, C.; Kühn, F. E. Dalton Trans. 2016, 45, 15. doi: 10.1039/C5DT03641K
73. [73]
  Ziegler, J. E.; Zdilla, M. J.; Evans, A. J.; Abu-Omar, M. M. Inorg. Chem. 2009, 48, 9998. doi: 10.1021/ic901792b
74. [74]
  Bi, S. W.; Wang, J. Y.; Liu, L. J.; Li, P.; Lin, Z. Y. Organometallics 2012, 31, 6139. doi: 10.1021/om300485w
75. [75]
  Larson, R. T.; Samant, A.; Chen, J.; Lee, W.; Bohn, M. A.; Ohlmann, D. M.; Zuend, S. J.; Toste, F. D. J. Am. Chem. Soc. 2017, 139, 14001. doi: 10.1021/jacs.7b07801
76. [76]
  Ahmad, I.; Chapman, G.; Nicholas, K. M. Inorg. Chem. 2010, 49, 4744. doi: 10.1021/ic100467p
77. [77]
  Vkuturi, S.; Chapman, G.; Ahmad, I.; Nicholas, K. M. Organometallics 2011, 30, 2810. doi: 10.1021/om2001662
78. [78]
  Arceo, E.; Ellman, J. A.; Bergman, R. G. J. Am. Chem. Soc. 2010, 132, 11408. doi: 10.1021/ja103436v
79. [79]
  Sousa, S. C.; Fernandes, A. C. Tetrahedron Lett. 2011, 52, 6960. doi: 10.1016/j.tetlet.2011.10.085
80. [80]
  Yi, J.; Liu, S.; Abu-Omar, M. M. ChemSusChem 2012, 5, 1401. doi: 10.1002/cssc.v5.8
81. [81]
  Canale, V.; Tonucci, L.; Bressana, M.; d'Alessandro, N. Catal. Sci. Technol. 2014, 4, 3697. doi: 10.1039/C4CY00631C
82. [82]
  Shiramizu, M.; Toste, F. D. Angew. Chem. Int. Ed. 2012, 51, 8082. doi: 10.1002/anie.v51.32
83. [83]
  Qu, S. L.; Dang, Y. F.; Wen, M. W.; Wang, Z. X. Chem.-Eur. J. 2013, 19, 3827. doi: 10.1002/chem.201204001
84. [84]
  Boucher-Jacobs, C.; Nicholas, K. M. ChemSusChem 2013, 6, 597. doi: 10.1002/cssc.201200781
85. [85]
  Shiramizu, M.; Toste, F. D. Angew. Chem. Int. Ed. 2013, 52, 12905. doi: 10.1002/anie.201307564
86. [86]
  Wang, G.; Jimtaisong, A.; Luck, R. L. Organometallics 2004, 23, 4522. doi: 10.1021/om049669v
87. [87]
  Morrill, C.; Grubbs, R. H. J. Am. Chem. Soc. 2005, 127, 2842. doi: 10.1021/ja044054a
88. [88]
  Morrill, C.; Beutner, G. L.; Grubbs, R. H. J. Org. Chem. 2006, 71, 7813. doi: 10.1021/jo061436l
89. [89]
  Herrmann, A. T.; Saito, T.; Stivala, C. E.; Tom, J.; Zakarian, A. J. Am. Chem. Soc. 2010, 132, 5962. doi: 10.1021/ja101673v
90. [90]
  Davis, J.; Srivastava, R. S. Tetrahedron Lett. 2014, 55, 4178. doi: 10.1016/j.tetlet.2014.05.044
91. [91]
  Li, X. K.; Wu, D.; Lu, T.; Yi, G. S.; Su, H. B.; Zhang, Y. G. Angew. Chem. Int. Ed. 2014, 53, 4200. doi: 10.1002/anie.201310991
92. [92]
  Shin, N.; Kwon, S.; Moon, S.; Hong, C. H.; Kim, Y. G. Tetrahedron 2017, 73, 4758. doi: 10.1016/j.tet.2017.06.053
93. [93]
  McClain, J. M.; Nicholas, K. M. ACS Catal. 2014, 4, 2109. doi: 10.1021/cs500461v
94. [94]
  Boucher-Jacobs, C.; Nicholas, K. M. Organometallics 2015, 34, 1985. doi: 10.1021/acs.organomet.5b00226
95. [95]
  Arterburn, J. B.; Liu, M.; Perry, M. C. Helv. Chim. Acta 2002, 85, 3225. doi: 10.1002/1522-2675(200210)85:10<3225::AID-HLCA3225>3.0.CO;2-H
96. [96]
  Denning, A. L.; Dang, H.; Liu, Z.; Nicholas, K. M.; Jentoft, F. C. ChemCatChem 2013, 5, 3567. doi: 10.1002/cctc.201300545
97. [97]
