Citation: Xi Zifan, Yuan Fanglong, Wang Zifei, Li Shuhua, Fan Louzhen. Highly Efficient and Stable Full-Color Random Lasing Emission Based on Carbon Quantum Dots[J]. Acta Chimica Sinica, ;2018, 76(6): 460-466. doi: 10.6023/A18020048 shu

Highly Efficient and Stable Full-Color Random Lasing Emission Based on Carbon Quantum Dots

College of Chemistry, Beijing Normal University, Beijing 100875

Corresponding author: Fan Louzhen, lzfan@bnu.edu.cn
Received Date: 1 February 2018
Available Online: 8 June 2018
Fund Project: Project supported by the National Natural Science Foundation of China (Key program, No. 21233003; General Program, No. 21573019), and the Fundamental Research Funds for the Central Universities

Figures(7)

The emerging fluorescent carbon quantum dots (CQDs) have shown enormous potentials in optoelectronic applications owing to their outstanding characteristics, such as tunable stable fluorescence emission, low cost, and environment-friendliness. However, the fluorescence of most reported CQDs is dominated by surface defects, which are in general energy dissipative, hard to support lasing emission. We have previously reported the bandgap emission CQDs from blue to red with a quantum yield (QY) over 50%, which is the highest value reported for bandgap emission CQDs. The bandgap transitions in CQDs were further confirmed by size-dependent optical properties through tansmission electron microscopy (TEM), which show uniform distribution nanoparticles with averge sizes of about 1.95, 2.41, 5.0 nm for blue, green and red CQDs, and their typical high-resolution TEM (HRTEM) images further indicates that most of the CQDs exhibit uniform atomic arrangements with high degree of crystallinity. By taking advantage of the high QY of CQDs, monochrome CQDs-based random lasing with low excitation threshold have been realized by using Au-Ag bimetallic porous nanowires as scatterers for the first time. The Au-Ag bimetallic porous nanowires possess a rough surface with Au nanoparticles and abundant nanogaps, leading to the extremely broadband surface plasmonic resonance peaks over the whole visible spectral range, which is benefit for efficient random lasing. The thresholds of the monochrome CQDs-based random lasers reached about 0.27, 0.21, 0.58 MW/cm² for blue, green and red, respectively. The full width at half maximum (FWHM) of the monochrome CQDs-based random lasers reached about 2.5, 1.9, 2.3 nm for blue, green and red, which is even comparable to the well-developed semiconductor QDs-based random lasers. The obtained random lasers show substantial stable emission color, which is of great significance for lasing display and lighting technology. Furthermore, white lasing with a CIE coordinate at (0.32, 0.33) was first demonstrated by combining red, green, blue fluorescent CQDs. This work does serve the purpose of understanding and providing significant opportunities for further improvements of CQDs-based lasers.
- carbon quantum dots,
- bandgap emission,
- random lasing,
- full-color,
- white laser
1. [1]
  Hill, M. T.; Gather, M. C. Nat. Photonics 2014, 8, 908. doi: 10.1038/nphoton.2014.239
2. [2]
  Luan, F.; Gu, B.; Gomes, A. S. L; Yong, K. T.; Wen, S. C.; Prasad, P. N. Nano Today 2015, 10, 168. doi: 10.1016/j.nantod.2015.02.006
3. [3]
  Wiersma, D. Nat. Phys. 2008, 4, 359. doi: 10.1038/nphys971
