Citation: SUN Yue, ZHANG Xian-Hui, NA Yan-Xiang, LI Chang-Li, FENG Ke-Cheng. Construction of Organic-Inorganic Hybrid from Dawson-Type Tungstophosphate and Tetranuclear Copper Complex[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(12): 2568-2574. doi: 10.3969/j.issn.1001-4861.2013.00.401
-
A novel hybrid compound [CuCl(H2O)4)][CuCl(H2O)(Phen)][{(CuPhen)2Cl2}2(bdc)]2[P2W18O62]·5H2O(1) (Phen=1,10-phenanthroline and bdc=1,4-benzenedicarboxylate), containing multinuclear CuⅡ complex cations, has been obtained in hydrothermal conditions and characterized by IR, elemental, thermogravimetric, electrochemical and single-crystal X-ray diffraction analysis. The main structural feature to this compound is the copper-Phen complex moieties which compose new tetranuclear copper-Phen complex cation [{(CuPhen)2Cl2}2(bdc)]2+ bridged by Cl and bdc ligands. Furthermore, a Compound 1-modiffied carbon paste electrode (1-CPE) displays the good electrocatalytic activity toward the reduction of nitrite. CCDC: 952036.
-
-
[1]
[1] Pope M T, MÜ ller A. Angew. Chem. Int. Ed., 1991, 30:34-48
-
[2]
[2] Hill C L, Prosser-McCartha C M. Coord. Chem. Rev., 1995, 143:407-455
-
[3]
[3] MÜ ller A, Peters F, Pope M T, et al. Chem. Rev., 1998, 98: 239-271
-
[4]
[4] Rhule J T, Hill C L, Judd D A, et al. Chem. Rev., 1998, 98: 327-357
-
[5]
[5] Gouzerh P, Proust A. Chem. Rev., 1998, 98:77-111
-
[6]
[6] Clemente-Juan J M, Coronado R. Coord. Chem. Rev., 1999, 193-195:361-394
-
[7]
[7] Hagraman P J, Hagraman K, Zubieta J. Angew. Chem. Int. Ed, 1999, 38:2638-2684
-
[8]
[8] Chesnut D J, Hagrman D, Zapf P J, et al. J. Coord. Chem. Rev., 1999, 190-192:737-769
-
[9]
[9] Hagrman P J, Finn R C, Zubieta J. Solid State Sci., 2001, 3: 745-774
-
[10]
[10] Kozhevnikov I V. Catalsis by Polyoxometalates. Chichester (UK): Wiley, 2002.
-
[11]
[11] Contant R, Hervé G. Rev. Inorg. Chem., 2002, 22:63-111
-
[12]
[12] Ushak S, Spodine E, Fur E L, et al. Inorg. Chem., 2006, 45: 5393-5399
-
[13]
[13] Burrows A D, Chan C W, Chowdhry M M. Chem. Soc. Rev., 1995, 24:329-339
-
[14]
[14] Wang S T, Wang E B, Hou Y, et al. Inorg. Chim. Acta, 2003, 349:123-127
-
[15]
[15] Ghosh A K, Ghoshal D, Ribas J, et al. Cryst. Growth Des., 2006, 6:36-39
-
[16]
[16] Reinoso S, Vitoria P, Felices L S, et al. Chem. Eur. J., 2005, 11:1538-1548
-
[17]
[17] Reinoso S, Vitoria P, Felices L S, et al. Inorg. Chem., 2006, 45:108-118
-
[18]
[18] Shivaiah V, Chatterijee T, Srinivasu K, et al. Eur. J. Inorg. Chem., 2007:231-234
-
[19]
[19] Reinoso S, Vitoria P, Gutié rrez-Zorrilla J M, et al. Inorg. Chem., 2007, 46:4010-4021
-
[20]
[20] Bian H, Xu J, Gu W, et al. Inorg. Chem. Commun., 2003, 6: 573-576
-
[21]
[21] Mukherjee P A, Hoshal D, Zangrando E, et al. Eur. J. Inorg. Chem., 2004:4675-4680
-
[22]
[22] Paul B, Zimmermann B, Fromm K M, et al. Z. Anorg. Allgem. Chem., 2004, 630:1650-1654
-
[23]
[23] Contant R. Inorg. Synth., 1990, 27:104-109
-
[24]
[24] WANG En-Bo (王恩波), HU Chang-Wen (胡长文), XU Lin (许琳). Introduction of Polyacid Chemistry (多酸化学导论). Beijing: Chemical Industry Press, 1998.
