Citation: Gao Yuxi, Hu Jun, Ju Yong. Supramolecular Self-Assembly Based on Natural Small Molecules[J]. Acta Chimica Sinica, ;2016, 74(4): 312-329. doi: 10.6023/A16010016 shu

Supramolecular Self-Assembly Based on Natural Small Molecules

Gao Yuxi ^a ,
Hu Jun ^b ,
Ju Yong ^a,,

a.
a Key Laboratory of Bioorganic Phosphorus Chemistry & Chemical Biology, Ministry of Education, Department of Chemistry, Tsinghua University, Beijing 100084;
b.
b State Key Lab of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022

Corresponding author: Ju Yong,
Received Date: 8 January 2016

Fund Project: 项目受国家自然科学基金(No. 21472108) (No. 21472108)国家重大科学研究计划(973计划, No. 2012CB821600) (973计划, No. 2012CB821600)

Natural products have been widely used in the construction of supramolecular self-assemblies due to not only their abundant resources, unique chiral structures, and multiple reaction sites, but also the good biocompatibility and the controllable degradability. Through the simple chemical modification natural products-based functional molecules would self-assemble into various supramolecular assemblies primarily promoted by non-covalent interactions, such as hydrogen bonding, π-π stacking, van der Waals forces, electrostatic interactions, and charge-transfer interactions. During the assembly process, their unique molecular chirality would be transferred and magnified into supramolecular assemblies, thus providing a facile method to fabricate helical ribbons, nanotubes, and other chiral nanostructures. Furthermore, their good biocompatibility and biological activity endow the assemblies with the ability to be widely applied in tissue engineering, drug delivery, cell imaging, and so on. In this review, recent developments of supramolecular self-assemblies based on amino acids, sugars, nucleosides, steroids, triterpenoids and other natural products were summarized.
- natural small molecules,
- supramolecular self-assembly,
- non-covalent interactions,
- chirality,
- biological activity
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沈阳化工大学材料科学与工程学院沈阳 110142