Citation: Song Hao, Liu Xiaoyu, Qin Yong. Advances on Nitrogen-centered Radical Chemistry:A Photocatalytic N-H Bond Activation Approach[J]. Acta Chimica Sinica, ;2017, 75(12): 1137-1149. doi: 10.6023/A17080384 shu

Advances on Nitrogen-centered Radical Chemistry:A Photocatalytic N-H Bond Activation Approach

Key Laboratory of Drug Targeting and Drug Delivery Systems of the Ministry of Education, West China School of Pharmacy, Sichuan University, Chengdu 610041, China

Corresponding author: Qin Yong, yongqin@scu.edu.cn
Received Date: 23 August 2017
Available Online: 28 December 2017
Fund Project: the National Science and Technology Major Projects for "Major New Drugs Innovation and Development" 2017ZX09101005-009-002the National Natural Science Foundation of China 21732005Project supported by the National Natural Science Foundation of China (Nos. 21572140, 21732005) and the National Science and Technology Major Projects for "Major New Drugs Innovation and Development" (No. 2017ZX09101005-009-002)the National Natural Science Foundation of China 21572140

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Nitrogen-centered radicals are highly reactive intermediates, which provide new opportunities for designing new chemical reactions and preparing nitrogen-containing molecules. Direct generation of nitrogen-centered radicals via activation of N-H bonds under photocatalytic conditions has emerged as a green, efficient, and economical process, where significant progress has been made with methodology development in very recent years. In this paper, we highlight the important advances in this area that were reported since 2016.
- nitrogen-centered radical,
- visible light,
- photocatalyst,
- single-electron transfer,
- cascade reaction
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