Citation: Li Wanfei, Ma Qian, Zheng Zhaozhao, Zhang Yuegang. Preparation of Three-dimensional Nitrogen-doped Carbon Nanoribbon and Application in Lithium/Sulfur Batteries[J]. Acta Chimica Sinica, ;2017, 75(2): 225-230. doi: 10.6023/A16080434 shu

Preparation of Three-dimensional Nitrogen-doped Carbon Nanoribbon and Application in Lithium/Sulfur Batteries

Li Wanfei ^a ,
Ma Qian ^a ,
Zheng Zhaozhao ^a ,
Zhang Yuegang ^a,b,*,,

a.
i-Lab, Suzhou Institute of Nano-Tech and Nano-bionics, Chinese Academy of Sciences, Suzhou, Jiangsu, 215123
b.
Department of Physics, Tsinghua University, Beijing, 100084

Corresponding author: Zhang Yuegang, ygzhang2012@sinano.ac.cn
Received Date: 25 August 2016
Revised Date: 5 December 2016

Fund Project: Project supported by the Natural Science Foundation of China 21433013, 51402345, 21403287Suzhou Science and Technology Development Program ZXG2013002, SYG201532

Figures(11)

Lithium/sulfur (Li-S) batteries have recently attracted intensive research interests due to their high theoretical specific energy of 2600 W·h·kg^-1. However, the poor electronic conductivity of sulfur and the high solubility of polysulfides in organic electrolytes lead to poor cycling stability and rate capability. Herein, we report a three-dimensional (3D) nanocomposite network made from nitrogen-doped carbon nanoribbon (NCNB) and nitrogen-doped graphene (NG), which has a high electronic conductivity and can serve as a conductive matrix and a sulfur immobilizer for the sulfur cathode. The NCNB is prepared by thermal nitridation of a unique 3D phenolic resin (PHF) isolated from the polycondensation reaction of 1,4-hydroquinone and formaldehyde. The N content of NCNB-NG can reach as high as 9.7 wt%. Although three types of N bonding geometries, including pyridinic N, pyrrolic N, and graphitic N, are identified in the NCNB-NG composites, we found the pyridinic N is dominant, which facilitates the trapping of intermediate lithium polysulfides. The sulfur was loaded on NCNB-NG by using a Na₂S₂O₃ solution as sulfur source. The scanning electron microscope (SEM) images show that almost no large S particle can be observed in the as-prepared S@NCNB-NG nanocomposites, suggesting a uniform coating of S on the NCNB-NG networks. The transmission electron microscopic (TEM) images and the elemental mapping by Energy-Dispersive X-ray (EDX) analysis also show that nano-sized S particles are uniformly distributed on the NCNB-NG matrix. The as-obtained S@NCNB-NG cathode can deliver a high specific capacity of 1338 mA·h·g^-1 at 0.05 C with about 80% S utilization. It also exhibits excellent rate capability and good cycle stability with a retained specific capacity of 556 mA·h·g^-1 after 300th cycles. These performances are much higher than the control samples using the S@NCNB and the S@PHF nanocomposites as cathodes. The improved performance can be attributed to the unique microstructure and the improved electronic conductivity of the NCNB-NG matrix.
