Citation: NIE Xue, CHEN Man-Sheng, YU Jiang-Xi. Synthesis, Crystal Structure, Thermal Stability and Luminescent Properties of Cd(Ⅱ) Complex Constructed from 3,5-Dinitrobenzoic Acid[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(12): 2704-2708. doi: 10.3969/j.issn.1001-4861.2013.00.395 shu

Synthesis, Crystal Structure, Thermal Stability and Luminescent Properties of Cd(Ⅱ) Complex Constructed from 3,5-Dinitrobenzoic Acid

1.
Department of Chemistry and Materials Science, Hengyang Normal University, Hengyang, Hunan 421008, China

Received Date: 27 March 2013
Available Online: 26 May 2013
Fund Project: 湖南省自然科学基金(No.13JJ6069) (No.13JJ6069)湖南省教育厅一般项目(No.13C082)资助项目。 (No.13C082)

A new complex [Cd(H₂O)₂(DNBA)(Im)₂](DNBA)·H₂O has been synthesized by H₂DNBA and Im with Cd(Ⅱ), where H₂DNBA =3,5-dinitrobenzoic acid, Im=imidazole. The crystal belongs to orthorhombic system, space group Ccc2. The cell parameters are: a=1.324 99(4) nm, b=1.516 01(5) nm, c=2.789 22(8) nm; V=5.602 7(3) nm³, D_c=1.719 g·cm^-3, Z=8, μ=0.866 mm^-1, F(000)=2 912, final discrepancy factors R₁=0.058 3, wR₂=0.146 4. There are two mononuclear Cd(Ⅱ) complexes in the asymmetric unit of the compound, and where the two Cd(Ⅱ) ions are in the same coordination number. In addition, the luminescent property of 1 is also discussed in the liquid state at room temperature. CCDC: 952035.
- cadmium(Ⅱ) complex;crystal structure;thermal stability and fluorescent property
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沈阳化工大学材料科学与工程学院沈阳 110142