Citation: HU Bin, YAN Liu-Shui, WU Mei-Feng, DENG Chun-Jian, HUANG Wei. Studies of Zinc(Ⅱ), Copper(Ⅱ) and Ferrous(Ⅱ) Complexes Having a Tridentate [2,2’∶6’,2"-Terpyridine]-4’-carboxylate Ligand[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(12): 2595-2602. doi: 10.3969/j.issn.1001-4861.2013.00.393
-
Three mononuclear complexes, formulated as [ZnL2]·4H2O(1), [CuL2]·4H2O(2) and [FeL2]·4H2O(3) (LH=[2,2'∶6',2"-terpyridine]-4'-carboxylic acid), have been synthesized under the solvothermal conditions and characterized by elemental analysis, IR spectral, and single-crystal and powder X-ray diffraction methods. Complexes 1~3 are isomorphous structures and they crystallize in the tetragonal space group I42d. The ligand shows a tridentate chelating mode where the deprotonated carboxylate unit is free of coordinative bond. Three-dimensional supramolecular networks are observed in 1~3, which are sustained by π-π stacking and hydrogen bonding interactions. In addition, the solid-state luminescence spectrum of zinc(Ⅱ) complex 1 reveals strong blue photoluminescence at room temperature. CCDC: 925947, 1; 925948, 2; 925949, 3.
-
-
[1]
[1] Wild A, Winter A, Schlutter F, et al. Chem. Soc. Rev., 2011, 40 (3):1459-1511
-
[2]
[2] Yuan S C, Chen H B, Wang H C. Prog. Chem., 2009, 21 (10): 2132-2152
-
[3]
[3] Pan Y X, Tong B, Zhi J G, et al. Prog. Chem., 2009, 21 (9): 1763-1771
-
[4]
[4] Constable E C. Chem. Soc. Rev., 2007, 36 (2):246-253
-
[5]
[5] Nazeeruddin M K, Pechy P, Renouard T, et al. J. Am. Chem. Soc., 2001, 123 (8):1613-1624
-
[6]
[6] Cooke M W, Hanan G S, Loiseau F, et al. J. Am. Chem. Soc., 2007, 129 (34):10479-10488
-
[7]
[7] Chou C C, Wu K L, Chi Y, et al. Angew. Chem.-Int. Ed., 2011, 50 (9):2054-2058
-
[8]
[8] Winter A, Friebe C, Chiper M, et al. J. Polym. Sci. Pol. Chem., 2009, 47 (16):4083-4098
-
[9]
[9] Seo K, Konchenko A V, Lee J, et al. J. Am. Chem. Soc., 2008, 130 (8):2553-2559
-
[10]
[10] Hayami S, Komatsu Y, Shimizu T, et al. Coord. Chem. Rev., 2011, 255 (17-18):1981-1990
-
[11]
[11] Winter A, Hager M D, Newkome G R, et al. Adv. Mater., 2011, 23 (48):5728-5748
-
[12]
[12] Wu P, Wong E L M, Ma D L, et al. Chem.-Eur. J., 2009, 15 (15):3652-3656
-
[13]
[13] Manner V W, DiPasquale A G, Mayer J M. J. Am. Chem. Soc., 2008, 130 (23):7210-7211
-
[14]
[14] Eryazici I, Moorefield C N, Newkome G R. Chem. Rev., 2008, 108 (6):1834-1895
-
[15]
[15] Cummings S D. Coord. Chem. Rev., 2009, 253 (9-10):1495-1516
-
[16]
[16] Sinha P, Raghuvanshi D S, Singh K N, et al. Polyhedron, 2012, 31 (1):227-234
-
[17]
[17] Wolpher H, Sinha S, Pan J X, et al. Inorg. Chem., 2007, 46 (3):638-651
-
[18]
[18] Schulze B, Escudero D, Friebe C, et al. Chem.-Eur. J., 2012, 18 (13):4010-4025
-
[19]
[19] Constable E C, Dunphy E L, Housecroft C E, et al. Dalton Trans., 2007, (38):4323-4332
-
[20]
[20] Husson J, Beley M, Kirsch G. Tetrahedron Lett., 2003, 44 (9): 1767-1770
-
[21]
[21] Cooke M W, Santoni M P, Hanan G S, et al. Inorg. Chem., 2008, 47 (14):6112-6114
-
[22]
[22] Park H J, Kim K H, Choi S Y, et al. Inorg. Chem., 2010, 49 (16):7340-7352
-
[23]
[23] Jarosz P, Du P W, Schneider J, et al. Inorg. Chem., 2009, 48 (20):9653-9663
-
[24]
[24] You W, Huang W, Fan Y, et al. J. Coord. Chem., 2009, 62 (13):2125-2137
-
[25]
[25] Huang W, You W, Wang L, et al. Inorg. Chim. Acta, 2009, 362 (7):2127-2135
-
[26]
[26] Huang W, Qian H F. J. Mol. Struct., 2008, 874 (1-3):64-76
-
[27]
[27] Siemens, SAINT v4 Software Reference Manual, Siemens Analytical X-Ray Systems, Inc., Madison, Wisconsin, USA, 2000.