- lithium/sulfur battery,
- carbon,
- N-doped,
- nanoribbon,
- three-dimensional
1. [1]
  Bruce, P. G.; Freunberger, S. A.; Hardwick, L. J.; Tarascon, J. M. Nat. Mater. 2012, 11, 172.
2. [2]
  Wang, D. W.; Zhou, G.; Li, F.; Wu, K. H.; Lu, G. Q.; Cheng, H. M.; Gentle, I. R. Phys. Chem. Chem. Phys. 2012, 14, 8703.
3. [3]
  Song, M.-K.; Cairns, E. J.; Zhang, Y. G. Nanoscale 2013, 5, 2186.
4. [4]
  Larcher, D.; Tarascon, J. M. Nat. Chem. 2015, 7, 19.
5. [5]
  Mikhaylik, Y. V.; Akridge, J. R. J. Electrochem. Soc. 2004, 151, A1969.
6. [6]
7. [7]
  Wild, M.; O'Neill, L.; Zhang, T.; Purkayastha, R.; Minton, G.; Marinescub, M.; Offer, G. J. Energy Environ. Sci. 2015, 8, 3477.
8. [8]
  Ji, X.; Lee, K. T.; Nazar, L. F. Nat. Mater. 2009, 8, 500.
9. [9]
  Liang, C.; Dudney, N. J.; Howe, J. Y. Chem. Mater. 2009, 21, 4724.
10. [10]
  Wang, H. L.; Yang, Y.; Liang, Y. Y.; Robinson, J. T.; Li, Y. G.; Jackson, A.; Cui, Y.; Dai, H. J. Nano Lett. 2011, 11, 2644.
11. [11]
  Cao, Y. L.; Li, X. L.; Aksay, I. A.; Lemmon, J.; Nie, Z. M.; Yang, Z. G.; Liu, J. Phys. Chem. Chem. Phys. 2011, 13, 7660.
12. [12]
  Guo, J. C.; Xu, Y. H.; Wang, C. S. Nano Lett. 2011, 11, 4288.
13. [13]
  Wei, S. C.; Zhang, H.; Huang, Y. Q.; Wang, W. K.; Xia, Y. Z.; Yu, Z. B. Energy Environ. Sci. 2011, 4, 736.
14. [14]
  He, G.; Ji, X.; Nazar, L. Energy Environ. Sci. 2011, 4, 2878.
15. [15]
  Song, M. K.; Zhang, Y. G.; Cairns, E. J. Nano Lett. 2013, 13, 5891.
16. [16]
  Qiu, Y. C.; Li, W. F.; Zhao, W.; Li, G. Z.; Hou, Y.; Liu, M. N.; Zhou, L. S.; Ye, F. M.; Li, H. F.; Wei, Z. H.; Yang, S. H.; Duan, W. H.; Ye, Y. F.; Guo, J. H.; Zhang, Y. G. Nano Lett. 2014, 14, 4821.
17. [17]
  Pope, M. A.; Aksay, I. A. Adv. Energy Mater. 2015, 5, 1500124.
18. [18]
  Suo, L. M.; Hu, Y. S.; Li, H.; Armand, M.; Chen, L. Q. Nat. Commun. 2013, 4, 1481.
19. [19]
20. [20]
  Zhang, S.; Ueno, K.; Dokko, K.; Watanabe, M. Adv. Energy Mater. 2015, 5, 1500117.
21. [21]
  Bauer, I.; Thieme, S.; Brückner, J.; Althues, H.; Kaskel, S. J. Power Sources 2014, 251, 417.
22. [22]
  Chung, S. H.; Manthiram, A. Adv. Mater. 2014, 26, 1360.
23. [23]
  Huang, J. Q.; Zhang, Q.; Peng, H. J.; Liu, X. Y.; Qian, W. Z.; Wei, F. Energy Environ. Sci. 2014, 7, 347.
24. [24]
  Zhang, Z. Y.; Lai, Y. Q.; Zhang, Z. A.; Zhang, K.; Li, J. Electrochim. Acta 2014, 129, 55.
