Citation: Du Jin, Lin Ning, Qian Yitai. Recent Development of the Synthetic Method for Si/Graphite Anode Materials[J]. Acta Chimica Sinica, ;2017, 75(2): 147-153. doi: 10.6023/A16100548 shu

Recent Development of the Synthetic Method for Si/Graphite Anode Materials

Department of Chemistry, University of Science and Technology of China, Hefei 230026

Corresponding author: Lin Ning, ningl@mail.ustc.edu.cn
Received Date: 15 October 2016

Fund Project: Project supported by the National Postdoctoral Program for Innovative Talents No. BX201600140and the China Postdoctoral Science Foundation funded Project No. 2016M600484

Figures(8)

Rechargeable lithium-ion batteries (LIBs) are recognized as the most important power supply for portable electronic devices, electric vehicle and hybrid electric vehicle. There is a continuing demand for advanced LIBs with longer life spans and higher capacity. Graphite based anode materials are now widely employed in LIBs due to their excellent cycling stability and good conductivity. However, the theoretical capacity of graphite is as low as 372 mA·h·g^-1 that is hard to meet the ever-increasing demand of high energy density LIBs. Recent years, Si based anode materials have attracted enormous attention due to its high reversible capacity (3579 mA·h·g^-1). However, the main challenge facing Si is the huge volume change during lithiation/delithiation process. It is well accepted that nanostructured Si could effectively release the strain stress caused by volume variation, thus maintaining the conductive and structural integrity of the electrode. But, the high surface area of nanostructured anode materials would result in serious side reactions between electrode materials and electrolyte, which would consume a lot of Li⁺, and leading to low coulombic efficiency. Very recently, preparation of nano-Si/graphite composite as anode for LIBs has been demonstrated as a promising high-capacity anode. The Si/graphite anode is able to take full advantages of the properties of these two materials such as the high specific capacity of nano-sized Si, mechanical flexibility and good conductivity of graphite. These beneficial features make Si/graphite hybrid composite as an ideal anode candidate for high-performance LIBs. To date, a lot of fabricating strategies have been reported to prepare Si/graphite composite. The keys and interests are focused on how to make the nanosized Si and graphite particles distributed uniformly, and how to construct a stable framework with three-dimensional conductive network. An overview of the methodologies proposed in the last decade for combining nanosized Si and graphite is summarized, which are composed of a series of technological means. Here, these methodologies are classified in three categories on basis of the composite step, including solid-state approach, liquid-phase mixture method, and chemical vapor deposition process.
- silicon,
- graphite,
- anode materials,
- synthetic method,
- Li-ion batteries
1. [1]
  (a) Whittingham, M. S. Chem. Rev. 2004, 104, 4271.(b) Li, H.; Wang, Z.; Chen, L.; Huang, X. Adv. Mater. 2009, 21, 4593.(c) Goodenough, J. B.; Kim, Y. Chem. Mater. 2009, 22, 587.(d) Larcher, D.; Tarascon, J. M. Nat. Chem. 2015, 7, 19.
2. [2]
