Citation: Zhi Kangkang, Dong Aijun, Yang Xin, Zhao Qianyu, Zhao Haitian, Zhang Hua, Wang Jing, Xu Pengfei. Preparation and Adsorption Properties Study of Glucose Magnetic Molecularly Imprinted Polymers with Dual Functional Monomers[J]. Acta Chimica Sinica, ;2015, 74(2): 199-207. doi: 10.6023/A15090636 shu

Preparation and Adsorption Properties Study of Glucose Magnetic Molecularly Imprinted Polymers with Dual Functional Monomers

Zhi Kangkang ^a,b ,
Dong Aijun ^a ,
Yang Xin ^a,*,, ,
Zhao Qianyu ^a ,
Zhao Haitian ^a ,
Zhang Hua ^a ,
Wang Jing ^a,b,*,, ,
Xu Pengfei ^a

a.
School of Chemical Engineering and Technology, Harbin Institute of Technology, Harbin 150000, China
b.
Key Laboratory of Agro-Product Quality and Safety, Institute of Quality Standard and Testing Technology for Agro-Product, Chinese Academy of Agricultural Sciences, Beijing 100081, China

Corresponding author: Yang Xin, yangxin@hit.edu.cn Wang Jing, w_jing2001@126.com
Received Date: 29 September 2015

Fund Project: the Outstanding Academic Leaders of Harbin No. 2014RFXXJ113

Figures(15)

