Citation: NIE Xue, CHEN Man-Sheng, YU Jiang-Xi. Synthesis, Crystal Structure, Thermal Stability and Luminescent Properties of Cd(Ⅱ) Complex Constructed from 3,5-Dinitrobenzoic Acid[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(12): 2704-2708. doi: 10.3969/j.issn.1001-4861.2013.00.395
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A new complex [Cd(H2O)2(DNBA)(Im)2](DNBA)·H2O has been synthesized by H2DNBA and Im with Cd(Ⅱ), where H2DNBA =3,5-dinitrobenzoic acid, Im=imidazole. The crystal belongs to orthorhombic system, space group Ccc2. The cell parameters are: a=1.324 99(4) nm, b=1.516 01(5) nm, c=2.789 22(8) nm; V=5.602 7(3) nm3, Dc=1.719 g·cm-3, Z=8, μ=0.866 mm-1, F(000)=2 912, final discrepancy factors R1=0.058 3, wR2=0.146 4. There are two mononuclear Cd(Ⅱ) complexes in the asymmetric unit of the compound, and where the two Cd(Ⅱ) ions are in the same coordination number. In addition, the luminescent property of 1 is also discussed in the liquid state at room temperature. CCDC: 952035.
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