3. [3]
4. [4]
5. [5]
6. [6]
  (a) Yoshio, M.; Wang, H.; Fukuda, K.; Umeno, T.; Abe, T.; Ogumi, Z. J. Mater. Chem. 2004, 14, 1754.(b) Courtel, F. M.; Niketic, S.; Duguay, D.; Abu-Lebdeh, Y.; Davidson, I. J. J. Power Sources 2011, 196, 2128.(c) Yoshio, M.; Wang, H.; Fukuda, K.; Hara, Y.; Adachi, Y. J. Electrochem. Soc. 2000, 147, 1245.(d) Yang, S.; Song, H.; Chen, X. Electrochem. Commun. 2006, 8, 137.
7. [7]
8. [8]
  Lee, J. K.; Oh, C.; Kim, N.; Hwang, J. Y.; Sun, Y. K. J. Mater. Chem. A 2016, 4, 5366.
9. [9]
  Li, H.; Wang, Z.; Chen, L.; Huang, X. Adv. Mater. 2009, 21, 4593.
10. [10]
  Wilson, A. M.; Way, B. M.; Dahn, J. R.; Van Buuren, T. J. Appl. Phys. 1995, 77, 2363.
11. [11]
  Yuan, L. X.; Wang, Z. H.; Zhang, W. X.; Hu, X. L.; Chen, J. T.; Huang, Y. H.; Goodenough, J. B. Energ. Environ. Sci. 2011, 4, 269.
12. [12]
  Wu, H.; Cui, Y. Nano Today 2012, 7, 414.
13. [13]
  Li, H.; Huang, X.; Chen, L.; Wu, Z.; Liang, Y. Electrochem. Solid St. 1999, 2, 547.
14. [14]
  Choi, J. W.; Cui, Y.; Nix, W. D. J. Mech. Phys. Solids 2011, 59, 1717.
15. [15]
  Liu, X. H.; Zhong, L.; Huang, S.; Mao, S. X.; Zhu, T.; Huang, J. Y. ACS Nano 2012, 6, 1522.
16. [16]
  McDowell, M. T.; Lee, S. W.; Harris, J. T.; Korgel, B. A.; Wang, C.; Nix, W. D.; Cui, Y. Nano Lett. 2013, 13, 758.
17. [17]
  Li, J.; Dozier, A. K.; Li, Y.; Yang, F.; Cheng, Y. T. J. Electrochem. Soc. 2011, 158, A689.
18. [18]
  Gómez-Cámer, J.-L.; Bünzl, C.; Hantel, M.-M. Carbon 2016, 105, 42.
19. [19]
  Zhao, H.; Du, A.; Ling, M.; Battaglia, V.; Liu, G. Electrochim. Acta 2016, 209, 159.
20. [20]
  Lee, H.-Y.; Lee, S.-M. J. Power Sources 2002, 112, 649.
21. [21]
  Yu, H.-J.; Liu, X.-L.; Chen, Y.-X.; Liu, H.-B. Ionics 2016, 22, 1847.
22. [22]
  Dash, R.; Pannala, S. Sci. Rep. 2016, 6, 27449.
23. [23]
24. [24]
  Dimov, N.; Kugino, S.; Yoshio, M. J. Power Sources 2004, 136, 108.
25. [25]
  Wang, P.; Li, Y.-N.; Yang, J.; Zheng, Y. Int. J. Electrochem. Sci. 2006, 1, 122.
26. [26]
  Lee, H.-Y.; Lee, S.-M. Electrochem. Commun. 2004, 6, 465.
27. [27]
  Zhang, Y.; Zhang, X. G.; Zhang, H. L.; Zhao, Z. G.; Li, F.; Liu, C.; Cheng, H. M. Electrochim. Acta 2006, 51, 4994.
28. [28]
  Xu, W.; Flake, J. C. J. Electrochem. Soc. 2010, 157, A41.
29. [29]
  Zuo, P.; Yin, G.; Tong, Y. Solid State Ionics 2006, 177, 3297.
30. [30]
  Zhou, W.; Upreti, S.; Whittingham, M. S. Electrochem. Commun. 2011, 13, 158.
31. [31]
  Jo, Y. N.; Kim, Y.; Kim, J. S.; Song, J. H.; Kim, K. J.; Kwag, C. Y.; Lee, D. J.; Park, C. W.; Kim, Y. J. J. Power Sources 2010, 195, 6031.
32. [32]
  Lai, J.; Guo, H.-J.; Wang, Z.-X.; Li, X.-H.; Zhang, X.-P.; Wu, F.-X. Yue, P. J. Alloy. Compd. 2012, 530, 30.
33. [33]
  Gan, L.; Guo, H.-J.; Wang, Z.-X.; Li, X.-H.; Peng, W.-J.; Wang, J.-X.; Huang, S.-L.; Su, M.-R. Electrochim. Acta 2013, 104, 117.
34. [34]
  Yu, J.; Zhan, H.-H.; Wang, Y.-Y.; Zhang, Z.-L.; Chen, H.; Li, H.; Zhong, Z.; Su, F.-B. J. Power Sources 2013, 228, 112.
35. [35]
  Li, J.; Wang, J.-T.; Yang, J.-Y.; Ma, X.-L.; Lu, S.-G. J. Alloy. Compd. 2016, 688, 1072.
36. [36]
  Zhou, R.; Fan, R.; Tian, Z.; Zhou, Y.; Guo, H.; Kou, L.; Zhang, D. J. Alloy. Compd. 2016, 658, 91.
37. [37]
  Wang, H.; Xie, J.; Zhang, S.; Cao, G.; Zhao, X. RSC Adv. 2016, 6, 69882.
38. [38]
  Zhang, L.; Wang, Y.; Kan, G.; Zhang, Z.; Wang, C.; Zhong, Z.; Su, F. RSC Adv. 2014, 4, 43114.