In this paper, dual functional monomers (concanavalin A and aminobenzeneboronic acid) method is applied to molecular imprinting technique, three synthetic methods of functional monomer were designed and their ability to adsorb glucose was evaluated. Step-by-step method (A1) was found to be a good synthetic method for selective adsorption, which could adsorb glucose powerfully. A kind of magnetic molecularly imprinted polymers (MMIPs) was synthesized by step-by-step method, in which superparamagnetic Fe₃O₄ nanoparticles were firstly synthesized by hydrothermal synthetic method and uniform SiO₂-coated Fe₃O₄ (Fe₃O₄@SiO₂) nanoparticles were prepared via Sol-gel method. The following Fe₃O₄@SiO₂ reacted with (3-aminopropyl)triethoxysilane to produce Fe₃O₄@SiO₂@NH₂. The aminated nanoparticles combine with concanavalin A to form Fe₃O₄@SiO₂@NH₂@ConA in the presence of disuccinimidyl suberate. Subsequently, the single-functionalized nanoparticles binded with aminobenzeneboronic acid to form Fe₃O₄@SiO₂@NH₂@APBA-ConA in the presence of disuccinimidyl suberate. Eventually, the MMIPs for glucose selective recognition, with core-shell structure, were synthesized by surface molecular imprinting method, using glucose (Glu) as template molecule, concanavalin A (ConA) and aminobenzeneboronic acid (APBA) as dual functional monomers, N,N'-methylenebisacrylamide as the crosslinking agent, ammonium peroxydisulfate as the initiator, superparamagnetic nanoparticles as magnetic carrier. The MMIPs were characterized by X-ray diffraction (XRD), energy dispersive spectrometer (EDS), scanning electron microscopy (SEM), Fourier transform infrared spectra (FT-IR), vibrating sample magnetometer (VSM) and thermogravimetric analysis (TGA). The SEM showed the nanoparticles were highly dispersive and uniform. The EDS, FT-IR and TGA revealed the success of step-by-step method. The VSM demonstrated the saturation magnetization values of Fe₃O₄ and MMIPs were 96.661 emu/g and 45.064 emu/g, respectively. The study on kinetics of MMIPs showed that the adsorption reaction could be considered as a second order reaction. The thermodynamics research revealed that the adsorption of MMIPs was fitted to Langmuir isotherms. The study on selective adsorption displayed that MMIPs had maximum imprinting factor of 2.93 and best selectivity. The class specific study of MMIPs showed that it could be applied to extraction and separation of glucosides.
- dual functional monomers,
- molecular imprinted,
- glucose,
- class specific,
- glucoside,
- superparamagnetic nanoparticles
1. [1]
2. [2]
  Guo, T.; Deng, Q.; Fang, G.; Liu, C.; Huang, X.; Wang, S. Biosens. Bioelectron. 2015, 74, 498.
3. [3]
  Qiu, C.; Yang, W.; Zhou, Z.; Yan, Y.; Xu, W. J. Appl. Polym. Sci. 2015, 132, 41.
4. [4]
  Gupta, V. K.; Yola, M. L.; Eren, T.; Atar, N. Sens. Actuators, B 2015, 218, 215.
5. [5]
  Eren, T.; Atar, N.; Yola, M. L.; Karimi-Maleh, H. Food Chem. 2015, 185, 430.
6. [6]
  Miura, C.; Li, H.; Matsunaga, H.; Haginaka, J.J. Pharm. Biomed. Anal. 2015, 114, 139.
7. [7]
  Huynh, T. P.; Kutner, W.Biosens. Bioelectron. 2015, 74, 856.
8. [8]
9. [9]
  Ramstroem, O.; Andersson, L. I.; Mosbach, K. J. Org. Chem. 1993, 58, 7562.
10. [10]
11. [11]
12. [12]
  Ahmadi, M. A.; Shadizadeh, S. J. Dispersion Sci. Technol. 2015, 83, 441.
13. [13]
  Acevedo, B.; Barriocanal, C.; Lupul, I.; Gryglewicz, G. Fuel 2015, 151, 83.
14. [14]
  Ahmadi, M. A.; Shadizadeh, S. J. Dispersion Sci. Technol. 2015, 36, 441.
15. [15]
  Yang, C.; Tan, R. Q. Mater. Sci. 2010, 45, 5347.
16. [16]
17. [17]
18. [18]
  Lu, Y.-W.; Chen, C.-W. Anal. Chem. 2013, 85, 8268.
19. [19]
20. [20]
21. [21]
  Huang, W.-X.; Yang, X.; Zhao, S. Analyst 2013, 138, 6653.
1. [1]
  Qiangqiang SUN , Pengcheng ZHAO , Ruoyu WU , Baoyue CAO . Multistage microporous bifunctional catalyst constructed by P-doped nickel-based sulfide ultra-thin nanosheets for energy-efficient hydrogen production from water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1151-1161. doi: 10.11862/CJIC.20230454
2. [2]
  Yuhao SUN , Qingzhe DONG , Lei ZHAO , Xiaodan JIANG , Hailing GUO , Xianglong MENG , Yongmei GUO . Synthesis and antibacterial properties of silver-loaded sod-based zeolite. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 761-770. doi: 10.11862/CJIC.20230169
3. [3]
  Yufang GAO , Nan HOU , Yaning LIANG , Ning LI , Yanting ZHANG , Zelong LI , Xiaofeng LI . Nano-thin layer MCM-22 zeolite: Synthesis and catalytic properties of trimethylbenzene isomerization reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1079-1087. doi: 10.11862/CJIC.20240036
4. [4]
  Chunmei GUO , Weihan YIN , Jingyi SHI , Jianhang ZHAO , Ying CHEN , Quli FAN . Facile construction and peroxidase-like activity of single-atom platinum nanozyme. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1633-1639. doi: 10.11862/CJIC.20240162
