Advanced Search

Citation: Zhu Haoyun, Huang Wei, Huang Yuli, Wang Weizhi. Field Effect Transistors Characteristics Based on Blends of Si Nanowires and Poly(3-dodecylthiophene)[J]. Acta Chimica Sinica, ;2016, 74(5): 429-434. doi: 10.6023/A15120789 shu

Field Effect Transistors Characteristics Based on Blends of Si Nanowires and Poly(3-dodecylthiophene)

  • 1.

    State Key Laboratory of Molecular Engineering of Polymers, Department of Macromolecular Science, Collaborative Innovation Center of Polymers and Polymer Composite Materials, Department of Macromolecular Science, Fudan University, Shanghai 200433

  • Corresponding author: Wang Weizhi, weizhiwang@fudan.edu.cn
  • Received Date: 21 December 2015

    Fund Project: the Innovation Program of Shanghai Municipal Education Commission 15ZZ002the National Natural Science Foundation of China 21274027the National Natural Science Foundation of China 20974022

Figures(5)

  • In order to enhance the field effect mobility of poly(3-dodecylthiophene), Si nanowires were added to the poly(3-dodecylthiophene) solution prior to film formation. The Si nanowires were produced by the electroless metal deposition method which involved the etching of silicon wafers in aqueous hydrofluoric acid and silver nitrate solution. The observation of scanning electron microscopy proved the uniform Si nanowires were obtained. The blend film was treated with thermal annealing to form ordered microcrystalline structure by self-organization. The annealing effect was measured by X-ray diffraction and atomic force microscopy which showed the enhancing diffraction peak and ordered atomic force microscopy images after annealing films. In the bottom gated field effect transistors, the blend film of Si nanowires and poly(3-dodecylthiophene) were formed on the SiO2/Si substrate by spin coating. The surface of the SiO2/Si substrate was coated with hexamethyldisilazane to produce a hydrophobic surface. The thickness of the Au source/drain electrodes was 100 nm. The annealing blend films worked as the semiconducting layer, 300 nm SiO2 worked as the gate dielectric and Si worked as the gate electrode. The charge carrier mobility of poly(3-dodecylthiophene) thin films was 0.015 cm2·V-1·s-1 and the charge carrier mobility of blend films was up to 0.68 cm2·V-1·s-1. The remarkable increase in the field effect mobility over that of pristine poly(3-dodecylthiophene) film is due to the high conductivity of Si nanowires which act as fast conducting channel between the crystalline regions of the poly(3-dodecylthiophene) film. To confirm and enhance the field effect transistors properties, we used the electric-double-layer transistor based on the blend films in which ion gel worked as the gate dielectric instead of SiO2. Here, Au foil worked as the gate electrode to form a top-gated field effect transistors. The charge carrier mobility of blend films was found to be relatively higher (6.2 cm2·V-1·s-1) when using ion gel as the dielectric layer.
  • 加载中
    1. [1]

      Padinger, F.; Rittberger, R. S.; Sariciftci, N. S. Adv. Funct. Mater. 2003, 13, 85.  doi: 10.1002/adfm.200390011

    2. [2]

      Li, G.; Shrotriya, V.; Huang, J.; Yao, Y.; Moriarty, T.; Emery, K.; Yang, Y. Nat. Mater. 2005, 4, 864.  doi: 10.1038/nmat1500

    3. [3]

      Jin, K. Y.; Lee, K.; Coates, N. E.; Daniel, M.; Nguyen, T.; Mark, D.; Heeger, A. J. Science 2007, 317, 222.  doi: 10.1126/science.1141711

    4. [4]

      He, M.; Han, W.; Ge, J.; Yu, W.; Yang, Y.; Qiu, F.; Lin, Z. Nanoscale 2011, 3, 3159.  doi: 10.1039/c1nr10293a

    5. [5]

      Pei, J.; Hao, Y.; Lü, H.; Sun, B.; Li, Y.; Wang, S. Acta Chim. Sinica 2014, 72(12), 1245.  doi: 10.6023/A14110783
       

    6. [6]

      Hao, Y.; Ma, J.; Sun, B.; Li, Y.; Ren, J. Acta Chim. Sinica 2010, 68(1), 33.
       