39. [39]
  Kim, S.-Y.; Lee, J.; Kim, B.-H. ACS Appl. Mater. Interf. 2016, 8, 12109.
40. [40]
  Holzapfel, M.; Buqa, H.; Krumeich, F.; Novak, P.; Petrat, F. M.; Veit, C. Electrochem. Solid St. 2005, 8, A516.
41. [41]
  Jeong, S.; Lee, J. P.; Ko, M.; Kim, G.; Park, S.; Cho, J. Nano Lett. 2013, 13, 3403.
42. [42]
  Ko, M.; Chae, S.; Ma, J.; Kim, N.; Lee, H. W.; Cui, Y.; Cho, J. Nat. Energy 2016, 1, 16113.
1. [1]
  Qi Li , Pingan Li , Zetong Liu , Jiahui Zhang , Hao Zhang , Weilai Yu , Xianluo Hu . Fabricating Micro/Nanostructured Separators and Electrode Materials by Coaxial Electrospinning for Lithium-Ion Batteries: From Fundamentals to Applications. Acta Physico-Chimica Sinica, 2024, 40(10): 2311030-. doi: 10.3866/PKU.WHXB202311030
2. [2]
  Yuanchao LI , Weifeng HUANG , Pengchao LIANG , Zifang ZHAO , Baoyan XING , Dongliang YAN , Li YANG , Songlin WANG . Effect of heterogeneous dual carbon sources on electrochemical properties of LiMn_0.8Fe_0.2PO₄/C composites. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 751-760. doi: 10.11862/CJIC.20230252
3. [3]
  Qingtang ZHANG , Xiaoyu WU , Zheng WANG , Xiaomei WANG . Performance of nano Li₂FeSiO₄/C cathode material co-doped by potassium and chlorine ions. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1689-1696. doi: 10.11862/CJIC.20240115
4. [4]
  Siyu Zhang , Kunhong Gu , Bing'an Lu , Junwei Han , Jiang Zhou . Hydrometallurgical Processes on Recycling of Spent Lithium-lon Battery Cathode: Advances and Applications in Sustainable Technologies. Acta Physico-Chimica Sinica, 2024, 40(10): 2309028-. doi: 10.3866/PKU.WHXB202309028
5. [5]
  Zhihuan XU , Qing KANG , Yuzhen LONG , Qian YUAN , Cidong LIU , Xin LI , Genghuai TANG , Yuqing LIAO . Effect of graphene oxide concentration on the electrochemical properties of reduced graphene oxide/ZnS. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1329-1336. doi: 10.11862/CJIC.20230447
6. [6]
  Xinpeng LIU , Liuyang ZHAO , Hongyi LI , Yatu CHEN , Aimin WU , Aikui LI , Hao HUANG . Ga₂O₃ coated modification and electrochemical performance of Li_1.2Mn_0.54Ni_0.13Co_0.13O₂ cathode material. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1105-1113. doi: 10.11862/CJIC.20230488
7. [7]
  Junke LIU , Kungui ZHENG , Wenjing SUN , Gaoyang BAI , Guodong BAI , Zuwei YIN , Yao ZHOU , Juntao LI . Preparation of modified high-nickel layered cathode with LiAlO₂/cyclopolyacrylonitrile dual-functional coating. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1461-1473. doi: 10.11862/CJIC.20240189
8. [8]
  Limei CHEN , Mengfei ZHAO , Lin CHEN , Ding LI , Wei LI , Weiye HAN , Hongbin WANG . Preparation and performance of paraffin/alkali modified diatomite/expanded graphite composite phase change thermal storage material. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 533-543. doi: 10.11862/CJIC.20230312
9. [9]
  Doudou Qin , Junyang Ding , Chu Liang , Qian Liu , Ligang Feng , Yang Luo , Guangzhi Hu , Jun Luo , Xijun Liu . Addressing Challenges and Enhancing Performance of Manganese-based Cathode Materials in Aqueous Zinc-Ion Batteries. Acta Physico-Chimica Sinica, 2024, 40(10): 2310034-. doi: 10.3866/PKU.WHXB202310034
10. [10]
