Citation: Xu Chenyu, Lin Jiayi, Pan Fuqiang, Deng Bowen, Wang Zhihua, Zhou Junhu, Chen Yun, Ma Jingcheng, Gu Zhien, Zhang Yanwei. Photo-thermochemical Cycle for CO₂ Reduction based on Effective Ni ion Substitute-doped TiO₂[J]. Acta Chimica Sinica, ;2017, 75(7): 699-707. doi: 10.6023/A17030083 shu

Photo-thermochemical Cycle for CO₂ Reduction based on Effective Ni ion Substitute-doped TiO₂

Xu Chenyu ^a ,
Lin Jiayi ^a ,
Pan Fuqiang ^a ,
Deng Bowen ^a ,
Wang Zhihua ^a ,
Zhou Junhu ^a ,
Chen Yun ^b ,
Ma Jingcheng ^b ,
Gu Zhien ^b ,
Zhang Yanwei ^a,*,,

a.
State Key Laboratory of Clean Energy Utilization, Zhejiang University, Hangzhou 310027
b.
Zhejiang Beilun Power Generation Co., Ningbo 315000

Corresponding author: Zhang Yanwei, zhangyw@zju.edu.cn
Received Date: 2 March 2017

Fund Project: National Natural Science Foundation of China 51276170the Fundamental Research Funds for the Central Universities 2017FZA4014the Innovative Research Groups of the National Natural Science Foundation of China 51621005

Figures(16)