  Ota, N.; Tamura, M.; Nakagawa, Y.; Okumura, K.; Tomishige, K. Angew. Chem. Int. Ed. 2015, 54, 1897. doi: 10.1002/anie.201410352
98. [98]
  Ota, N.; Tamura, M.; Nakagawa, Y.; Okumura, K.; Tomishige, K. ACS Catal. 2016, 6, 3213. doi: 10.1021/acscatal.6b00491
99. [99]
  Tazawa, S.; Ota, N.; Tamura, M.; Nakagawa, Y.; Okumura, K.; Tomishige, K. ACS Catal. 2016, 6, 6393. doi: 10.1021/acscatal.6b01864
100. [100]
  Sandbrink, L.; Klindtworth, E.; Islam, H.; Beale, A. M.; Palkovits, R. ACS Catal. 2016, 6, 677. doi: 10.1021/acscatal.5b01936
101. [101]
  Li, X. K.; Zhang, Y. G. ChemSusChem 2016, 9, 2774. doi: 10.1002/cssc.201600865
102. [102]
  Hills, L.; Moyano, R.; Montilla, F.; Pastor, A.; Galindo, A.; Álvarez, E.; Marchetti, F.; Pettinari, C. Eur. J. Inorg. Chem. 2013, 3352.
103. [103]
  Dethlefsen, J. R.; Lupp, D.; Oh, B. C.; Fristrup, P. ChemSusChem 2014, 7, 425. doi: 10.1002/cssc.201300945
104. [104]
  Lupp, D.; Christensen, N. J.; Dethlefsen, J. R.; Fristrup, P. Chem.-Eur. J. 2015, 21, 3435. doi: 10.1002/chem.v21.8
105. [105]
  Dethlefsen, J. R.; Lupp, D.; Teshome, A.; Nielsen, L. B.; Fristrup, P. ACS Catal. 2015, 5, 3638. doi: 10.1021/acscatal.5b00427
106. [106]
  Beckerle, K.; Sauer, A.; Spaniol, T. P.; Okuda, J. Polyhedron 2016, 116, 105. doi: 10.1016/j.poly.2016.03.053
107. [107]
  Sandbrink, L.; Beckerle, K.; Meiners, I.; Liffmann, R.; Rahimi, K.; Okuda, J.; Palkovits, R. ChemSusChem 2017, 10, 1375. doi: 10.1002/cssc.v10.7
108. [108]
  Chapman Jr., G.; Kenneth, M.; Nicholas, K. M. Chem. Commun. 2013, 49, 8199. doi: 10.1039/c3cc44656e
109. [109]
  Galindo, A. Inorg. Chem. 2016, 55, 2284. doi: 10.1021/acs.inorgchem.5b02649
110. [110]
  Poutas, L. C. V.; Reis, M. C.; Sanz, R.; Lopez, C. S.; Faza, O. N. Inorg. Chem. 2016, 55, 11372. doi: 10.1021/acs.inorgchem.6b01916
111. [111]
  Jiang, Y.; Jiang, J.; Fu, Y. Organometallics 2016, 35, 3388. doi: 10.1021/acs.organomet.6b00602
112. [112]
  Geary, L. M.; Chen, T. Y.; Montgomery, T. P.; Krische, M. J. J. Am. Chem. Soc. 2014, 136, 5920. doi: 10.1021/ja502659t
113. [113]
  Gopaladasu, T. V.; Nicholas, K. M. ACS Catal. 2016, 6, 1901. doi: 10.1021/acscatal.5b02667
114. [114]
  Kwok, K. M.; Choong, C. K. S.; Ong, D. S. W.; Ng, J. C. Q.; Gwie, C. G.; Chen, L.; Borgna, A. ChemCatChem 2017, 9, 2443. doi: 10.1002/cctc.v9.13
115. [115]
  Stanowski, S.; Nicholas, K. M.; Srivastava, R. S. Organometallics 2012, 31, 515. doi: 10.1021/om200447z
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  Xin MA , Ya SUN , Na SUN , Qian KANG , Jiajia ZHANG , Ruitao ZHU , Xiaoli GAO . A Tb₂ complex based on polydentate Schiff base: Crystal structure, fluorescence properties, and biological activity. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1347-1356. doi: 10.11862/CJIC.20230357
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8. [8]
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沈阳化工大学材料科学与工程学院沈阳 110142