    7. [7]

      Ohmori, Y.; Uchida, M.; Muro, K.; Yoshino, K. Jpn. Appl. Phys. 1991, 30, L1938.  doi: 10.1143/JJAP.30.L1938

    8. [8]

      Ohmori, Y.; Uchida, M.; Muro, K.; Yoshino, K. Solid State Commun. 1991, 80, 605.  doi: 10.1016/0038-1098(91)90161-N

    9. [9]

      Mcquade, D. T.; Pullen, A. E.; Swager, T. M. Chem. Rev. 2000, 100, 2537.  doi: 10.1021/cr9801014

    10. [10]

      Facchetti, A. Chem. Mater. 2011, 23, 733.  doi: 10.1021/cm102419z

    11. [11]

      Wang, C.; Dong, H.; Hu, W.; Liu, Y.; Zhu, D. Chem. Rev. 2012, 112, 2208.  doi: 10.1021/cr100380z

    12. [12]

      Zhao, G. J.; He, Y. J.; Peng, B. Chin. J. Chem. 2012, 30, 19.  doi: 10.1002/cjoc.201100145

    13. [13]

      Scheinert, S.; Paasch, G.; Schrödner, M.; Roth, H. K.; Sensfuß, S.; Doll, T. J. Appl. Phys. 2002, 92, 330.  doi: 10.1063/1.1486253

    14. [14]

      Payerne, R.; Brun, M.; Rannou, P.; Baptist, R.; Grévin, B. Synth. Met. 2004, 146, 311.  doi: 10.1016/j.synthmet.2004.08.026

    15. [15]

      Tanaka, S.; Grévin, B.; Rannou, P.; Suzuki, H.; Mashiko, S. Thin Solid Films 2006, 499, 168.  doi: 10.1016/j.tsf.2005.07.250

    16. [16]

      Sauvé, G.; Javier, A. E.; Zhang, R.; Liu, J.; Sydlik, S. A.; Kowalewski, T.; McCullough, R. D. J. Mater. Chem. 2010, 20, 3195.  doi: 10.1039/c000172d

    17. [17]

      Babel, A.; Jenekhe, S. A. Synth. Met. 2005, 148, 169.  doi: 10.1016/j.synthmet.2004.09.033

    18. [18]

      Wang, G.; Swensen, J.; Moses, D.; Heeger, A. J. J. Appl. Phys. 2003, 93, 6137.  doi: 10.1063/1.1568526

    19. [19]

      Nagamatsu, S.; Takashima, W.; Kaneto, K.; Yoshida, Y.; Tanigaki, N.; Yase, K. Appl. Phys. Lett. 2004, 84, 4608.  doi: 10.1063/1.1751222

    20. [20]

      Yu, H. Z.; Peng, J. B. Acta Phys.-Chim. Sin. 2008, 24, 905.

    21. [21]

      Motaung, D. E.; Malgas, G. F.; Nkosi, S. S.; Mhlongo, G. H.; Mwakikunga, B. W.; Malwela, T.; Arendse, C. J.; Muller, T. F. G.; Cummings, F. R. J. Mater. Sci. 2013, 48, 1763.  doi: 10.1007/s10853-012-6937-6

    22. [22]

      Lu, G.; Tang, H.; Qu, Y.; Li, L.; Yang, X. Macromolecules 2007, 40, 6579.  doi: 10.1021/ma071135t

    23. [23]

      Babel, A.; Jenekhe, S. A. J. Phys. Chem. B 2003, 107, 1749.

    24. [24]

      Zen, A.; Saphiannikova, M.; Neher, D.; Asawapirom, U.; Scherf, U. Chem. Mater. 2005, 17, 781.  doi: 10.1021/cm040183e

    25. [25]

      Jiu, T.; Reiss, P.; Guillerez, S.; Bettignies, R. D.; Bailly, S.; Chandezon, F. IEEE J. Sel. Top. Quant. 2010, 16, 1619.  doi: 10.1109/JSTQE.2010.2044557

    26. [26]

      Kergoat, L.; Battaglini, N.; Miozzo, L.; Piro, B.; Pham, M. C.; Yassar, A.; Horowitz, G. Org. Electron. 2011, 12, 1253.  doi: 10.1016/j.orgel.2011.04.006

    27. [27]