To study the mechanism of the photo-thermochemical cycle (PTC), titanium dioxide (ST) and Ni-doped TiO₂(NT) films were produced using a sol-gel method and applied in the PTC for CO₂ reduction.And commercial P25(PT) has been used as a compared sample.A comparison of CO production shows that Ni-doped TiO₂ performed better than undoped TiO₂ and P25.Average CO production of NT PTCs was 5.30 μmol/g-cat and it was nearly 3.13 times of ST PTCs'CO production and 2.28 times of PT PTCs'.Scanning electron microscopy (SEM), transmission electron microscopy (TEM), energy-dispersive X-ray spectroscopy (EDXS) and X-ray diffraction (XRD) were used to assess the crystal structure and morphology of the films.Ni element could be found in NT by EDXS and inductively coupled plasma-atomic emission spectrometry (ICP-AES), and the mass fraction of Ni was 0.54% and 0.436% which were agreed with experiments.This result of XRD indicated that Ni²⁺ may have high dispersion without significant change in TiO₂ and Ni²⁺ ions were doped into the TiO₂ lattice so that Ni-O-Ti bonds were formed.Photoluminescence (PL), time-resolved PL, UV-visible diffuse reflectance spectra (UV-visible DRS) and X-ray photoelectron spectroscopy (XPS) analyses were also conducted to investigate the charge transfer and reaction mechanisms on the sample surface.The incorporation of Ni into TiO₂ resulted in a weaker PL intensity than that of bare TiO₂, which suggests that the introduction of Ni into TiO₂ effectively suppressed the undesirable recombination of electrons and holes.According to UV-visible DRS results, the Eg of PT is approximately 3.07 eV, which is smaller than that of ST (E_g=3.23 eV) and PT (E_g=3.20 eV).The narrower band gap of NT indicates that NT absorbed light with a wider wavelength range than that absorbed by ST and PT.By XPS patterns, the increase of Ni^+/0 and Ti³⁺ indicated that the VO may have been produced on the bond of Ni-O-Ti after UV illumination, and oxygen vacancies (VO) have been consumed after thermal step in PTC.Density functional theory (DFT) calculations related to the anatase (101) surface of TiO₂ and Ni doped TiO₂ was performed to verify and provide guidance for enhancing the PTC mechanism.Single and second VO formation energy have been calculated.The Ni-doped surface exhibits better performance than the undoped surface in the first step in PTC, because of its lower V_O formation energy which produce more V_O sites.Density of states (DOS) and partial density of states (PDOS) results indicated that narrow energy gap and impurity energy level of Ni-doped TiO₂ may lead to a wider wavelength range of NT.As a result, several key factors of the mechanism have been clarified.
- photo-thermal synergy,
- CO₂ conversion,
- oxygen vacancy,
- Ni substituted doping,
- DFT calculation
1. [1]
  Grob, G. R. Appl. Energ. 2003, 76, 39. doi: 10.1016/S0306-2619(03)00045-X
2. [2]
  Song, C. Catal. Today 2006, 115, 2. doi: 10.1016/j.cattod.2006.02.029
3. [3]
  Olah, G. A.; Prakash, G. K.; Goeppert, A. J. Am. Chem. Soc. 2011, 133, 12881. doi: 10.1021/ja202642y
4. [4]
  Yuan, Q.; Chen, X.; Wang, J.; Zhai, J. Acta Chim. Sinica 2014, 72, 624.
5. [5]
  Zhong, J.; Meng, Q.; Chen, B.; Tong, Z.; Wu, L. Acta Chim. Sinica 2017, 75, 34. doi: 10.3969/j.issn.0253-2409.2017.01.006
6. [6]
  Ying, Z.; Zhang, Y.; Xu, S.; Zhou, J.; Liu, J.; Wang, Z.; Cen, K. Int. J. Hydrogen Energ. 2014, 39, 18727. doi: 10.1016/j.ijhydene.2014.09.039
7. [7]