25. [25]
  Chung, S. H.; Manthiram, A. J. Phys. Chem. Lett. 2014, 5, 1978.
26. [26]
  Huang, J. Q.; Zhang, Q.; Wei, F. Energy Storage Mater. 2015, 1, 127.
27. [27]
  Huang, J. Q.; Zhuang, T. Z.; Zhang, Q.; Peng, H. J.; Chen, C. M.; Wei, F. ACS Nano 2015, 9, 3002.
28. [28]
  Zhang, Y.; Gu, H.; Iijima, S. Appl. Phys. Lett. 1998, 73, 3827.
29. [29]
  Zhang, Y.; Iijima, S. Appl. Phys. Lett. 1999, 75, 3087.
30. [30]
  Scott, C. D.; Arepalli, S.; Nikolaev, P.; Smalley, R. E. Appl. Phys. A-Mater. Sci. & Proc. 2001, 72, 573.
31. [31]
  Zhu, H. W.; Li, X. S.; Jiang, B.; Xu, C. L.; Zhu, Y. F.; Wu, D. H. Chem. Phys. Lett. 2002, 366, 664.
32. [32]
  Lange, H.; Sioda, M.; Huczko, A.; Zhu, Y. Q.; Kroto, H. W.; Walton, D. R. M. Carbon 2003, 41,1617.
33. [33]
  Guo, J.; Wang, X.; Yao, Y.; Yang, X.; Liu, X.; Xu, B. Mater. Chem. Phys. 2007, 105, 175.
34. [34]
  Dong, X. C.; Li, B.; Wei, A.; Cao, X. H.; Chan-Park, M. B.; Zhang, H.; Li, L. J.; Huang, W.; Chen, P. Carbon 2011, 49, 2944.
35. [35]
  Choi, H.; Kim, H.; Hwang, S.; Kang, M.; Jung, D. W.; Jeon, M. Scripta Mater. 2011, 64, 601.
36. [36]
  Poh, H. L.; Sanek, F.; Ambrosi, A.; Zhao, G.; Sofer, Z.; Pumera, M. Nanoscale 2012, 4, 3515.
37. [37]
  Chen, J.; Yao, B. W.; Li, C.; Shi, G. Q. Carbon 2013, 64, 225.
38. [38]
  Liu, N.; Lu, Z. D.; Zhao, J.; McDowell, M. T.; Lee, H. W.; Zhao, W. T.; Cui, Y. Nat. Nanotech. 2014, 9, 187.
39. [39]
  Yang, C.; Yin, Y.; Ye, H.; Jiang, K.; Zhang, J.; Guo, Y. ACS Appl. Mater. Interfaces 2014, 6, 8789.
40. [40]
  Qiu, Y.; Zhang, X.; Yang, S. H. Phys. Chem. Chem. Phys. 2011, 13, 12554.
41. [41]
  Li, X.; Wang, H.; Robinson, J. T.; Sanchez, H.; Diankov, G.; Dai, H. J. J. Am. Chem. Soc. 2009, 131, 15939.
42. [42]
  Huang, J. Q.; Liu, X. F.; Zhang, Q.; Chen, C. M.; Zhao, M. Q.; Zhang, S. M.; Zhu, W. C.; Qian, W. Z.; Wei, F. Nano Energy 2013, 2, 314.
43. [43]
  Li, Z.; Jiang, Y.; Yuan, L. X.; Yi, Z. Q.; Wu, C.; Liu, Y.; Strasser, P.; Huang, Y. H. ACS Nano 2014, 8, 9295.
44. [44]
  Li, H. F.; Yang, X. W.; Wang, X. M.; Liu, M. N.; Ye, F. M.; Wang, J.; Qiu, Y. C.; Li, W. F.; Zhang, Y. G. Nano Energy 2015, 12, 468.
45. [45]
  Ji, X.; Nazar, L. F. J. Mater. Chem. 2010, 20, 9821.
46. [46]
  Liu, M. N.; Ye, F. M.; Li, W. F.; Li, H. F.; Zhang, Y. G. Nano Res. 2016, 9, 94.
47. [47]
  Xu, Y. X.; Bai, H.; Lu, G. W.; Li, C.; Shi, G. Q. J. Am. Chem. Soc. 2008, 130, 5856.
48. [48]
  Dai, K.; Lu, L. H.; Liu, Q.; Zhu, G. P.; Wei, X. Q.; Bai, J.; Xuan, L. L.; Wang, H. Dalton Trans. 2014, 43, 6295.
49. [49]
  Weng, W.; Pol, V. G.; Amine, K. Adv. Mater. 2013, 25, 1608.
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