      Park, Y. D.; Lim, J. A.; Jang, Y.; Hwang, M.; Lee, H. S.; Lee, D. H.; Lee, H.; Baek, J.; Cho, K. Org. Electron. 2008, 9, 317.  doi: 10.1016/j.orgel.2007.11.007

    28. [28]

      Tomioka, K.; Tanaka, T.; Hara, S.; Hiruma, K.; Fukui, T. IEEE J. Sel. Top. Quant. 2011, 17, 1112.  doi: 10.1109/JSTQE.2010.2068280

    29. [29]

      Duan, X.; Niu, C.; Sahi, V.; Chen, J.; Parce, J. W.; Empedocles, S.; Goldman, J. L. Nature 2003, 425, 274.  doi: 10.1038/nature01996

    30. [30]

      Chang, S.; Chuang, V. P.; Boles, S. T.; Ross, C. A.; Thompson, C. V. Adv. Funct. Mater. 2009, 19, 2495.  doi: 10.1002/adfm.v19:15

    31. [31]

      Chen, Y. W.; Jiang, S. H.; Shao, B. X.; Wang, R. C. Chin. J. Inorg. Chem. 2007, 23, 915.

    32. [32]

      Yang, J. Y.; Lu, S. G.; Ding, H. Y.; Zhang, X. Y.; Kan, S. R. Chinese J. Inorg. Chem. 2010, 26, 1837.

    33. [33]

      Srivastava, S. K.; Kumar, D.; Schmitt, S. W.; Sood, K. N.; Christiansen, S. H.; Singh, P. K. Nanotechnology 2014, 25, 175601.  doi: 10.1088/0957-4484/25/17/175601

    34. [34]

      Peng, K.; Fang, H.; Hu, J.; Wu, Y.; Zhu, J.; Yan, Y.; Lee, S. Chem. Eur. J. 2006, 12, 7942.  doi: 10.1002/(ISSN)1521-3765

    35. [35]

      Liao, L.; Bai, J.; Lin, Y. C.; Qu, Y.; Huang, Y.; Duan, X. Adv. Mater. 2010, 22, 1941.  doi: 10.1002/adma.200904415

    36. [36]

      Lei, T.; Dou, J.; Cao, X.; Wang, J.; Pei, J. Adv. Mater. 2013, 25, 6589.  doi: 10.1002/adma.201302278

    37. [37]

      Fu, X. L.; Wang, C. L.; Li, R. J.; Dong, H. L.; Hu, W. P. Sci. China Chem. 2010, 6, 1225.

    38. [38]

      Lin, J.; Zhong, J.; Zhong, S.; Li, H.; Zhang, H.; Chen, W. Appl. Phys. Lett. 2013, 103, 63109.  doi: 10.1063/1.4818463

    39. [39]

      Tarabella, G.; Mahvash Mohammadi, F.; Coppedè, N.; Barbero, F.; Iannotta, S.; Santato, C.; Cicoira, F. Chem. Sci. 2013, 4, 1395.  doi: 10.1039/c2sc21740f

    40. [40]

      Huang, J. K.; Jiang, P.; Hsu, C. L.; Chiu, M. H.; Juang, Z. Y.; Chang, Y. H.; Chang, W. H.; Iwasa, Y.; Takenobu, T.; Li, L. J. ACS Nano 2014, 8, 923.  doi: 10.1021/nn405719x

    41. [41]

      Yuan, H.; Shimotani, H.; Ye, J.; Yoon, S.; Aliah, H.; Tsukazaki, A.; Kawasaki, M.; Iwasa, Y. J. Am. Chem. Soc. 2010, 132, 18402.  doi: 10.1021/ja108912x

    42. [42]

      Zhang, J.; Han, Z.; Chen, M.; Yang, X.; Cao, W. J. Phys. Chem. Solids 2010, 71, 1316.  doi: 10.1016/j.jpcs.2010.05.014

    43. [43]

      Srivastava, S. K.; Kumar, D.; Schmitt, S. W.; Sood, K. N.; Christiansen, S. H.; Singh, P. K. Nanotechnology 2014, 25, 175601.  doi: 10.1088/0957-4484/25/17/175601

    44. [44]

