Citation: Yang Xiangping, Guo Xiaoxue, Zhang Chenghua, Wang Xiaoping, Yang Yong, Li Yongwang. Synthesis and Catalytic Properties of Iron Based Fischer-Tropsch Catalyst Mediated by MOFs Fe-MIL-100[J]. Acta Chimica Sinica, ;2017, 75(4): 360-366. doi: 10.6023/A16100549 shu

Synthesis and Catalytic Properties of Iron Based Fischer-Tropsch Catalyst Mediated by MOFs Fe-MIL-100

Yang Xiangping ^a ,
Guo Xiaoxue ^a ,
Zhang Chenghua ^b,c ,
Wang Xiaoping ^b ,
Yang Yong ^b,c ,
Li Yongwang ^b,c,*,,

a.
College of Chemical Engineering, China University of Petroleum (HD), Qingdao 266000
b.
National Engineering Laboratory of Coal Indirect Liquefaction, Synfuels CHINA Co. Ltd., Beijing 101407
c.
State Key Laboratory of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001

Corresponding author: Li Yongwang, zhangchh@sxicc.ac.cn
Received Date: 15 October 2016

Fund Project: the National Natural Science Foundation of China 91545109International Cooperation in Science and Technology of Shanxi Province 2014081004

Figures(8)