4. [4]
  Wiersma, D. Nature 2000, 406, 132.
5. [5]
  Wang, Y.; Duan, Z. J.; Qiu, Z.; Zhang, P.; Wu, J. W.; Zhang, D. K.; Xiang, T. X. Sci. Rep. 2017, 7, 8385. doi: 10.1038/s41598-017-08625-3
6. [6]
  Polson, R. C.; Vardeny, Z. V. Appl. Phys. Lett. 2004, 85, 1289. doi: 10.1063/1.1782259
7. [7]
  Fan, F.; Turkdogan, S.; Liu, Z. C.; Shelhammer, D.; Ning, C. Z. Nat. Nanotechnol. 2015, 10, 796. doi: 10.1038/nnano.2015.149
8. [8]
  Liu, Z. C.; Yin, L. J.; Ning, H.; Yang, Z. Y.; Tong, L. M.; Ning, C. Z. Nano Lett. 2013, 13, 4945. doi: 10.1021/nl4029686
9. [9]
  Lu, Y. J.; Wang, C. Y.; Kim, J.; Chen, H. Y.; Lu, M. Y.; Chen, Y. C.; Chang, W. H.; Chen, L. J.; Stockman, M. I.; Shih, C. K.; Gwo, S. Nano Lett. 2014, 14, 4381. doi: 10.1021/nl501273u
10. [10]
  Cai, P.; Jia, Y.; Feng, X. Y.; Li, J.; Li, J. B. Chin. J. Chem. 2017, 35, 881. doi: 10.1002/cjoc.v35.6
11. [11]
  Huang, L. ; Li, Z. C. ; Huang, S. Q. ; Reiss, P. ; Li, L. Acta Chim. Sinica 2017, 75, 300(in Chinese).
12. [12]
  Shao, Y. B.; Yue, J. L.; Sun, S.; Xia, H. Chin. J. Chem. 2017, 35, 73. doi: 10.1002/cjoc.v35.1
13. [13]
  Li, C. L.; Zang, Z. G.; Han, C.; H, Z. P.; Tang, X. S.; Du, J.; Leng, Y. X.; Sun, K. Nano Energy 2017, 40, 195. doi: 10.1016/j.nanoen.2017.08.013
14. [14]
  Li, Y. J; Lv, Y. C.; Zou, C. M.; Zhang, W.; Yao, J. N.; Zhao, Y. S. J. Am. Chem. Soc. 2016, 138, 2122. doi: 10.1021/jacs.5b12755
15. [15]
  Veldhuis, S. A.; Boix, P. P.; Yantara, N.; Li, M. J.; Sum, T. Z.; Mathews, N.; Mhaisalkar, S. G. Adv. Mater. 2016, 28, 6804. doi: 10.1002/adma.201600669
16. [16]
  Rauter, P.; Capasso, F. Laser Photonics Rev. 2015, 11, 565.
17. [17]
  Li, T. F.; Li, Y. W.; Xiao, L.; Yu, H. T.; Fan, L. Z. Acta Chim. Sinica 2014, 72, 227(in Chinese). doi: 10.3866/PKU.WHXB201312161
18. [18]
  Du, F. K.; Xu, J. S.; Zeng, F.; Wu, S, Z. Acta Chim. Sinica 2016, 74, 241(in Chinese).
19. [19]
  Li, S. H.; Zhou, S. X.; Li, Y. C.; Li, X. H.; Zhu, J.; Fan, L. Z.; Yang, S. H. ACS Appl. Mater. Interfaces 2017, 9, 22332. doi: 10.1021/acsami.7b07267
20. [20]
  Liu, Y. T.; Zhou, S. X.; Fan, L. Z.; Fan, H. Microchim. Acta 2016, 183, 2605. doi: 10.1007/s00604-016-1909-1
21. [21]
  Xie, R. B.; Wang, Z. F.; Yu, H. T.; Fan, Z. T.; Yuan, F. L.; Li, Y. C.; Li, X. H.; Fan, L. Z.; Fan, H. Electrochim. Acta 2016, 201, 220. doi: 10.1016/j.electacta.2016.03.198
22. [22]
  Guo, R. H.; Zhou, S. X.; Li, Y. C.; Li, X. H.; Fan, L. Z.; Voelcker, N. H. ACS Appl. Mater. Interfaces 2015, 7, 23958. doi: 10.1021/acsami.5b06523
23. [23]
  Li, S. H.; Li, Y. C.; Gao, J.; Zhu, J.; Fan, L. Z.; Li, X. H. Anal. Chem. 2014, 86, 1021.
24. [24]
  Fan, Z. T.; Zhou, S. X.; Garcia, C.; Fan, L. Z.; Zhou, J. B. Nanoscale 2017, 9, 4928. doi: 10.1039/C7NR00888K
25. [25]
  Yuan, F. L.; Ding, L.; Li, Y. C.; Li, X. H.; Fan, L. Z.; Zhou, S. X.; Fang, D. C.; Yang, S. H. Nanoscale 2015, 7, 11727 doi: 10.1039/C5NR02007G
26. [26]
  Fan, Z. T.; Li, S. H.; Yuan, F. L.; Fan, L. Z. RSC Adv. 2015, 5, 19773. doi: 10.1039/C4RA17131D
27. [27]
  Yuan, F. L.; Li, S. H.; Fan, Z. T.; Meng, X. Y.; Fan, L. Z.; Yang, S. H. Nano Today 2016, 11, 565. doi: 10.1016/j.nantod.2016.08.006
28. [28]
  Xie, R. B.; Wang, Z. F.; Liu, Y. T.; Fan, L. Z.; Li, Y. C.; Li, X. H.; Anal. Methods 2016, 8, 4001. doi: 10.1039/C6AY00289G
29. [29]