5. [5]
  Juan WANG , Zhongqiu WANG , Qin SHANG , Guohong WANG , Jinmao LI . NiS and Pt as dual co-catalysts for the enhanced photocatalytic H₂ production activity of BaTiO₃ nanofibers. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1719-1730. doi: 10.11862/CJIC.20240102
6. [6]
  Guimin ZHANG , Wenjuan MA , Wenqiang DING , Zhengyi FU . Synthesis and catalytic properties of hollow AgPd bimetallic nanospheres. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 963-971. doi: 10.11862/CJIC.20230293
7. [7]
  Yang YANG , Pengcheng LI , Zhan SHU , Nengrong TU , Zonghua WANG . Plasmon-enhanced upconversion luminescence and application of molecular detection. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 877-884. doi: 10.11862/CJIC.20230440
8. [8]
  Siyu HOU , Weiyao LI , Jiadong LIU , Fei WANG , Wensi LIU , Jing YANG , Ying ZHANG . Preparation and catalytic performance of magnetic nano iron oxide by oxidation co-precipitation method. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1577-1582. doi: 10.11862/CJIC.20230469
9. [9]
  Yuanpei ZHANG , Jiahong WANG , Jinming HUANG , Zhi HU . Preparation of magnetic mesoporous carbon loaded nano zero-valent iron for removal of Cr(Ⅲ) organic complexes from high-salt wastewater. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1731-1742. doi: 10.11862/CJIC.20240077
10. [10]
  Peiran ZHAO , Yuqian LIU , Cheng HE , Chunying DUAN . A functionalized Eu³⁺ metal-organic framework for selective fluorescent detection of pyrene. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 713-724. doi: 10.11862/CJIC.20230355
11. [11]
  Tiantian MA , Sumei LI , Chengyu ZHANG , Lu XU , Yiyan BAI , Yunlong FU , Wenjuan JI , Haiying YANG . Methyl-functionalized Cd-based metal-organic framework for highly sensitive electrochemical sensing of dopamine. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 725-735. doi: 10.11862/CJIC.20230351
12. [12]
  Yan LIU , Jiaxin GUO , Song YANG , Shixian XU , Yanyan YANG , Zhongliang YU , Xiaogang HAO . Exclusionary recovery of phosphate anions with low concentration from wastewater using a CoNi-layered double hydroxide/graphene electronically controlled separation film. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1775-1783. doi: 10.11862/CJIC.20240043
13. [13]
  Yuanchao LI , Weifeng HUANG , Pengchao LIANG , Zifang ZHAO , Baoyan XING , Dongliang YAN , Li YANG , Songlin WANG . Effect of heterogeneous dual carbon sources on electrochemical properties of LiMn_0.8Fe_0.2PO₄/C composites. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 751-760. doi: 10.11862/CJIC.20230252
14. [14]
  Yingchun ZHANG , Yiwei SHI , Ruijie YANG , Xin WANG , Zhiguo SONG , Min WANG . Dual ligands manganese complexes based on benzene sulfonic acid and 2, 2′-bipyridine: Structure and catalytic properties and mechanism in Mannich reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1501-1510. doi: 10.11862/CJIC.20240078
15. [15]
  Ming ZHENG , Yixiao ZHANG , Jian YANG , Pengfei GUAN , Xiudong LI . Energy storage and photoluminescence properties of Sm³⁺-doped Ba_0.85Ca_0.15Ti_0.90Zr_0.10O₃ lead-free multifunctional ferroelectric ceramics. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 686-692. doi: 10.11862/CJIC.20230388
16. [16]
  Hongyi LI , Aimin WU , Liuyang ZHAO , Xinpeng LIU , Fengqin CHEN , Aikui LI , Hao HUANG . Effect of Y(PO₃)₃ double-coating modification on the electrochemical properties of Li[Ni_0.8Co_0.15Al_0.05]O₂. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1320-1328. doi: 10.11862/CJIC.20230480
17. [17]
  Xin XIONG , Qian CHEN , Quan XIE . First principles study of the photoelectric properties and magnetism of La and Yb doped AlN. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1519-1527. doi: 10.11862/CJIC.20240064
18. [18]
  Siyi ZHONG , Xiaowen LIN , Jiaxin LIU , Ruyi WANG , Tao LIANG , Zhengfeng DENG , Ao ZHONG , Cuiping HAN . Targeting imaging and detection of ovarian cancer cells based on fluorescent magnetic carbon dots. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1483-1490. doi: 10.11862/CJIC.20240093
19. [19]
  Xiutao Xu , Chunfeng Shao , Jinfeng Zhang , Zhongliao Wang , Kai Dai . Rational Design of S-Scheme CeO₂/Bi₂MoO₆ Microsphere Heterojunction for Efficient Photocatalytic CO₂ Reduction. Acta Physico-Chimica Sinica, 2024, 40(10): 2309031-. doi: 10.3866/PKU.WHXB202309031
20. [20]
  Zhaoyang WANG , Chun YANG , Yaoyao Song , Na HAN , Xiaomeng LIU , Qinglun WANG . Lanthanide(Ⅲ) complexes derived from 4′-(2-pyridyl)-2, 2′∶6′, 2″-terpyridine: Crystal structures, fluorescent and magnetic properties. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1442-1451. doi: 10.11862/CJIC.20240114

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(1145)
HTML views(227)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142