  Agrafiotis, C.; Roeb, M.; Sattler, C. Renew. Sust. Energ. Rev. 2015, 42, 254. doi: 10.1016/j.rser.2014.09.039
8. [8]
  Yu, W.; Xu, Difa.; Peng, T. J. Mater. Chem. A 2015, 3, 19936. doi: 10.1039/C5TA05503B
9. [9]
  Chen, J.; Du, X.; Yu, T.; Zeng, Y.; Zhang, X.; Li, Y. Acta Chim. Sinica 2016, 74, 523.
10. [10]
  Fletcher, E. A. J. Sol. Energ. 2001, 123, 63. doi: 10.1115/1.1349552
11. [11]
  William, C. C.; Christoph, F.; Mandy, A.; Danien, S.; Philipp, F.; Sossina, M. H.; Aldo, S. Science 2010, 330, 1797. doi: 10.1126/science.1197834
12. [12]
  Furler, P.; Scheffe, J. R.; Steinfeld, A. Energ. Environ. Sci. 2012, 5, 6098. doi: 10.1039/C1EE02620H
13. [13]
  Romero, M.; Steinfeld, A. Energ. Environ. Sci. 2012, 5, 9234. doi: 10.1039/c2ee21275g
14. [14]
  Arifin, D.; Aston, V. J.; Liang, X.; McDaniel, A. H.; Weimer, A. W. Energ. Environ. Sci. 2012, 5, 9438. doi: 10.1039/c2ee22090c
15. [15]
  Le Gal, A.; Abanades, S.; Flamant, G. Energ. Fuel. 2011, 25, 4836. doi: 10.1021/ef200972r
16. [16]
  Zhang, J.; Chen, Y. Acta Chim. Sinica 2017, 75, 41. doi: 10.7503/cjcu20160643
17. [17]
  Feng, B.; Muhammad, F, E.; Wei L.; Tao, H. Chin. J. Chem. 2015, 33, 112. doi: 10.1002/cjoc.v33.1
18. [18]
  Sun, D.; Li, Z. Chin. J. Chem. 2017, 35, 135. doi: 10.1002/cjoc.v35.2
19. [19]
  Zhang, Y.; Xu, C.; Chen, J.; Zhang, X.; Wang, Z.; Zhou, J.; Cen, K. Appl. Energ. 2015, 156, 223. doi: 10.1016/j.apenergy.2015.07.028
20. [20]
  Zhang, Y.; Chen, J.; Xu, C.; Zhou, K.; Wang, Z.; Zhou, J.; Cen, K. Int. J. Hydrogen Energ. 2016, 41, 2215. doi: 10.1016/j.ijhydene.2015.12.067
21. [21]
  Xu, C.; Zhang, Y.; Chen, J.; Lin, J.; Zhang, X.; Wang, Z.; Zhou, J. Appl. Catal. B-Environ. 2017, 204, 324. doi: 10.1016/j.apcatb.2016.11.027
22. [22]
  Fujishima, A.; Honda, K. Nature 1972, 238, 37. doi: 10.1038/238037a0
23. [23]
  He, Z.; Tang, J.; Shen, J.; Chen, J.; Song, S. Appl. Surf. Sci. 2016, 364, 416. doi: 10.1016/j.apsusc.2015.12.163
24. [24]
  Low, J.; Cheng, B.; Yu, J. Appl. Surf. Sci. 2017, 392, 658. doi: 10.1016/j.apsusc.2016.09.093
25. [25]
  Mei, T.; Harshkumar, H. P.; Matthew, S. S. Nature 2014, 508, 340. doi: 10.1038/nature13231
26. [26]
  Jiao, K.; Zhao, C.; Fang, P.; Mei, T. Tetrahedron Lett. 2017, 58, 797. doi: 10.1016/j.tetlet.2016.12.065
27. [27]
  Liu, X.; Liu, J.; Zhang, S.; Nan, Z.; Shi, Q. J. Phys. Chem. C 2016, 120, 1328. doi: 10.1021/acs.jpcc.5b10618
28. [28]
  Chang, S.-M.; Liu, W.-S. Appl. Catal. B-Environ. 2014, 466, 156.
29. [29]
  Li, A.; Li, J.; Liu, Y.; Zhang, J.; Zhao, L.; Lu, Y. Acta Chim. Sinica 2013, 71, 815.
30. [30]
  Chen, W.-T.; Chan, A.; Sun-Waterhouse, D.; Moriga, T.; Idriss, H.; Waterhouse, G. I. N. J. Catal. 2015, 326, 43. doi: 10.1016/j.jcat.2015.03.008
31. [31]
  Lin, X.; Lin, L.; Huang, K.; Chen, X.; Dai, W.; Fu, X. Appl. Catal. B-Environ. 2015, 416, 168.
32. [32]
  Liu, Y.; Wang, Z.; Fan, W.; Geng, Z.; Feng, L. Ceram. Int. 2014, 40, 3887. doi: 10.1016/j.ceramint.2013.08.030
33. [33]
  Do, J. Y.; Kwak, B. S.; Park, S.-M.; Kang, M. Int. J. Photoenergy 2016, 1.
34. [34]
  Shimoda, N.; Shoji, D.; Tani, K.; Fujiwara, M.; Urasaki, K.; Kikuchi, R.; Satokawa, S. A. Appl. Catal. B-Environ. 2015, 486, 174.
35. [35]
  Kho, E. T.; Scott, J.; Amal, R. Chem. Eng. Sci. 2016, 140, 161. doi: 10.1016/j.ces.2015.10.021
36. [36]
  Lai, L.-L.; Wen, W.; Wu, J.-M. RSC Adv. 2016, 6, 25511. doi: 10.1039/C6RA01752E
37. [37]
  Ohno, T.; Sarukawa, K.; Tokieda, K.; Matsumura, M. J. Catal. 2001, 203, 82. doi: 10.1006/jcat.2001.3316
38. [38]
