Citation: Pei Pengkun, Zhang Fan, Yi Hong, Lei Aiwen. Visible Light Promoted Benzylic C_sp3-H Bond Activation and Functionalization[J]. Acta Chimica Sinica, ;2017, 75(1): 15-21. doi: 10.6023/A16080417 shu

Visible Light Promoted Benzylic C_sp3-H Bond Activation and Functionalization

College of Chemistry and Molecular Sciences, Wuhan University, Wuhan 430072

Corresponding author: Lei Aiwen, aiwenlei@whu.edu.cn
Received Date: 16 August 2016

Fund Project: the National Natural Science Foundation of China 21390400the Program for Changjiang Scholars and Innovative Research Team in University IRT1030the 973 Program 2012CB725302the National Natural Science Foundation of China 21520102003the Program of Introducing Talents of Discipline to Universities of China 111 Programthe Research Fund for the Doctoral Program of Higher Education of China 20120141130002the Ministry of Science and Technology of China 2012YQ120060the National Natural Science Foundation of China 21302148the National Natural Science Foundation of China 21272180

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In recent years, visible-light-promoted photoredox catalytic activation of organic molecules has been flourishing vigorously. This kind of methodology usually takes advantage of transition-metal complexes and organic dyes as photosensitizers, which can directly react with organic substrates through a single-electron-transfer (SET) progress under visible light irradiation. It's operable to construct C-X (X=C, N, O …) bond via the radical or radical ion generated during the SET process. On the basis of different key intermediates, this highlight gives a brief summary on the recent development of visible light promoted benzylic C_sp3-H activation and functionalization.
- visible light photoredox,
- C_sp3-H bond activation,
- toluene derivatives,
- green chemistry
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Visible Light Promoted Benzylic Csp3-H Bond Activation and Functionalization

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通讯作者: 陈斌, bchen63@163.com

Visible Light Promoted Benzylic C_sp3-H Bond Activation and Functionalization