  Pan, L. L.; Sun, S.; Zhang, A. D.; Jiang, K.; Zhang, L.; Dong, C. Q.; Huang, Q.; Wu, A. G.; Lin, H. W. Anal. Methods 2012, 4, 58. doi: 10.1039/C1AY05366C
30. [30]
  Wang, Z. F.; Yuan, F. L.; Li, X. H.; Li, Y. C.; Zhong, H. Z.; Fan, L. Z.; Yang, S. H. Adv. Mater. 2017, 29, 1702910. doi: 10.1002/adma.v29.37
31. [31]
  Yuan, F. L.; Wang, Z. B.; Li, X. H.; Li, Y. C.; Tan, Z. A.; Fan, L. Z.; Yang, S. H. Adv. Mater. 2017, 29, 1604436. doi: 10.1002/adma.v29.3
32. [32]
  Xie, W. J.; Fu, Y. Y.; Ma, H.; Zhang, M.; Fan, L. Z. Acta Chim. Sinica 2012, 70, 2169(in Chinese).
33. [33]
  Zhang, M.; Bai, L. L.; Shang, W. H.; Xie, W. J.; Ma, H.; Fu, Y. Y.; Fang, D. C.; Sun, H.; Fan, L. Z.; Han, M.; Liu, C. M.; Yang, S. H. J. Mater. Chem. 2012, 22, 7461. doi: 10.1039/c2jm16835a
34. [34]
  Fan, Z. T.; Li, Y. C.; Li, X. H.; Fan, L. Z.; Zhou, S. X.; Fang, D. C.; Yang, S. H. Carbon 2014, 70, 149. doi: 10.1016/j.carbon.2013.12.085
35. [35]
  Tan, X. Y.; Li, Y. C.; Li, X. H.; Zhou, S. X.; Yang, S. H. Chem. Commun. 2015, 51, 2544. doi: 10.1039/C4CC09332A
36. [36]
  Shi, X. Y.; Wang, Y. R.; Wang, Z. N.; Wei, S. J.; Sun, Y. Y.; Liu, D. H.; Zhou, J.; Zhang, Y. Y.; Shi, J. W. Adv. Optical Mater. 2014, 2, 88. doi: 10.1002/adom.201300299
37. [37]
  Chen, R.; Utama, M. I. B.; Peng, Z. P.; Peng, B.; Xiong, Q. H.; Sun, H. D. Adv. Mater. 2011, 23, 1404. doi: 10.1002/adma.v23.11
1. [1]
  Shijie Li , Ke Rong , Xiaoqin Wang , Chuqi Shen , Fang Yang , Qinghong Zhang . Design of Carbon Quantum Dots/CdS/Ta₃N₅ S-Scheme Heterojunction Nanofibers for Efficient Photocatalytic Antibiotic Removal. Acta Physico-Chimica Sinica, 2024, 40(12): 2403005-. doi: 10.3866/PKU.WHXB202403005
2. [2]
  Chengcheng Si , Linshan Chai , Huiyuan Liu , Liye Sun , Shijian Cheng , Hailing Li , Wenyun Wang , Fang Liu , Qing Feng , Min Liu . Harry Potter China Tour Themed Innovative Science Popularization Experiment: Chemistry Magic Meets the Real World at Wuhan Station. University Chemistry, 2024, 39(9): 283-287. doi: 10.12461/PKU.DXHX202401069
3. [3]
  Zhenlin Zhou , Siyuan Chen , Yi Liu , Chengguo Hu , Faqiong Zhao . A New Program of Voltammetry Experiment Teaching Based on Laser-Scribed Graphene Electrode. University Chemistry, 2024, 39(2): 358-370. doi: 10.3866/PKU.DXHX202308049
4. [4]
  Tianlong Zhang , Jiajun Zhou , Hongsheng Tang , Xiaohui Ning , Yan Li , Hua Li . Virtual Simulation Experiment for Laser-Induced Breakdown Spectroscopy (LIBS) Analysis. University Chemistry, 2024, 39(6): 295-302. doi: 10.3866/PKU.DXHX202312049
5. [5]
  Zian Lin , Yingxue Jin . Matrix-Assisted Laser Desorption/Ionization Mass Spectrometry (MALDI-MS) for Disease Marker Screening and Identification: A Comprehensive Experiment Teaching Reform in Instrumental Analysis. University Chemistry, 2024, 39(11): 327-334. doi: 10.12461/PKU.DXHX202403066
6. [6]
  Miaomiao He , Zhiqing Ge , Qiang Zhou , Jiaqing He , Hong Gong , Lingling Li , Pingping Zhu , Wei Shao . Exploring the Fascinating Realm of Quantum Dots. University Chemistry, 2024, 39(6): 231-237. doi: 10.3866/PKU.DXHX202310040
7. [7]
  Jianjun Liu , Xue Yang , Chi Zhang , Xueyu Zhao , Zhiwei Zhang , Yongmei Chen , Qinghong Xu , Shao Jin . Preparation and Fluorescence Characterization of CdTe Semiconductor Quantum Dots. University Chemistry, 2024, 39(7): 307-315. doi: 10.3866/PKU.DXHX202311031
8. [8]
