Citation: XU Jing, CHEN Min-Dong. Syntheses and Crystal Structures of Complexes Based on 4-[(1H-imidazol-4-yl)methylamino]benzoic Acid Ligand[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(12): 2666-2672. doi: 10.3969/j.issn.1001-4861.2013.00.398 shu

Syntheses and Crystal Structures of Complexes Based on 4-[(1H-imidazol-4-yl)methylamino]benzoic Acid Ligand

XU Jing ,
CHEN Min-Dong

1.
Key laboratory of atmospheric environment monitoring and pollution control, School of environment science and technology, Nanjing University of Information Science and Technology, Nanjing 210044, China

Received Date: 19 July 2013
Available Online: 27 August 2013
Fund Project: 国家自然科学基金(No.21272118)资助项目。 (No.21272118)

Reactions of ligand 4-[(1H-imidazol-4-yl)methylamino]benzoic acid (H₂L) with transition metal salts led to the formation of three complexes [M(HL)₂(H₂O)₂](M(Ⅱ)=Mn(Ⅱ)(1), Cd(Ⅱ)(2), Cu(Ⅱ)(3)) under different conditions. The single crystal X-ray diffraction analyses revealed that three complexes crystallized in the same triclinic space group P1 are isomorphous and isostructural, and the molecules are further connected by hydrogen bonds interactions resulting in formation of 3D structures. Thermal stability and electrochemistry properties of complexes were also investigated. CCDC: 945340, 1; 945338, 2; 945339, 3.
- 4-[(1H-imidazol-4-yl)methylamino]benzoic acid;complex;hydrgen bonding interaction;properties
1. [1]
  [1] Bernstein J, Davey R J, Henck J O. Angew. Chem. Int. Ed., 1999, 38:3441-3461
2. [2]
  [2] Eckert H, Ward M. Chem. Mater., 2001, 13:3061-3083
3. [3]
  [3] Rao C N R, Natarajan S, Vaidhyanathan R. Angew. Chem. Int. Ed., 2004, 43:1466-1496
4. [4]
  [4] Helay F, Maris T, Wuest J D. Cryst. Growth Des., 2008, 8: 4517-4525
5. [5]
  [5] Manzano B R, Jaló n F A, Soriano M L, et al. Cryst. Growth Des., 2008, 8:15851594
6. [6]
  [6] Li Y P, Yang P. Chin. J. Chem., 2007, 5:1715-1724
7. [7]
  [7] Yang X G, Li D S, Fu F, et al. Chin. J. Chem., 2008, 26:655-660
8. [8]
  [8] ZHANG Li (张丽), NIU Su-Yun (牛淑云), JIN Jin (金晶), et al. Acta Chim. Sin. (Huaxue Xuebao), 2007, 65:1032-1038
9. [9]
  [9] Cote A P, Benin A I, Ockwig N W, et al. Science, 2005, 310: 1166-1170.
10. [10]
  [10] Yaghi O M, O′Keeffe M, Ockwig N W, et al. Nature, 2003, 423:705-714
11. [11]
  [11] Wu C D, Hu A, Zhang L, et al. J. Am. Chem. Soc., 2005, 127:8940-8941
12. [12]
  [12] Fang Q R, Zhu G S, Xue M, et al. Cryst. Growth Des., 2008, 8:319-329
13. [13]
  [13] Koh K, Wong-Foy A G, Matzger A J. Angew. Chem. Int. Ed., 2008, 47:677-680.
14. [14]
  [14] Song Y, Zhang P, Ren X M, et al. J. Am. Chem. Soc., 2005, 127:3708-3709
15. [15]
  [15] Yigit M V, Biyikli K, Moulton B, et al. Cryst. Growth Des., 2006, 6:63-69
16. [16]
  [16] Gao H L, Ding B, Yi L, et al. Inorg. Chem. Commun., 2005, 8:151-153
17. [17]
  [17] Gao H L, Yi L, Ding B, et al. Inorg. Chem., 2006, 45:481-483
18. [18]
  [18] Ghosh S K, Bharadwaj P K. Eur. J. Inorg. Chem., 2005, 4886-4889
19. [19]
  [19] Wang H S, Zhao B, Zhai B, et al. Cryst. Growth Des., 2007, 7:1851-1857
20. [20]
  [20] Koh C K. Chem. Soc. Rev., 2002, 31:157-167
21. [21]
  [21] SAINT, Pragram for Data Extraction and Reduction, Bruker AXS, Inc.; Madison, WI, 2001.
22. [22]
  [22] Sheldrick G M. SHELXS-97, Program for Crystal Structure Solution, University of Göttingen, Germany, 1997.
23. [23]
  [23] Sheldrick G M. SHELXL-97, Program for Crystal Structure Refinement, University of Göttingen, Germany, 1997.
24. [24]
  [24] Hellyer R M, Larsen D S, Brooker S. Eur. J. Inorg. Chem., 2009, 1162-1171
25. [25]
  [25] Nicola C D, Garau F, Karabach Y Y, et al. Eur. J. Inorg. Chem., 2009, 666-676
26. [26]
  [26] Wang X L, Lin H Y, Liu G C, et al. J. Organomet. Chem., 2008, 693:2767-2774
27. [27]
  [27] Wang X L, Zhao H Y, Lin H Y, et al. Electroanalysis, 2008, 20:1055-1059
28. [28]
  [28] Younathan J N, Wood K S, Meyer T J. Inorg. Chem., 1992, 31:3280-3285
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