Citation: Yang Tao, Cui Yanan, Chen Huaiyin, Li Weihua. Controllable Preparation of Two Dimensional Metal-or Covalent Organic Frameworks for Chemical Sensing and Biosensing[J]. Acta Chimica Sinica, ;2017, 75(4): 339-350. doi: 10.6023/A16110592 shu

Controllable Preparation of Two Dimensional Metal-or Covalent Organic Frameworks for Chemical Sensing and Biosensing

Yang Tao ^a ,
Cui Yanan ^a ,
Chen Huaiyin ^b ,
Li Weihua ^b,*,,

a.
College of Chemistry and Molecular Engineering, Qingdao University of Science and Technology, Qingdao 266042
b.
Key Laboratory of Marine Environmental Corrosion and Bio-fouling, Institute of Oceanology, Chinese Academy of Sciences, Qingdao 266071

Corresponding author: Li Weihua, ytlwh666@163.com
Received Date: 9 November 2016

Fund Project: Marine Science and Technology Projects of Huangdao District 2014-4-1the National Natural Science Foundation of China 41476083863 program 2015AA034404the National Natural Science Foundation of China 21275084the National Natural Science Foundation of China 51525903the National Natural Science Foundation of China 21675092

Figures(17)

In recent years, with the continuously deep and expanded researches of two-dimensional (2D) nanomaterials rep-resented by graphene, 2D framework materials represented by 2D metal-organic frameworks (MOFs) and covalent organic frameworks (COFs) have attracted great research interests and extensive attention. Compared with other mesoporous or mi-croporous nanomaterials, these organic framework materials provide uniformly nano-sized pores. And as compared to graphene, 2D organic framework materials can be expected to design and assemble the functionalized building units. For example, carboxyl group, amino group, hydroxyl group, etc. can be grafted onto the frameworks through various chemical reactions. These advantages are hopeful to make 2D organic framework materials a new generation of functional materials to improve the sensitivity and stability of the sensing interfaces. This review simply summarized 2D MOFs and COFs respectively, and generalized the current methods for preparing 2D MOFs and COFs nanomaterials based on "bottom-up" and "top-down" strategies and made simple comments. In addition, the applications of (2D) MOFs and COFs materials in chemical sensing and biosensing fields were introduced, and the potential and key problems of 2D MOFs and COFs in sensing applications were also discussed. And at last, this review gives some outlook for the future applications of 2D MOFs and COFs nanomaterials.
- metal-organic frameworks,
- covalent organic frameworks,
- two-dimensional nanomaterials,
- sensing,
- fluorescence,
- electrochemistry
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