      Huang, J.; Pu, J.; Hsu, C.; Chiu, M.; Juang, Z.; Chang, Y.; Chang, W.; Iwasa, Y.; Takenobu, T.; Li, L. ACS Nano 2014, 8, 923.  doi: 10.1021/nn405719x

  • 加载中
    1. [1]

      Mengfei He ,  Chao Chen ,  Yue Tang ,  Si Meng ,  Zunfa Wang ,  Liyu Wang ,  Jiabao Xing ,  Xinyu Zhang ,  Jiahui Huang ,  Jiangbo Lu ,  Hongmei Jing ,  Xiangyu Liu ,  Hua Xu . Epitaxial Growth of Nonlayered 2D MnTe Nanosheets with Thickness-Tunable Conduction for p-Type Field Effect Transistor and Superior Contact Electrode. Acta Physico-Chimica Sinica, 2025, 41(2): 100016-. doi: 10.3866/PKU.WHXB202310029

    2. [2]

      Jiahong ZHENG , Jingyun YANG . Preparation and electrochemical properties of hollow dodecahedral CoNi2S4 supported by MnO2 nanowires. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1881-1891. doi: 10.11862/CJIC.20240170

    3. [3]

      You Wu ,  Chang Cheng ,  Kezhen Qi ,  Bei Cheng ,  Jianjun Zhang ,  Jiaguo Yu ,  Liuyang Zhang . ZnO/D-A共轭聚合物S型异质结高效光催化产H2O2及其电荷转移动力学研究. Acta Physico-Chimica Sinica, 2024, 40(11): 2406027-. doi: 10.3866/PKU.WHXB202406027

    4. [4]

      Zhongxin YU , Wei SONG , Yang LIU , Yuxue DING , Fanhao MENG , Shuju WANG , Lixin YOU . Fluorescence sensing on chlortetracycline of a Zn-coordination polymer based on mixed ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2415-2421. doi: 10.11862/CJIC.20240304

    5. [5]

      Bao Jia ,  Yunzhe Ke ,  Shiyue Sun ,  Dongxue Yu ,  Ying Liu ,  Shuaishuai Ding . Innovative Experimental Teaching for the Preparation and Modification of Conductive Organic Polymer Thin Films in Undergraduate Courses. University Chemistry, 2024, 39(10): 271-282. doi: 10.12461/PKU.DXHX202404121

    6. [6]

      Xiao SANG , Qi LIU , Jianping LANG . Synthesis, structure, and fluorescence properties of Zn(Ⅱ) coordination polymers containing tetra-alkenylpyridine ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2124-2132. doi: 10.11862/CJIC.20240158

    7. [7]

      Xiaotian ZHU , Fangding HUANG , Wenchang ZHU , Jianqing ZHAO . Layered oxide cathode for sodium-ion batteries: Surface and interface modification and suppressed gas generation effect. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 254-266. doi: 10.11862/CJIC.20240260

    8. [8]

      Junjie Zhang ,  Yue Wang ,  Qiuhan Wu ,  Ruquan Shen ,  Han Liu ,  Xinhua Duan . Preparation and Selective Separation of Lightweight Magnetic Molecularly Imprinted Polymers for Trace Tetracycline Detection in Milk. University Chemistry, 2024, 39(5): 251-257. doi: 10.3866/PKU.DXHX202311084

    9. [9]

      Xingchao Zhao ,  Xiaoming Li ,  Ming Liu ,  Zijin Zhao ,  Kaixuan Yang ,  Pengtian Liu ,  Haolan Zhang ,  Jintai Li ,  Xiaoling Ma ,  Qi Yao ,  Yanming Sun ,  Fujun Zhang . 倍增型全聚合物光电探测器及其在光电容积描记传感器上的应用. Acta Physico-Chimica Sinica, 2025, 41(1): 2311021-. doi: 10.3866/PKU.WHXB202311021

    10. [10]

      Liyang ZHANG , Dongdong YANG , Ning LI , Yuanyu YANG , Qi MA . Crystal structures, luminescent properties and Hirshfeld surface analyses of three cadmium(Ⅱ) complexes based on 2-(3-(pyridin-2-yl)-1H-pyrazol-1-yl)benzoate. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1943-1952. doi: 10.11862/CJIC.20240079

    11. [11]

      . 