  Zhang, Y.; Chen, J.; Li, X. Catal. Lett. 2010, 139, 129. doi: 10.1007/s10562-010-0425-x
39. [39]
  Yuan, J.; Wu, Q.; Zhang, P.; Yao, J.; He, T.; Cao, Y. Environ. Sci. Technol. 2012, 46, 2330. doi: 10.1021/es203333k
40. [40]
  Yan, Y.; Yu, Y.; Huang, S.; Yang, Y.; Yang, X.; Yin, S.; Cao, Y. J. Phys. Chem. C 2017, 121, 1089. doi: 10.1021/acs.jpcc.6b07180
41. [41]
  Cui, E.; Lu, G. Int. J. Hydrogen Energ. 2014, 39, 8959. doi: 10.1016/j.ijhydene.2014.03.258
42. [42]
  Kumar, V. V.; Naresh, G.; Deepa, S.; Bhavani, P. G.; Nagaraju, M.; Sudhakar, M.; Chary, K. V. R.; Tardio, J.; Bhargava, S. K.; Venugopal, A. Appl. Catal. A-Gen. 2017, 531, 169. doi: 10.1016/j.apcata.2016.10.032
43. [43]
  Liu, Q.; Ding, D.; Ning, C.; Wang, X. Int. J. Hydrogen Energ. 2015, 40, 2107. doi: 10.1016/j.ijhydene.2014.12.064
44. [44]
  Kim, D. H.; Kim, S. Y.; Han, S. W.; Cho, Y. K.; Jeong, M.-G.; Park, E. J.; Kim, Y. D. Appl. Catal. A-Gen. 2015, 495, 184. doi: 10.1016/j.apcata.2015.02.015
45. [45]
  Gao, M.; Jiang, D.; Sun, D.; Hou, B.; Li, D. Acta Chim. Sinica 2014, 72, 1092.
46. [46]
  Lin, C.-K.; Chuang, C.-C.; Raghunath, P.; Srinivasadesikan, V.; Wang, T. T.; Lin, M. C. Chem. Phys. Lett. 2017, 667, 278. doi: 10.1016/j.cplett.2016.10.082
47. [47]
  Chen, Q. L.; Li, B.; Zheng, G.; He, K. H.; Zheng, A. S. Physica B 2011, 406, 3841 doi: 10.1016/j.physb.2011.07.007
48. [48]
  Ma, J.; He, H.; Liu, F. Appl. Catal. B-Environ. 2015, 179, 21. doi: 10.1016/j.apcatb.2015.05.003
1. [1]
  Wenlong LI , Xinyu JIA , Jie LING , Mengdan MA , Anning ZHOU . Photothermal catalytic CO₂ hydrogenation over a Mg-doped In₂O_3-x catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 919-929. doi: 10.11862/CJIC.20230421
2. [2]
  Hao XU , Ruopeng LI , Peixia YANG , Anmin LIU , Jie BAI . Regulation mechanism of halogen axial coordination atoms on the oxygen reduction activity of Fe-N₄ site: A density functional theory study. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 695-701. doi: 10.11862/CJIC.20240302
3. [3]
  Qinjin DAI , Shan FAN , Pengyang FAN , Xiaoying ZHENG , Wei DONG , Mengxue WANG , Yong ZHANG . Performance of oxygen vacancy-rich V-doped MnO₂ for high-performance aqueous zinc ion battery. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 453-460. doi: 10.11862/CJIC.20240326
4. [4]
  Lina Guo , Ruizhe Li , Chuang Sun , Xiaoli Luo , Yiqiu Shi , Hong Yuan , Shuxin Ouyang , Tierui Zhang . 层状双金属氢氧化物的层间阴离子对衍生的Ni-Al₂O₃催化剂光热催化CO₂甲烷化反应的影响. Acta Physico-Chimica Sinica, 2025, 41(1): 2309002-. doi: 10.3866/PKU.WHXB202309002
5. [5]
  Meifeng Zhu , Jin Cheng , Kai Huang , Cheng Lian , Shouhong Xu , Honglai Liu . Classical Density Functional Theory for Understanding Electrochemical Interface. University Chemistry, 2025, 40(3): 148-152. doi: 10.12461/PKU.DXHX202405166
6. [6]
  Jin CHANG . Supercapacitor performance and first-principles calculation study of Co-doping Ni(OH)₂. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1697-1707. doi: 10.11862/CJIC.20240108
7. [7]
  Jiaxing Cai , Wendi Xu , Haoqiang Chi , Qian Liu , Wa Gao , Li Shi , Jingxiang Low , Zhigang Zou , Yong Zhou . 具有0D/2D界面的InOOH/ZnIn₂S₄空心球S型异质结用于增强光催化CO₂转化性能. Acta Physico-Chimica Sinica, 2024, 40(11): 2407002-. doi: 10.3866/PKU.WHXB202407002
8. [8]
  Yanhui XUE , Shaofei CHAO , Man XU , Qiong WU , Fufa WU , Sufyan Javed Muhammad . Construction of high energy density hexagonal hole MXene aqueous supercapacitor by vacancy defect control strategy. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1640-1652. doi: 10.11862/CJIC.20240183