-
[28]
[28] Sheldrick G M. SADABS, Program for Empirical Absorption Correction of Area Dectector Data, Univ. of Gottingen, Germany, 2000.
-
[29]
[29] Sheldrick G M. SHELXTL, Version 6.10 Software Reference Manual, Siemens Analytical X-Ray Systems, Inc., Madison, Wisconsin, USA, 2000.
-
[30]
[30] Wang P, Li Z, LÜ G C, et al. Inorg. Chem. Commun., 2012, 18:87-91
-
[31]
[31] Beves J E, Bray D J, Clegg J K, et al. Inorg. Chim. Acta, 2008, 361 (9-10):2582-2590
-
[1]
-
-
[1]
Xin MA , Ya SUN , Na SUN , Qian KANG , Jiajia ZHANG , Ruitao ZHU , Xiaoli GAO . A Tb2 complex based on polydentate Schiff base: Crystal structure, fluorescence properties, and biological activity. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1347-1356. doi: 10.11862/CJIC.20230357
-
[2]
Zhaoyang WANG , Chun YANG , Yaoyao Song , Na HAN , Xiaomeng LIU , Qinglun WANG . Lanthanide(Ⅲ) complexes derived from 4′-(2-pyridyl)-2, 2′∶6′, 2″-terpyridine: Crystal structures, fluorescent and magnetic properties. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1442-1451. doi: 10.11862/CJIC.20240114
-
[3]
Haitang WANG , Yanni LING , Xiaqing MA , Yuxin CHEN , Rui ZHANG , Keyi WANG , Ying ZHANG , Wenmin WANG . Construction, crystal structures, and biological activities of two LnⅢ3 complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1474-1482. doi: 10.11862/CJIC.20240188
-
[4]
Xinting XIONG , Zhiqiang XIONG , Panlei XIAO , Xuliang NIE , Xiuying SONG , Xiuguang YI . Synthesis, crystal structures, Hirshfeld surface analysis, and antifungal activity of two complexes Na(Ⅰ)/Cd(Ⅱ) assembled by 5-bromo-2-hydroxybenzoic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1661-1670. doi: 10.11862/CJIC.20240145
-
[5]
Jingjing QING , Fan HE , Zhihui LIU , Shuaipeng HOU , Ya LIU , Yifan JIANG , Mengting TAN , Lifang HE , Fuxing ZHANG , Xiaoming ZHU . Synthesis, structure, and anticancer activity of two complexes of dimethylglyoxime organotin. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1301-1308. doi: 10.11862/CJIC.20240003
-
[6]
Yingchun ZHANG , Yiwei SHI , Ruijie YANG , Xin WANG , Zhiguo SONG , Min WANG . Dual ligands manganese complexes based on benzene sulfonic acid and 2, 2′-bipyridine: Structure and catalytic properties and mechanism in Mannich reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1501-1510. doi: 10.11862/CJIC.20240078
-
[7]
Xiaoling LUO , Pintian ZOU , Xiaoyan WANG , Zheng LIU , Xiangfei KONG , Qun TANG , Sheng WANG . Synthesis, crystal structures, and properties of lanthanide metal-organic frameworks based on 2, 5-dibromoterephthalic acid ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1143-1150. doi: 10.11862/CJIC.20230271
-
[8]
Yuanpei ZHANG , Jiahong WANG , Jinming HUANG , Zhi HU . Preparation of magnetic mesoporous carbon loaded nano zero-valent iron for removal of Cr(Ⅲ) organic complexes from high-salt wastewater. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1731-1742. doi: 10.11862/CJIC.20240077
-
[9]
Qilu DU , Li ZHAO , Peng NIE , Bo XU . Synthesis and characterization of osmium-germyl complexes stabilized by triphenyl ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1088-1094. doi: 10.11862/CJIC.20240006
-
[10]