      南开大学师唯/华北电力大学（保定）刘景维：二维配位聚合物中有序的亲锂冠醚位点用于无枝晶锂沉积

      . CCS Chemistry, 2025, 7(0): -.

    12. [12]

      Hong LI , Xiaoying DING , Cihang LIU , Jinghan ZHANG , Yanying RAO . Detection of iron and copper ions based on gold nanorod etching colorimetry. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 953-962. doi: 10.11862/CJIC.20230370

    13. [13]

      Kexin Dong ,  Chuqi Shen ,  Ruyu Yan ,  Yanping Liu ,  Chunqiang Zhuang ,  Shijie Li . Integration of Plasmonic Effect and S-Scheme Heterojunction into Ag/Ag3PO4/C3N5 Photocatalyst for Boosted Photocatalytic Levofloxacin Degradation. Acta Physico-Chimica Sinica, 2024, 40(10): 2310013-. doi: 10.3866/PKU.WHXB202310013

    14. [14]

      Xinyu Liu ,  Weiran Hu ,  Zhengkai Li ,  Wei Ji ,  Xiao Ni . Algin Lab: Surging Luminescent Sea. University Chemistry, 2024, 39(5): 396-404. doi: 10.3866/PKU.DXHX202312021

    15. [15]

      Hailang JIA , Hongcheng LI , Pengcheng JI , Yang TENG , Mingyun GUAN . Preparation and performance of N-doped carbon nanotubes composite Co3O4 as oxygen reduction reaction electrocatalysts. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 693-700. doi: 10.11862/CJIC.20230402

    16. [16]

      Lina Guo ,  Ruizhe Li ,  Chuang Sun ,  Xiaoli Luo ,  Yiqiu Shi ,  Hong Yuan ,  Shuxin Ouyang ,  Tierui Zhang . 层状双金属氢氧化物的层间阴离子对衍生的Ni-Al2O3催化剂光热催化CO2甲烷化反应的影响. Acta Physico-Chimica Sinica, 2025, 41(1): 2309002-. doi: 10.3866/PKU.WHXB202309002

    17. [17]

      Rui Li ,  Huan Liu ,  Yinan Jiao ,  Shengjian Qin ,  Jie Meng ,  Jiayu Song ,  Rongrong Yan ,  Hang Su ,  Hengbin Chen ,  Zixuan Shang ,  Jinjin Zhao . 卤化物钙钛矿的单双向离子迁移. Acta Physico-Chimica Sinica, 2024, 40(11): 2311011-. doi: 10.3866/PKU.WHXB202311011

    18. [18]

      Qingtang ZHANG , Xiaoyu WU , Zheng WANG , Xiaomei WANG . Performance of nano Li2FeSiO4/C cathode material co-doped by potassium and chlorine ions. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1689-1696. doi: 10.11862/CJIC.20240115

    19. [19]

      Qi Li ,  Pingan Li ,  Zetong Liu ,  Jiahui Zhang ,  Hao Zhang ,  Weilai Yu ,  Xianluo Hu . Fabricating Micro/Nanostructured Separators and Electrode Materials by Coaxial Electrospinning for Lithium-Ion Batteries: From Fundamentals to Applications. Acta Physico-Chimica Sinica, 2024, 40(10): 2311030-. doi: 10.3866/PKU.WHXB202311030

    20. [20]

      Haitang WANG , Yanni LING , Xiaqing MA , Yuxin CHEN , Rui ZHANG , Keyi WANG , Ying ZHANG , Wenmin WANG . Construction, crystal structures, and biological activities of two LnⅢ3 complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1474-1482. doi: 10.11862/CJIC.20240188

Get Citation
PDF
XML
Metrics
  • PDF Downloads(0)
  • Abstract views(1103)
  • HTML views(94)

通讯作者: 陈斌, bchen63@163.com
  • 1. 

    沈阳化工大学材料科学与工程学院 沈阳 110142

  1. 本站搜索
  2. 百度学术搜索
  3. 万方数据库搜索
  4. CNKI搜索
Address：Zhongguancun North First Street 2,100190 Beijing, PR China Tel: +86-010-82449177-888
Powered By info@rhhz.net

/

DownLoad:  Full-Size Img  PowerPoint
Return