Depletion of crude oil resources and environmental concerns have spurred worldwide interest in finding un-oil route for liquid fuels. Fischer-Tropsch synthesis is an effective progress for a wide spectrum of hydrocarbon chains from synthesis gas. The use of iron-based catalysts would be preferred in the industry. Here we present a strategy to produce highly dispersed active component embedded in a matrix of porous carbon. Through the carbonization of iron-containing metal-organic frameworks (Fe-MIL-100) at different temperature in N₂, four kinds of Fe@C catalysts were prepared. Glucose was used as additional carbon precursor for the synthesis catalyst samples to prevent particle agglomeration. Our strategy avoids the particle agglomeration in the weak metal-support interaction Fe@C catalysts during calcination, reduction and reaction. The structure and morphology of prepared catalysts were characterized by X-ray diffraction (XRD), N₂ physical adsorption, transmission electron microscopy (TEM), inductively coupled plasma-atomic emission spectrometer (ICP-AES). It is demonstrated that the iron loading, the particle size, and the Fe phase structure of Fe@C catalysts can be controlled by changing the carbonization temperature of Fe-MIL-100. With increasing the temperature, the iron loading and the particle size increase gradually. Depending on the carbonization temperature, the Fe₃O₄ phase is dominant at 400 and 500℃. The FeO and Fe phase appear at 600℃. The Fe₃C phase prevails at 700℃. The high dispersion of the metal phase and its encapsulation in a highly porous carbon matrix result in an unrivalled FTS activity. The spatial restriction created by encapsulation seems to minimize sintering and oxidation of the active Hägg carbide phase. When the reaction conditions were set at 260℃, 3 MPa, the space velocity of 8000 h^-1, the conversion of CO is up to 68%. The Fe time yield (FTY) of the Fe@C-500 catalyst were as high as 164 μmol_CO·g_Fe^-1·s^-1, which surpasses that of most F-T catalysts reported in the literature in middle-temperature Fischer-Tropsch synthesis.
- Fischer-Tropsch synthesis,
- iron-based Fischer-Tropsch catalysts,
- iron carbide phases,
- metal organic frameworks,
- Fe-MIL-100
1. [1]
  Yang, W. S.; Fang, D. Y.; Xiang, H. W.; Li, Y. W. Acta Chim. Sinica 2005, 63, 157. doi: 10.3321/j.issn:0567-7351.2005.02.012
2. [2]
  Gao, L.; Xu, Y.; Hou, B.; Wu, D.; Sun, Y. H. Acta Chim. Sinica 2008, 66, 1851. doi: 10.3321/j.issn:0567-7351.2008.16.001
3. [3]
  Zhang, J.; Zhang, Z.-P.; Su, J.-J.; Fu, D.-L.; Dai, W.-W.; Liu, D.; Xu, J.; Han, Y.-F. CIESC J. 2016, 67, 550.
4. [4]
  Suo, H.-Y.; Wang, S.-G.; Zhang, C.-H.; Xu, J.; Wu, B.-S.; Yang, Y.; Xiang, H.-W.; Li, Y.-W. J. Catal. 2012, 286, 111. doi: 10.1016/j.jcat.2011.10.024
5. [5]
  Krylova, A. Y.; Panin, A. A.; Lyadov, A. S.; Sagitov, S. A.; Kurkon, V. I.; Kryazhev, Y. G. Petrol. Chem. 2011, 51, 317. doi: 10.1134/S0965544111050094
6. [6]
  Abbaslou, R. M. M.; Tavasoli, A.; Dalai, A. K. Appl. Catal. A-General 2009, 355, 33. doi: 10.1016/j.apcata.2008.11.023
7. [7]
  Lv, J.-Z.; Hu, R.-Z.; Zhuo, O.; Xu, B.-L.; Yang, L.-J.; Wu, Q.; Wang, X.-Z.; Fan, Y.-N.; Hu, Z. Acta Chim. Sinica 2014, 72, 1017. doi: 10.3866/PKU.WHXB201401251
8. [8]
  deKrafft, K. E.; Wang, C.; Lin, W. Adv. Mater. 2014, 24, 2014.
9. [9]
  Gascon, J.; Corma, A.; Kapteijn, F.; Llabrés, I.; Xamena, F. X. ACS Catal. 2014, 4, 361. doi: 10.1021/cs400959k
10. [10]
  Masoomi, M. Y.; Morsali, A. Coord. Chem. Rev. 2012, 256, 2921. doi: 10.1016/j.ccr.2012.05.032
11. [11]
  Wang, C.; Xie, Z.-G.; Kathryn, E. J. Am. Chem. Soc. 2011, 133, 13445. doi: 10.1021/ja203564w
12. [12]
