Citation: Wang Dehong, Zhang Long, Luo Sanzhong. Photo-induced Catalytic Asymmetric Free Radical Reactions[J]. Acta Chimica Sinica, ;2017, 75(1): 22-33. doi: 10.6023/A16080418 shu

Photo-induced Catalytic Asymmetric Free Radical Reactions

Wang Dehong ^a,b ,
Zhang Long ^a,b ,
Luo Sanzhong ^a,b,*,,

a.
Key Laboratory of Molecular Recognition and Functions, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190
b.
University of Chinese Academy of Sciences, Beijing 100049

Corresponding author: Luo Sanzhong, luosz@iccas.ac.cn
Received Date: 16 August 2016

Fund Project: the National Natural Science Foundation of China 21390400the National Natural Science Foundation of China 21572232

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Enantioselective control of free radical reactions has eluded organic chemists for decades. Echoed with the renaissance of photo-induced processes, or so called photocatalysis or photoredox catalysis in organic synthesis, photo-induced organic radical chemistry has regained its prominence in developing catalytic asymmetric radical reaction. The generally mild conditions inherited with photochemistry, particularly visible light photo-processes, have allowed for controllable generation of free radicals as well as the subsequent bond formations. The past five years have witnessed dramatic advances in exploring photo-induced catalytic asymmetric free radical reactions, and enormous potentials along this line are envisaged. This perspective gives a brief summary on the important advances in this field. Accordingly, the major advances are classified based on different radical species including α-amino/oxyl radicals, radicals generated from enones and its analogues, benzyl radicals, α-carbonyl radicals, polyhalogenated alkyl radicals and nitrogen radicals. Brief discussion of mechanism is presented whenever relevant.
- photoredox catalysis,
- free radical reaction,
- asymmetric catalysis,
- synergistic catalysis
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