9. [9]
  Hailang JIA , Hongcheng LI , Pengcheng JI , Yang TENG , Mingyun GUAN . Preparation and performance of N-doped carbon nanotubes composite Co₃O₄ as oxygen reduction reaction electrocatalysts. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 693-700. doi: 10.11862/CJIC.20230402
10. [10]
  Maomao Liu , Guizeng Liang , Ningce Zhang , Tao Li , Lipeng Diao , Ping Lu , Xiaoliang Zhao , Daohao Li , Dongjiang Yang . Electron-rich Ni2+ in Ni3S2 boosting electrocatalytic CO2 reduction to formate and syngas. Chinese Journal of Structural Chemistry, 2024, 43(8): 100359-100359. doi: 10.1016/j.cjsc.2024.100359
11. [11]
  Xiaoning TANG , Shu XIA , Jie LEI , Xingfu YANG , Qiuyang LUO , Junnan LIU , An XUE . Fluorine-doped MnO₂ with oxygen vacancy for stabilizing Zn-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1671-1678. doi: 10.11862/CJIC.20240149
12. [12]
  Lu XU , Chengyu ZHANG , Wenjuan JI , Haiying YANG , Yunlong FU . Zinc metal-organic framework with high-density free carboxyl oxygen functionalized pore walls for targeted electrochemical sensing of paracetamol. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 907-918. doi: 10.11862/CJIC.20230431
13. [13]
  Qin Hu , Liuyun Chen , Xinling Xie , Zuzeng Qin , Hongbing Ji , Tongming Su . Ni掺杂构建电子桥及激活MoS₂惰性基面增强光催化分解水产氢. Acta Physico-Chimica Sinica, 2024, 40(11): 2406024-. doi: 10.3866/PKU.WHXB202406024
14. [14]
  Jie ZHAO , Sen LIU , Qikang YIN , Xiaoqing LU , Zhaojie WANG . Theoretical calculation of selective adsorption and separation of CO₂ by alkali metal modified naphthalene/naphthalenediyne. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 515-522. doi: 10.11862/CJIC.20230385
15. [15]
  Min WANG , Dehua XIN , Yaning SHI , Wenyao ZHU , Yuanqun ZHANG , Wei ZHANG . Construction and full-spectrum catalytic performance of multilevel Ag/Bi/nitrogen vacancy g-C₃N₄/Ti₃C₂T_x Schottky junction. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1123-1134. doi: 10.11862/CJIC.20230477
16. [16]
  Wentao Lin , Wenfeng Wang , Yaofeng Yuan , Chunfa Xu . Concerted Nucleophilic Aromatic Substitution Reactions. University Chemistry, 2024, 39(6): 226-230. doi: 10.3866/PKU.DXHX202310095
17. [17]
  . . Chinese Journal of Inorganic Chemistry, 2024, 40(11): 0-0.
18. [18]
  Endong YANG , Haoze TIAN , Ke ZHANG , Yongbing LOU . Efficient oxygen evolution reaction of CuCo₂O₄/NiFe-layered bimetallic hydroxide core-shell nanoflower sphere arrays. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 930-940. doi: 10.11862/CJIC.20230369
19. [19]
  Wenjing ZHANG , Xiaoqing WANG , Zhipeng LIU . Recent developments of inorganic metal complex-based photothermal materials and their applications in photothermal therapy. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2356-2372. doi: 10.11862/CJIC.20240254
20. [20]
  Qianqian Liu , Xing Du , Wanfei Li , Wei-Lin Dai , Bo Liu . Synergistic Effects of Internal Electric and Dipole Fields in SnNb₂O₆/Nitrogen-Enriched C₃N₅ S-Scheme Heterojunction for Boosting Photocatalytic Performance. Acta Physico-Chimica Sinica, 2024, 40(10): 2311016-. doi: 10.3866/PKU.WHXB202311016

Get Citation

PDF

XML

Metrics

PDF Downloads(13)
Abstract views(2398)
HTML views(330)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Photo-thermochemical Cycle for CO2 Reduction based on Effective Ni ion Substitute-doped TiO2

Metrics

通讯作者: 陈斌, bchen63@163.com

Photo-thermochemical Cycle for CO₂ Reduction based on Effective Ni ion Substitute-doped TiO₂