  Liu, B.; Shioyama, H.; Jiang, H.; Zhang, X.; Xu, Q. Carbon 2010, 48, 456. doi: 10.1016/j.carbon.2009.09.061
13. [13]
  Santos, V. P.; Wezendonk, T. A.; Jaén, J. J. D.; Dugulan, A. L.; Nasalevich, M. A.; Islam, H.-U.; Chojecki, A.; Sartipi, S.; Sun, X. H.; Hakeem. A. A.; Koeken, A. C. J.; Ruitenbeek, M.; Davidian, T.; Meima, G. R.; Sankar, G.; Kapeijn, F.; Makkee, M.; Gascon, J. Nat. Commun. 2015, 6, 6451. doi: 10.1038/ncomms7451
14. [14]
  Horcajada, P.; Surblé, S.; Serre, C.; Hong, D.-Y.; Seo, Y.-K.; Chang, J.-C.; Grenéche, J.-M.; Margiolaki, I.; Frey, G. ChemComm 2007, 27, 2820.
15. [15]
  Fang, C. M.; Sluiter, M. H. F.; Huis, M. A.; Ande, C. K.; Zandbergen, H. W. Phys. Rev. Lett. 2010, 105, 055503. doi: 10.1103/PhysRevLett.105.055503
16. [16]
  Merkle, R.; Maier, J. Z. Anorg. Allg. Chem. 2005, 631, 1163. doi: 10.1002/(ISSN)1521-3749
17. [17]
  Qiu, C. W.; Wu, B. S.; Meng, S. C.; Li, Y. W. Acta Chim. Sinica 2015, 73, 690.
18. [18]
  Park, J. Y.; Lee, Y. J.; Khanna, P. K.; Jun, K. W.; Bae, J. W.; Kim, Y. H. J. Mol. Catal. A 2010, 323, 84. doi: 10.1016/j.molcata.2010.03.025
19. [19]
  Yang, C.; Zhao, H.; Hou, Y.; Ma, D. J. Am. Chem. Soc. 2012, 134, 15814. doi: 10.1021/ja305048p
20. [20]
  Zhang, Q.; Kang, J.; Wang, Y. ChemCatChem 2010, 2, 1030. doi: 10.1002/cctc.201000071
21. [21]
  Wezendonk, T. A.; Santos, V. P.; Nasalevich, M. A.; Warringa, Q. S. E.; Dugulan, A. L.; Chojecki, A.; Koeken, C. J.; Ruitenbeek, M.; Meima, G.; Islam, H.-U.; Sankar, G.; Makkee, M.; Kapteijn, F.; Gascon, H.-U. ACS Catal. 2016, 6, 3236. doi: 10.1021/acscatal.6b00426
22. [22]
  Yu, G.; Sun, B.; Pei, Y.; Xie, S.; Yan, S.; Qiao, M.; Fan, K.; Zhang, X.; Zong, B. J. J. Am. Chem. Soc. 2010, 132, 935. doi: 10.1021/ja906370b
1. [1]
  Tianyun Chen , Ruilin Xiao , Xinsheng Gu , Yunyi Shao , Qiujun Lu . Synthesis, Crystal Structure, and Mechanoluminescence Properties of Lanthanide-Based Organometallic Complexes. University Chemistry, 2024, 39(5): 363-370. doi: 10.3866/PKU.DXHX202312017
2. [2]
  Zelong LIANG , Shijia QIN , Pengfei GUO , Hang XU , Bin ZHAO . Synthesis and electrocatalytic CO₂ reduction performance of metal-organic framework catalysts loaded with silver particles. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 165-173. doi: 10.11862/CJIC.20240409
3. [3]
  Xiaoling LUO , Pintian ZOU , Xiaoyan WANG , Zheng LIU , Xiangfei KONG , Qun TANG , Sheng WANG . Synthesis, crystal structures, and properties of lanthanide metal-organic frameworks based on 2, 5-dibromoterephthalic acid ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1143-1150. doi: 10.11862/CJIC.20230271
4. [4]
  Yuanpei ZHANG , Jiahong WANG , Jinming HUANG , Zhi HU . Preparation of magnetic mesoporous carbon loaded nano zero-valent iron for removal of Cr(Ⅲ) organic complexes from high-salt wastewater. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1731-1742. doi: 10.11862/CJIC.20240077
5. [5]
  Jiaming Xu , Yu Xiang , Weisheng Lin , Zhiwei Miao . Research Progress in the Synthesis of Cyclic Organic Compounds Using Bimetallic Relay Catalytic Strategies. University Chemistry, 2024, 39(3): 239-257. doi: 10.3866/PKU.DXHX202309093
6. [6]
  Wenjie SHI , Fan LU , Mengwei CHEN , Jin WANG , Yingfeng HAN . Synthesis and host-guest properties of imidazolium-functionalized zirconium metal-organic cage. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 105-113. doi: 10.11862/CJIC.20240360
7. [7]
  Jingjing QING , Fan HE , Zhihui LIU , Shuaipeng HOU , Ya LIU , Yifan JIANG , Mengting TAN , Lifang HE , Fuxing ZHANG , Xiaoming ZHU . Synthesis, structure, and anticancer activity of two complexes of dimethylglyoxime organotin. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1301-1308. doi: 10.11862/CJIC.20240003
8. [8]