Kaimin WANG , Xiong GU , Na DENG , Hongmei YU , Yanqin YE , Yulu MA . Synthesis, structure, fluorescence properties, and Hirshfeld surface analysis of three Zn(Ⅱ)/Cu(Ⅱ) complexes based on 5-(dimethylamino) isophthalic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1397-1408. doi: 10.11862/CJIC.20240009
-
[11]
Zongfei YANG , Xiaosen ZHAO , Jing LI , Wenchang ZHUANG . Research advances in heteropolyoxoniobates. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 465-480. doi: 10.11862/CJIC.20230306
-
[12]
Gaofeng WANG , Shuwen SUN , Yanfei ZHAO , Lixin MENG , Bohui WEI . Structural diversity and luminescence properties of three zinc coordination polymers based on bis(4-(1H-imidazol-1-yl)phenyl)methanone. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 849-856. doi: 10.11862/CJIC.20230479
-
[13]
Chuanming GUO , Kaiyang ZHANG , Yun WU , Rui YAO , Qiang ZHAO , Jinping LI , Guang LIU . Performance of MnO2-0.39IrOx composite oxides for water oxidation reaction in acidic media. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1135-1142. doi: 10.11862/CJIC.20230459
-
[14]
Endong YANG , Haoze TIAN , Ke ZHANG , Yongbing LOU . Efficient oxygen evolution reaction of CuCo2O4/NiFe-layered bimetallic hydroxide core-shell nanoflower sphere arrays. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 930-940. doi: 10.11862/CJIC.20230369
-
[15]
Qiangqiang SUN , Pengcheng ZHAO , Ruoyu WU , Baoyue CAO . Multistage microporous bifunctional catalyst constructed by P-doped nickel-based sulfide ultra-thin nanosheets for energy-efficient hydrogen production from water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1151-1161. doi: 10.11862/CJIC.20230454
-
[16]
Yan LIU , Jiaxin GUO , Song YANG , Shixian XU , Yanyan YANG , Zhongliang YU , Xiaogang HAO . Exclusionary recovery of phosphate anions with low concentration from wastewater using a CoNi-layered double hydroxide/graphene electronically controlled separation film. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1775-1783. doi: 10.11862/CJIC.20240043
-
[17]
Hong LI , Xiaoying DING , Cihang LIU , Jinghan ZHANG , Yanying RAO . Detection of iron and copper ions based on gold nanorod etching colorimetry. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 953-962. doi: 10.11862/CJIC.20230370
-
[18]
Huan ZHANG , Jijiang WANG , Guang FAN , Long TANG , Erlin YUE , Chao BAI , Xiao WANG , Yuqi ZHANG . A highly stable cadmium(Ⅱ) metal-organic framework for detecting tetracycline and p-nitrophenol. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 646-654. doi: 10.11862/CJIC.20230291
-
[19]
Ruikui YAN , Xiaoli CHEN , Miao CAI , Jing REN , Huali CUI , Hua YANG , Jijiang WANG . Design, synthesis, and fluorescence sensing performance of highly sensitive and multi-response lanthanide metal-organic frameworks. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 834-848. doi: 10.11862/CJIC.20230301
-
[20]
Xiaoxia WANG , Ya'nan GUO , Feng SU , Chun HAN , Long SUN . Synthesis, structure, and electrocatalytic oxygen reduction reaction properties of metal antimony-based chalcogenide clusters. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1201-1208. doi: 10.11862/CJIC.20230478
-
[1]
Metrics
- PDF Downloads(0)
- Abstract views(537)
- HTML views(72)