  Zhihong LUO , Yan SHI , Jinyu AN , Deyi ZHENG , Long LI , Quansheng OUYANG , Bin SHI , Jiaojing SHAO . Two-dimensional silica-modified polyethylene oxide solid polymer electrolyte to enhance the performance of lithium-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 1005-1014. doi: 10.11862/CJIC.20230444
11. [11]
  Qingyan JIANG , Yanyong SHA , Chen CHEN , Xiaojuan CHEN , Wenlong LIU , Hao HUANG , Hongjiang LIU , Qi LIU . Constructing a one-dimensional Cu-coordination polymer-based cathode material for Li-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 657-668. doi: 10.11862/CJIC.20240004
12. [12]
  Jiahong ZHENG , Jiajun SHEN , Xin BAI . Preparation and electrochemical properties of nickel foam loaded NiMoO₄/NiMoS₄ composites. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 581-590. doi: 10.11862/CJIC.20230253
13. [13]
  Zizhuo Liang , Fuming Du , Ning Zhao , Xiangxin Guo . Revealing the reason for the unsuccessful fabrication of Li3Zr2Si2PO12 by solid state reaction. Chinese Journal of Structural Chemistry, 2023, 42(11): 100108-100108. doi: 10.1016/j.cjsc.2023.100108
14. [14]
  Liang Ming , Dan Liu , Qiyue Luo , Chaochao Wei , Chen Liu , Ziling Jiang , Zhongkai Wu , Lin Li , Long Zhang , Shijie Cheng , Chuang Yu . Si-doped Li₆PS₅I with enhanced conductivity enables superior performance for all-solid-state lithium batteries. Chinese Chemical Letters, 2024, 35(10): 109387-. doi: 10.1016/j.cclet.2023.109387
15. [15]
  Peng XU , Shasha WANG , Nannan CHEN , Ao WANG , Dongmei YU . Preparation of three-layer magnetic composite Fe₃O₄@polyacrylic acid@ZiF-8 for efficient removal of malachite green in water. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 544-554. doi: 10.11862/CJIC.20230239
16. [16]
  Wendian XIE , Yuehua LONG , Jianyang XIE , Liqun XING , Shixiong SHE , Yan YANG , Zhihao HUANG . Preparation and ion separation performance of oligoether chains enriched covalent organic framework membrane. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1528-1536. doi: 10.11862/CJIC.20240050
17. [17]
  Zhuo WANG , Junshan ZHANG , Shaoyan YANG , Lingyan ZHOU , Yedi LI , Yuanpei LAN . Preparation and photocatalytic performance of CeO₂-reduced graphene oxide by thermal decomposition. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1708-1718. doi: 10.11862/CJIC.20240067
18. [18]
  Xiaoning TANG , Shu XIA , Jie LEI , Xingfu YANG , Qiuyang LUO , Junnan LIU , An XUE . Fluorine-doped MnO₂ with oxygen vacancy for stabilizing Zn-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1671-1678. doi: 10.11862/CJIC.20240149
19. [19]
  Zeyu XU , Anlei DANG , Bihua DENG , Xiaoxin ZUO , Yu LU , Ping YANG , Wenzhu YIN . Evaluation of the efficacy of graphene oxide quantum dots as an ovalbumin delivery platform and adjuvant for immune enhancement. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1065-1078. doi: 10.11862/CJIC.20240099
20. [20]
  Hao BAI , Weizhi JI , Jinyan CHEN , Hongji LI , Mingji LI . Preparation of Cu₂O/Cu-vertical graphene microelectrode and detection of uric acid/electroencephalogram. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1309-1319. doi: 10.11862/CJIC.20240001

Get Citation

PDF

XML

Metrics

PDF Downloads(19)
Abstract views(1507)
HTML views(326)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142