Advanced Search

Citation: Wang Yujue, Hu Min, Wang Yu, Qin Yanhong, Chen Hongyang, Zeng Limin, Lei Jianrong, Huang Xiaofeng, He Lingyan, Zhang Ruiqin, Wu Zhijun. Characterization and Influence Factors of PM2.5 Emitted from Crop Straw Burning[J]. Acta Chimica Sinica, ;2016, 74(4): 356-362. doi: 10.6023/A16010008 shu

Characterization and Influence Factors of PM2.5 Emitted from Crop Straw Burning

  • a.

    a State Key Joint Laboratory of Environmental Simulation and Pollution Control, College of Environmental Sciences and Engineering, Peking University, Beijing 100871;

  • b.

    b Key Laboratory for Urban Habitat Environmental Science and Technology, School of Environment and Energy, Peking University Shenzhen Graduate School, Shenzhen 518055;

  • c.

    c Department of Chemistry, Zhengzhou University, Zhengzhou 450001

  • Corresponding author: Hu Min, 
  • Received Date: 5 January 2016

    Fund Project: 项目受环保部公益性行业科研专项(No. 201409010) (No. 201409010)国家自然科学基金重大项目(Nos. 91544214, 21190052) (Nos. 91544214, 21190052)中国科学院战略性先导科技专项(No. XDB05010500)资助. (No. XDB05010500)

  • Large quantities of particulate pollutants are emitted into the atmosphere during biomass burning processes. In China, large amounts of agricultural residues are burned in the field during harvest seasons, which influence regional air quality and human health. Corn and wheat are two major crops grown in China, whose burning was simulated in this study. The controlled laboratory simulation of straw burning was performed in the Laboratory of Biomass Burning Simulation at Peking University Shenzhen Graduate School. The burning simulation system was improved and verified. Straw burning aerosols (PM2.5) samples were collected and measured by gravimetric method. Organic carbon (OC) and elemental carbon (EC) were measured by thermal/optical method. Water-soluble inorganic ions and organic matter were measured by ion chromatography. Emission level, characterization and influence factors of crop straw burning aerosols are discussed. PM2.5 emission factors of corn and wheat straw burning are 1082.8 and 835.7~897.3 mg/kg, respectively. Organic matter (OM), which is calculated by multiplying organic carbon (OC) by 1.3, is the major component of PM2.5, accounting for 42%~66% of the total mass. Nearly half (37%~50%) of OM are water soluble. Cl- and K+are two major components among water-soluble inorganic ions, accounting for 4%~15% and 2%~14% of total particle mass, respectively. The K+/EC ratio is 0.5~3.8. The proportions of these species in PM2.5 are comparable to previous studies. Straw moisture content and burning temperature influence the emission level and characterization of straw burning aerosols. Emission factors of PM2.5 and OC increase with the increase of straw moisture content because of incomplete burning. With higher moisture content, more thermal energy is used for the evaporation of water, lowering the burning temperature. Then less proportion of K+and Cl- are released from biomass into the smoke. Therefore, their contributions to the particle mass decrease with the increase of straw moisture content. The emissions of PM2.5 and OC/EC by crop straw burning in the field are estimated based on the emission factors obtained in this study. Corn and wheat burning in the field yield 92.7 Gg PM2.5 and 47.5 Gg OC every year in China, accounting for important fractions among the total mass.
  • 加载中
    1. [1]

      [1] Simoneit, B. R. T. Appl. Geochem. 2002, 17, 129.

    2. [2]

      [2] Anderson, B. E.; Grant, W. B.; Gregory, G. L.; Browell, E. V.; Collins, J. E.; Sachse, G. W.; Bagwell, D. R.; Hudgins, C. H.; Blake, D. R.; Blake, N. J. J. Geophys. Res. 1996, 101, 24117.

    3. [3]

      [3] Cheng, Y.; Engling, G.; He, K. B.; Duan, F. K.; Ma, Y. L.; Du, Z. Y.; Liu, J. M.; Zheng, M.; Weber, R. J. Atmos. Chem. Phys. 2013, 13, 7765.

    4. [4]

      [4] Khan, A. A.; de Jong, W.; Jansens, P. J.; Spliethoff, H. Fuel Process. Technol. 2009, 90, 21.

    5. [5]

      [5] Radzi bin Abas, M.; Oros, D. R.; Simoneit, B. R. Chemosphere 2004, 55, 1089.

    6. [6]

      [6] Andreae, M. O.; Merlet, P. Global Biogeochem. Cycles 2001, 15, 955.

    7. [7]

      [7] Iinuma, Y.; Brüggemann, E.; Gnauk, T.; Müller, K.; Andreae, M. O.; Helas, G.; Parmar, R.; Herrmann, H. J. Geophys. Res. 2007, 112.

    8. [8]

      [8] Streets, D. G.; Yarber, K. F.; Woo, J. H.; Carmichael, G. R. Global Biogeochem. Cycles 2003, 17, 1099.

