Citation: SHI Wei-Dong, REN Ao, LIU Chun-Bo, BAI Hong-Ye, CHE Guang-Bo, SUN He-Yi, CONG Yao. Synthesis, Crystal Structure and Photocatalytic Property of Co(Ⅱ) Compound with Dipyrido[3,2-a∶2’,3’-c]-phenazine-2-carboxylic Acid[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(12): 2649-2654. doi: 10.3969/j.issn.1001-4861.2013.00.404 shu

Synthesis, Crystal Structure and Photocatalytic Property of Co(Ⅱ) Compound with Dipyrido[3,2-a∶2’,3’-c]-phenazine-2-carboxylic Acid

1.
School of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang, Jiangsu 212013, China

Received Date: 14 May 2013
Available Online: 9 October 2013
Fund Project: 国家科学自然基金(No.61205040)，江苏大学自然科学基金(No.09JDG001，11jdg104)，江苏省自然科学基金(No.BK2012701，BK2011528)资助项目。 (No.61205040)，江苏大学自然科学基金(No.09JDG001，11jdg104)，江苏省自然科学基金(No.BK2012701，BK2011528)

[CoCl_0.5(H₂O)_0.5(HDPPZC)₂](PW₁₂O₄₀)_0.5·3.5H₂O (1) has been synthesized under hydrothermal conditions using HDPPZC (dipyrido[3,2-a∶2',3'-c]-phenazine-2-carboxylic acid) as a neutral organic ligand. Compound 1 has been characterized by single-crystal X-ray diffraction, elemental analysis, UV-Vis spectrum and thermogravimetric analysis (TGA). It crystallizes in triclinic, space group P1 with a=1.036 0(2) nm, b=1.564 0(3) nm, c=1.656 0(3) nm, α=80.99(3)°, β=84.93(3)°, γ=85.44(3)°, V=2.633 9(9) nm³, Z=1. Single-crystal X-ray diffraction analysis reveals that compounds 1 consists of a discrete dinuclear, linked by hydrogen bonding and π-π stacking interactions into 2D supramolecular framework. Furthermore, we studied the Rhodamine B (RhB) photodegration process by Compound 1 as the catalyst. CCDC: 968312.
- cobalt(Ⅱ) compound;crystal structure;photocatalytic property
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沈阳化工大学材料科学与工程学院沈阳 110142