Citation: HU Bin, YAN Liu-Shui, WU Mei-Feng, DENG Chun-Jian, HUANG Wei. Studies of Zinc(Ⅱ), Copper(Ⅱ) and Ferrous(Ⅱ) Complexes Having a Tridentate [2,2’∶6’,2"-Terpyridine]-4’-carboxylate Ligand[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(12): 2595-2602. doi: 10.3969/j.issn.1001-4861.2013.00.393 shu

Studies of Zinc(Ⅱ), Copper(Ⅱ) and Ferrous(Ⅱ) Complexes Having a Tridentate [2,2’∶6’,2"-Terpyridine]-4’-carboxylate Ligand

1.
1 School of Environmental and Chemical Engineering, Nanchang Hangkong University, Nanchang 330063, China;

Received Date: 22 February 2013
Available Online: 6 August 2013
Fund Project: 国家自然科学基金(No.21165013，21171088)；中国博士后基金(No.2012M511720)；江西省自然科学基金(No.2010GZH0112)；江西省教育厅科技(青年)基金(No.DB201302155)南昌航空大学博士基金(No.EA201102327)资助项目。 (No.21165013，21171088)；中国博士后基金(No.2012M511720)；江西省自然科学基金(No.2010GZH0112)；江西省教育厅科技(青年)基金(No.DB201302155)南昌航空大学博士基金(No.EA201102327)

Three mononuclear complexes, formulated as [ZnL₂]·4H₂O(1), [CuL₂]·4H₂O(2) and [FeL₂]·4H₂O(3) (LH=[2,2'∶6',2"-terpyridine]-4'-carboxylic acid), have been synthesized under the solvothermal conditions and characterized by elemental analysis, IR spectral, and single-crystal and powder X-ray diffraction methods. Complexes 1~3 are isomorphous structures and they crystallize in the tetragonal space group I42d. The ligand shows a tridentate chelating mode where the deprotonated carboxylate unit is free of coordinative bond. Three-dimensional supramolecular networks are observed in 1~3, which are sustained by π-π stacking and hydrogen bonding interactions. In addition, the solid-state luminescence spectrum of zinc(Ⅱ) complex 1 reveals strong blue photoluminescence at room temperature. CCDC: 925947, 1; 925948, 2; 925949, 3.
- zinc(Ⅱ) complex;copper(Ⅱ) complex;ferrous(Ⅱ) complex;fluorescence property;crystal structure
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