    9. [9]

      [9] Cao, G. L.; Zhang, X. Y.; Zheng, F. C. Atmos. Environ. 2006, 40, 6516.

    10. [10]

      [10] Yan, X. Y.; Ohara, T.; Akimoto, H. Atmos. Environ. 2006, 40, 5262.

    11. [11]

      [11] Li, X.; Wang, S.; Duan, L.; Hao, J.; Li, C.; Chen, Y.; Yang, L. Environ. Sci. Technol. 2007, 41, 6052.

    12. [12]

      [12] Hays, M. D.; Fine, P. M.; Geron, C. D.; Kleeman, M. J.; Gullett, B. K. Atmos. Environ. 2005, 39, 6747.

    13. [13]

      [13] Turn, S. Q.; Jenkins, B. M.; Chow, J. C.; Pritchett, L. C.; Campbell, D.; Cahill, T.; Whalen, S. A. J. Geophys. Res.-Atmos. 1997, 102, 3683.

    14. [14]

      [14] Li, J. F.; Song, Y.; Mao, Y.; Mao, Z. C.; Wu, Y. S.; Li, M. M.; Huang, X.; He, Q. C.; Hu, M. Atmos. Environ. 2014, 92, 442.

    15. [15]

      [15] Sanchis, E.; Ferrer, M.; Calvet, S.; Coscollà, C.; Yusà, V.; Cambra-López, M. Atmos. Environ. 2014, 98, 25.

    16. [16]

      [16] Shen, G.; Xue, M.; Wei, S.; Chen, Y.; Wang, B.; Wang, R.; Shen, H.; Li, W.; Zhang, Y.; Huang, Y.; Chen, H.; Wei, W.; Zhao, Q.; Li, B.; Wu, H.; Tao, S. J. Environ. Sci. 2013, 25, 511.

    17. [17]

      [17] Lu, H.; Zhu, L.; Zhu, N. Atmos. Environ. 2009, 43, 978.

    18. [18]

      [18] Ortiz de Zárate, I.; Ezcurra, A.; Lacaux, J. P.; Van Dinh, P. Atmos. Environ. 2000, 34, 3183.

    19. [19]

      [19] Nguyen, B. C.; Putaud, J. P.; Mihalopoulos, N.; Bonsang, B.; Doan, C. Environ. Monit. Assess. 1994, 31, 131.

    20. [20]

      [20] Levin, E. J. T.; McMeeking, G. R.; Carrico, C. M.; Mack, L. E.; Kreidenweis, S. M.; Wold, C. E.; Moosmüller, H.; Arnott, W. P.; Hao, W. M.; Collett, J. L.; Malm, W. C. J. Geophys. Res. 2010, 115.

    21. [21]

      [21] Dhammapala, R.; Claiborn, C.; Corkill, J.; Gullett, B. Atmos. Environ. 2006, 40, 1007.

    22. [22]

      [22] Guo, S.; Hu, M.; Guo, Q.; Shang, D. Acta Chim. Sinica 2014, 72, 658. (郭松, 胡敏, 郭庆丰, 尚冬杰, 化学学报, 2014, 72, 658.)

    23. [23]

      [23] Bae, M.-S.; Park, S.-S. Asian J. Atmos. Environ. 2013, 7, 95.

    24. [24]

      [24] Chen, L. W. A.; Verburg, P.; Shackelford, A.; Zhu, D.; Susfalk, R.; Chow, J. C.; Watson, J. G. Atmos. Chem. Phys. 2010, 10, 6617.

    25. [25]

      [25] Bjorkman, E.; Stromberg, B. Energy Fuels 1997, 11, 1026.

    26. [26]

      [26] Jensen, P. A.; Frandsen, F. J.; Dam-Johansen, K.; Sander, B. Energy Fuels 2000, 14, 1280.

    27. [27]

      [27] Knudsen, J. N.; Jensen, P. A.; Dam-Johansen, K. Energy Fuels 2004, 18, 1385.

    28. [28]

      [28] He, L. Y.; Lin, Y.; Huang, X. F.; Guo, S.; Xue, L.; Su, Q.; Hu, M.; Luan, S. J.; Zhang, Y. H. Atmos. Chem. Phys. 2010, 10, 11535.

    29. [29]

      [29] Guo, S.; Hu, M.; Wang, Z. B.; Slanina, J.; Zhao, Y. L. Atmos. Chem. Phys. 2010, 10, 947.

    30. [30]

      [30] Huan, N.; Zeng, L. M.; Shao, M.; Cui, L.; Mao, J. T.; Zhou, N.; Dong, H. B.; Yu, Z. Y.; Luo, Z. M. Acta Sci. Nat. Univ. Pekinensis 2006, 42, 265 (in Chinese). (郇宁, 曾立民, 邵敏, 崔良, 毛节泰, 周楠, 董华斌, 俞仲英, 罗志明, 北京大学学报(自然科学版), 2006, 42, 265.)