  Liang TANG , Jingfei NI , Kang XIAO , Xiangmei LIU . Synthesis and X-ray imaging application of lanthanide-organic complex-based scintillators. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1892-1902. doi: 10.11862/CJIC.20240139
9. [9]
  Youlin SI , Shuquan SUN , Junsong YANG , Zijun BIE , Yan CHEN , Li LUO . Synthesis and adsorption properties of Zn(Ⅱ) metal-organic framework based on 3, 3', 5, 5'-tetraimidazolyl biphenyl ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1755-1762. doi: 10.11862/CJIC.20240061
10. [10]
  Hong CAI , Jiewen WU , Jingyun LI , Lixian CHEN , Siqi XIAO , Dan LI . Synthesis of a zinc-cobalt bimetallic adenine metal-organic framework for the recognition of sulfur-containing amino acids. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 114-122. doi: 10.11862/CJIC.20240382
11. [11]
  Li'na ZHONG , Jingling CHEN , Qinghua ZHAO . Synthesis of multi-responsive carbon quantum dots from green carbon sources for detection of iron ions and L-ascorbic acid. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 709-718. doi: 10.11862/CJIC.20240280
12. [12]
  Yi DING , Peiyu LIAO , Jianhua JIA , Mingliang TONG . Structure and photoluminescence modulation of silver(Ⅰ)-tetra(pyridin-4-yl)ethene metal-organic frameworks by substituted benzoates. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 141-148. doi: 10.11862/CJIC.20240393
13. [13]
  Fugui XI , Du LI , Zhourui YAN , Hui WANG , Junyu XIANG , Zhiyun DONG . Functionalized zirconium metal-organic frameworks for the removal of tetracycline from water. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 683-694. doi: 10.11862/CJIC.20240291
14. [14]
  Jiapei Zou , Junyang Zhang , Xuming Wu , Cong Wei , Simin Fang , Yuxi Wang . A Comprehensive Experiment Based on Electrocatalytic Nitrate Reduction into Ammonia: Synthesis, Characterization, Performance Exploration, and Applicable Design of Copper-based Catalysts. University Chemistry, 2024, 39(6): 373-382. doi: 10.3866/PKU.DXHX202312081
15. [15]
  Xiangyu CAO , Jiaying ZHANG , Yun FENG , Linkun SHEN , Xiuling ZHANG , Juanzhi YAN . Synthesis and electrochemical properties of bimetallic-doped porous carbon cathode material. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 509-520. doi: 10.11862/CJIC.20240270
16. [16]
  Feng Sha , Xinyan Wu , Ping Hu , Wenqing Zhang , Xiaoyang Luan , Yunfei Ma . Design of Course Ideology and Politics for the Comprehensive Organic Synthesis Experiment of Benzocaine. University Chemistry, 2024, 39(2): 110-115. doi: 10.3866/PKU.DXHX202307082
17. [17]
  Xinyu Zhu , Meili Pang . Application of Functional Group Addition Strategy in Organic Synthesis. University Chemistry, 2024, 39(3): 218-230. doi: 10.3866/PKU.DXHX202308106
18. [18]
  Wenxiu Yang , Jinfeng Zhang , Quanlong Xu , Yun Yang , Lijie Zhang . Bimetallic AuCu Alloy Decorated Covalent Organic Frameworks for Efficient Photocatalytic Hydrogen Production. Acta Physico-Chimica Sinica, 2024, 40(10): 2312014-. doi: 10.3866/PKU.WHXB202312014
19. [19]
  Jiaojiao Yu , Bo Sun , Na Li , Cong Wen , Wei Li . Improvement of Classical Organic Experiment Based on the “Reverse-Step Optimization Method”: Taking Synthesis of Ethyl Acetate as an Example. University Chemistry, 2025, 40(3): 333-341. doi: 10.12461/PKU.DXHX202405177
20. [20]
  Mengzhen JIANG , Qian WANG , Junfeng BAI . Research progress on low-cost ligand-based metal-organic frameworks for carbon dioxide capture from industrial flue gas. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 1-13. doi: 10.11862/CJIC.20240355

Get Citation

PDF

XML

Metrics

PDF Downloads(12)
Abstract views(1976)
HTML views(503)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142