-
[25]
[25] Zhang C D, Liu S X, Ma F J, et al. Dalton Trans., 2010, 39: 8033-8037
-
[26]
[26] Zhao J W, Zheng S T, Liu W, et al. J. Solid State Chem., 2008, 181:637-645
-
[27]
[27] Niu J, Guo D, Zhao J, et al. New J. Chem., 2004, 28:980- 987
-
[28]
[28] Lu Y, Xu Y, Li Y, et al. Inorg. Chem., 2006, 45:2055-2060
-
[29]
[29] Tian A, Ying J, Peng J, et al. Inorg. Chem., 2008, 47:3274- 3283
-
[30]
[30] Janiak C. J. Chem. Soc., Dalton Trans., 2000:3885-3896
-
[31]
[31] Deakin L, Arif A M, Miller J S. Inorg. Chem., 1999, 38: 5072-5077
-
[32]
[32] Massoud S S, Mautner F A, Vicente R, et al. Inorg. Chim. Acta, 2006, 359:1489-1500
-
[33]
[33] Sadakane M, Steckhan E. Chem. Rev., 1998, 98:219-237
-
[34]
[34] McCormac T, Fabre B, Bidan G J. Electroanal. Chem., 1997, 425:49-54
-
[1]
-
-
[1]
Tiantian MA , Sumei LI , Chengyu ZHANG , Lu XU , Yiyan BAI , Yunlong FU , Wenjuan JI , Haiying YANG . Methyl-functionalized Cd-based metal-organic framework for highly sensitive electrochemical sensing of dopamine. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 725-735. doi: 10.11862/CJIC.20230351
-
[2]
Jingjing QING , Fan HE , Zhihui LIU , Shuaipeng HOU , Ya LIU , Yifan JIANG , Mengting TAN , Lifang HE , Fuxing ZHANG , Xiaoming ZHU . Synthesis, structure, and anticancer activity of two complexes of dimethylglyoxime organotin. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1301-1308. doi: 10.11862/CJIC.20240003
-
[3]
Lu XU , Chengyu ZHANG , Wenjuan JI , Haiying YANG , Yunlong FU . Zinc metal-organic framework with high-density free carboxyl oxygen functionalized pore walls for targeted electrochemical sensing of paracetamol. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 907-918. doi: 10.11862/CJIC.20230431
-
[4]
Jing SU , Bingrong LI , Yiyan BAI , Wenjuan JI , Haiying YANG , Zhefeng Fan . Highly sensitive electrochemical dopamine sensor based on a highly stable In-based metal-organic framework with amino-enriched pores. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1337-1346. doi: 10.11862/CJIC.20230414
-
[5]
Xiaoling LUO , Pintian ZOU , Xiaoyan WANG , Zheng LIU , Xiangfei KONG , Qun TANG , Sheng WANG . Synthesis, crystal structures, and properties of lanthanide metal-organic frameworks based on 2, 5-dibromoterephthalic acid ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1143-1150. doi: 10.11862/CJIC.20230271
-
[6]
Yuanpei ZHANG , Jiahong WANG , Jinming HUANG , Zhi HU . Preparation of magnetic mesoporous carbon loaded nano zero-valent iron for removal of Cr(Ⅲ) organic complexes from high-salt wastewater. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1731-1742. doi: 10.11862/CJIC.20240077
-
[7]
Qiuyang LUO , Xiaoning TANG , Shu XIA , Junnan LIU , Xingfu YANG , Jie LEI . Application of a densely hydrophobic copper metal layer in-situ prepared with organic solvents for protecting zinc anodes. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1243-1253. doi: 10.11862/CJIC.20240110
-
[8]
Youlin SI , Shuquan SUN , Junsong YANG , Zijun BIE , Yan CHEN , Li LUO . Synthesis and adsorption properties of Zn(Ⅱ) metal-organic framework based on 3, 3', 5, 5'-tetraimidazolyl biphenyl ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1755-1762. doi: 10.11862/CJIC.20240061
-
[9]
Endong YANG , Haoze TIAN , Ke ZHANG , Yongbing LOU . Efficient oxygen evolution reaction of CuCo2O4/NiFe-layered bimetallic hydroxide core-shell nanoflower sphere arrays. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 930-940. doi: 10.11862/CJIC.20230369