  Siyi ZHONG , Xiaowen LIN , Jiaxin LIU , Ruyi WANG , Tao LIANG , Zhengfeng DENG , Ao ZHONG , Cuiping HAN . Targeting imaging and detection of ovarian cancer cells based on fluorescent magnetic carbon dots. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1483-1490. doi: 10.11862/CJIC.20240093
9. [9]
  Zeyu XU , Anlei DANG , Bihua DENG , Xiaoxin ZUO , Yu LU , Ping YANG , Wenzhu YIN . Evaluation of the efficacy of graphene oxide quantum dots as an ovalbumin delivery platform and adjuvant for immune enhancement. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1065-1078. doi: 10.11862/CJIC.20240099
10. [10]
  Yueguang Chen , Wenqiang Sun . “Carbon” Adventures. University Chemistry, 2024, 39(9): 248-253. doi: 10.3866/PKU.DXHX202308074
11. [11]
  Lei Shu , Zimin Duan , Yushen Kang , Zijian Zhao , Hong Wang , Lihua Zhu , Hui Xiong , Nan Wang . An Exploration of the CO₂-Involved Carbon Cycle World. University Chemistry, 2024, 39(5): 144-153. doi: 10.3866/PKU.DXHX202309084
12. [12]
  Lei Shu , Zhengqing Hao , Kai Yan , Hong Wang , Lihua Zhu , Fang Chen , Nan Wang . Development of a Double-Carbon Related Experiment: Preparation, Characterization and Carbon-Capture Ability of Eggshell-Derived CaO. University Chemistry, 2024, 39(4): 149-156. doi: 10.3866/PKU.DXHX202310134
13. [13]
  Weina Wang , Fengyi Liu , Wenliang Wang . “Extracting Commonality, Delving into Typicals, Deriving Individuality”: Constructing a Knowledge Graph of Crystal Structures. University Chemistry, 2024, 39(3): 36-42. doi: 10.3866/PKU.DXHX202308029
14. [14]
  Liangyu Gong , Jie Wang , Fengyu Du , Lubin Xu , Chuanli Ma , Shihai Yan , Zhuwei Song , Fuheng Liu , Xiuzhong Wang . Construction and Practice of “One-Point, Two-Lines and Three-Sides” Innovative Experimental Platform. University Chemistry, 2024, 39(4): 26-32. doi: 10.3866/PKU.DXHX202308023
15. [15]
  Hongyan Feng , Weiwei Li . Reflections on the Safety of Chemical Science Popularization Activities. University Chemistry, 2024, 39(9): 379-384. doi: 10.12461/PKU.DXHX202404087
16. [16]
  Zizheng LU , Wanyi SU , Qin SHI , Honghui PAN , Chuanqi ZHAO , Chengfeng HUANG , Jinguo PENG . Surface state behavior of W doped BiVO₄ photoanode for ciprofloxacin degradation. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 591-600. doi: 10.11862/CJIC.20230225
17. [17]
  Dongju Zhang , Rongxiu Zhu . Construction of Ideological and Political Education in Quantum Chemistry Course: Several Teaching Cases to Reveal the Universal Connection of Things. University Chemistry, 2024, 39(7): 272-277. doi: 10.3866/PKU.DXHX202311032
18. [18]
  Peifeng Su , Xin Lu . Development of Undergraduate Quantum Mechanics Module in Chemistry Department under the “Double First Class” Initiative. University Chemistry, 2024, 39(8): 99-103. doi: 10.3866/PKU.DXHX202401087
19. [19]
  Haiping Wang . A Streamlined Method for Drawing Lewis Structures Using the Valence State of Outer Atoms. University Chemistry, 2024, 39(8): 383-388. doi: 10.12461/PKU.DXHX202401073
20. [20]
  Kai CHEN , Fengshun WU , Shun XIAO , Jinbao ZHANG , Lihua ZHU . PtRu/nitrogen-doped carbon for electrocatalytic methanol oxidation and hydrogen evolution by water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1357-1367. doi: 10.11862/CJIC.20230350

Get Citation

PDF

XML

Metrics

PDF Downloads(36)
Abstract views(2880)
HTML views(670)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142