    31. [31]

      [31] Koopmans, A.; Koppejan, J. Regional Consultation on Modern Applications of Biomass Energy 1997, 6.

    32. [32]

      [32] Hao, W. M.; Liu, M. H. Global Biogeochem. Cycles 1994, 8, 495.

  • 加载中
    1. [1]

      Donghui PAN , Yuping XU , Xinyu WANG , Lizhen WANG , Junjie YAN , Dongjian SHI , Min YANG , Mingqing CHEN . Preparation and in vivo tracing of 68Ga-labeled PM2.5 mimetic particles for positron emission tomography imaging. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 669-676. doi: 10.11862/CJIC.20230468

    2. [2]

      Yajun Hou , Chuanzheng Zhu , Qiang Wang , Xiaomeng Zhao , Kun Luo , Zongshuai Gong , Zhihao Yuan . ~2.5 nm pores in carbon-based cathode promise better zinc-iodine batteries. Chinese Chemical Letters, 2024, 35(5): 108697-. doi: 10.1016/j.cclet.2023.108697

    3. [3]

      Zhihuan XU , Qing KANG , Yuzhen LONG , Qian YUAN , Cidong LIU , Xin LI , Genghuai TANG , Yuqing LIAO . Effect of graphene oxide concentration on the electrochemical properties of reduced graphene oxide/ZnS. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1329-1336. doi: 10.11862/CJIC.20230447

    4. [4]

      Peng ZHOU , Xiao CAI , Qingxiang MA , Xu LIU . Effects of Cu doping on the structure and optical properties of Au11(dppf)4Cl2 nanocluster. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1254-1260. doi: 10.11862/CJIC.20240047

    5. [5]

      Xiaoning TANG , Junnan LIU , Xingfu YANG , Jie LEI , Qiuyang LUO , Shu XIA , An XUE . Effect of sodium alginate-sodium carboxymethylcellulose gel layer on the stability of Zn anodes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1452-1460. doi: 10.11862/CJIC.20240191

    6. [6]

      Yuanchao LI , Weifeng HUANG , Pengchao LIANG , Zifang ZHAO , Baoyan XING , Dongliang YAN , Li YANG , Songlin WANG . Effect of heterogeneous dual carbon sources on electrochemical properties of LiMn0.8Fe0.2PO4/C composites. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 751-760. doi: 10.11862/CJIC.20230252

    7. [7]

      Zeyuan WANG , Songzhi ZHENG , Hao LI , Jingbo WENG , Wei WANG , Yang WANG , Weihai SUN . Effect of I2 interface modification engineering on the performance of all-inorganic CsPbBr3 perovskite solar cells. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1290-1300. doi: 10.11862/CJIC.20240021

    8. [8]

      Haitang WANG , Yanni LING , Xiaqing MA , Yuxin CHEN , Rui ZHANG , Keyi WANG , Ying ZHANG , Wenmin WANG . Construction, crystal structures, and biological activities of two LnⅢ3 complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1474-1482. doi: 10.11862/CJIC.20240188

    9. [9]

      Hongyi LI , Aimin WU , Liuyang ZHAO , Xinpeng LIU , Fengqin CHEN , Aikui LI , Hao HUANG . Effect of Y(PO3)3 double-coating modification on the electrochemical properties of Li[Ni0.8Co0.15Al0.05]O2. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1320-1328. doi: 10.11862/CJIC.20230480

    10. [10]

      Xin MA , Ya SUN , Na SUN , Qian KANG , Jiajia ZHANG , Ruitao ZHU , Xiaoli GAO . A Tb2 complex based on polydentate Schiff base: Crystal structure, fluorescence properties, and biological activity. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1347-1356. doi: 10.11862/CJIC.20230357

    11. [11]

      Jinlong YAN , Weina WU , Yuan WANG . A simple Schiff base probe for the fluorescent turn-on detection of hypochlorite and its biological imaging application. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1653-1660. doi: 10.11862/CJIC.20240154

    12. [12]

      Yonghui ZHOU , Rujun HUANG , Dongchao YAO , Aiwei ZHANG , Yuhang SUN , Zhujun CHEN , Baisong ZHU , Youxuan ZHENG . Synthesis and photoelectric properties of fluorescence materials with electron donor-acceptor structures based on quinoxaline and pyridinopyrazine, carbazole, and diphenylamine derivatives. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 701-712. doi: 10.11862/CJIC.20230373

Get Citation
PDF
XML
Metrics
  • PDF Downloads(0)
  • Abstract views(696)
  • HTML views(100)

通讯作者: 陈斌, bchen63@163.com
  • 1. 

    沈阳化工大学材料科学与工程学院 沈阳 110142

  1. 本站搜索
  2. 百度学术搜索
  3. 万方数据库搜索
  4. CNKI搜索
Address：Zhongguancun North First Street 2,100190 Beijing, PR China Tel: +86-010-82449177-888
Powered By info@rhhz.net

/

DownLoad:  Full-Size Img  PowerPoint
Return