-
[10]
Xin MA , Ya SUN , Na SUN , Qian KANG , Jiajia ZHANG , Ruitao ZHU , Xiaoli GAO . A Tb2 complex based on polydentate Schiff base: Crystal structure, fluorescence properties, and biological activity. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1347-1356. doi: 10.11862/CJIC.20230357
-
[11]
Zhaoyang WANG , Chun YANG , Yaoyao Song , Na HAN , Xiaomeng LIU , Qinglun WANG . Lanthanide(Ⅲ) complexes derived from 4′-(2-pyridyl)-2, 2′∶6′, 2″-terpyridine: Crystal structures, fluorescent and magnetic properties. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1442-1451. doi: 10.11862/CJIC.20240114
-
[12]
Jiahong ZHENG , Jiajun SHEN , Xin BAI . Preparation and electrochemical properties of nickel foam loaded NiMoO4/NiMoS4 composites. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 581-590. doi: 10.11862/CJIC.20230253
-
[13]
Zhihuan XU , Qing KANG , Yuzhen LONG , Qian YUAN , Cidong LIU , Xin LI , Genghuai TANG , Yuqing LIAO . Effect of graphene oxide concentration on the electrochemical properties of reduced graphene oxide/ZnS. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1329-1336. doi: 10.11862/CJIC.20230447
-
[14]
Qin ZHU , Jiao MA , Zhihui QIAN , Yuxu LUO , Yujiao GUO , Mingwu XIANG , Xiaofang LIU , Ping NING , Junming GUO . Morphological evolution and electrochemical properties of cathode material LiAl0.08Mn1.92O4 single crystal particles. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1549-1562. doi: 10.11862/CJIC.20240022
-
[15]
Qingtang ZHANG , Xiaoyu WU , Zheng WANG , Xiaomei WANG . Performance of nano Li2FeSiO4/C cathode material co-doped by potassium and chlorine ions. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1689-1696. doi: 10.11862/CJIC.20240115
-
[16]
Wenxiu Yang , Jinfeng Zhang , Quanlong Xu , Yun Yang , Lijie Zhang . Bimetallic AuCu Alloy Decorated Covalent Organic Frameworks for Efficient Photocatalytic Hydrogen Production. Acta Physico-Chimica Sinica, 2024, 40(10): 2312014-. doi: 10.3866/PKU.WHXB202312014
-
[17]
Yuanchao LI , Weifeng HUANG , Pengchao LIANG , Zifang ZHAO , Baoyan XING , Dongliang YAN , Li YANG , Songlin WANG . Effect of heterogeneous dual carbon sources on electrochemical properties of LiMn0.8Fe0.2PO4/C composites. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 751-760. doi: 10.11862/CJIC.20230252
-
[18]
Xinpeng LIU , Liuyang ZHAO , Hongyi LI , Yatu CHEN , Aimin WU , Aikui LI , Hao HUANG . Ga2O3 coated modification and electrochemical performance of Li1.2Mn0.54Ni0.13Co0.13O2 cathode material. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1105-1113. doi: 10.11862/CJIC.20230488
-
[19]
Yan LIU , Jiaxin GUO , Song YANG , Shixian XU , Yanyan YANG , Zhongliang YU , Xiaogang HAO . Exclusionary recovery of phosphate anions with low concentration from wastewater using a CoNi-layered double hydroxide/graphene electronically controlled separation film. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1775-1783. doi: 10.11862/CJIC.20240043
-
[20]
Peiran ZHAO , Yuqian LIU , Cheng HE , Chunying DUAN . A functionalized Eu3+ metal-organic framework for selective fluorescent detection of pyrene. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 713-724. doi: 10.11862/CJIC.20230355
-
[1]
Metrics
- PDF Downloads(0)
- Abstract views(232)
- HTML views(23)