Citation: Wang Yinhang, Li Wei, Luo Sha, Liu Shouxin, Ma Chunhui, Li Jian. Research Advances on the Applications of Immobilized Ionic Liquids Functional Materials[J]. Acta Chimica Sinica, ;2018, 76(2): 85-94. doi: 10.6023/A17070319 shu

Research Advances on the Applications of Immobilized Ionic Liquids Functional Materials

College of Material Science and Engineering, Northeast Forestry University, Harbin 150040

Corresponding author: Ma Chunhui, mchmchmchmch@163.com
Received Date: 14 July 2017
Available Online: 23 February 2017
Fund Project: the National Natural Science Foundation of China 31570567the Postdoctoral Scientific Research Developmental Fund of Heilongjiang Province in 2016 LBH-Q16001Project supported by the National Key R&D Program of China (No. 2017YFD0601006), the Central University Basic Research Expenses (Nos. 2572016BB01, 2572016BB02), the Postdoctoral Scientific Research Developmental Fund of Heilongjiang Province in 2016 (LBH-Q16001), the Research Start-up Funding of Introduce Talents in Northeast Forestry University (No. YQ2015-02), and the National Natural Science Foundation of China (Nos. 31500467, 31570567)the Central University Basic Research Expenses 2572016BB01the National Natural Science Foundation of China 31500467the Research Start-up Funding of Introduce Talents in Northeast Forestry University YQ2015-02the Central University Basic Research Expenses 2572016BB02the National Key R&D Program of China 2017YFD0601006

Figures(9)

As the biomass energy and green chemistry processes have gained more and more attention from researchers, ionic liquids as a novel green solvent were widely concerned by research teams since 1990s, because of many excellent properties of chemical stability, low viscosity, high conductivity and so on. The research on the preparation methods and application fields is getting better, especially in the fields of catalytic reaction, photoelectron chemistry, materials chemistry and biomass pretreatment. However, some disadvantages such as large consumption, high cost, hard to separate, and complexity in purification process were appeared. Thus, in recent years, many scholars tried to immobilize ILs on inorganic porous materials or organic polymer materials by physical adsorption or chemical grafting. In this way, the characteristics of ILs were transferred to the polyphase solid catalysts, and it can be applied to the continuous and closed fixed-bed reactions. In this review, the development of immobilized ionic liquid technology were summarized in detail, and the current applications of immobilized ionic liquid were illustrated with a multi-angle. The immobilized ionic liquid as catalysts were used in chemical catalytic field depending on the chemical structure of ionic liquid; While the immobilized ionic liquid as a functional materials were used in adsorption separation field depending on the surface characteristic of solid carrier.
- immobilized ionic liquid,
- catalyst,
- adsorbent material,
- application field
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沈阳化工大学材料科学与工程学院沈阳 110142