Citation: ZHANG Jian-Guo, YIN Xin, WU Jin-Ting, SUN Mou, FENG Jin-Ling, ZHANG Tong-Lai, ZHOU Zun-Ning. Two High-Nitrogen Energetic Salts Based on 3,6-Dihydrazino-1,2,4,5-tetrazine[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(12): 2587-2594. doi: 10.3969/j.issn.1001-4861.2013.00.391
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Two high-nitrogen energetic salts were prepared by reacting 3,6-dihydrazino-1,2,4,5-tetrazine (DHT) and perchloric acid or nitric acid aqueous solution. Their structures have been determined by using X-ray single crystal diffraction method. (DHT)(NO3)2 (1) belongs to monoclinic, C2/c space group, a=1.300 0(6) nm, b= 0.834 9(3) nm, c=1.018 7(5) nm, β=118.89(5)°, Z=4; (DHT)(ClO4)2(2) belongs to orthorhombic, P21212 space group, a=0.980 4(4) nm, b=1.074 7(4) nm, c=0.532 5(2) nm, Z=2. The thermal decomposition was investigated with DSC and TG-DTG measurement. The non-isothermal kinetic parameters of the first exothermic process were studied by applying Kissingers, Ozawa-Doyles and Starinks methods. The critical temperature of thermal explosion and sensitivity properties also have been fully investigated. We can come to the conclusion that the two salts have potential application in sensitive energetic material area. CCDC: 884111, 1; 884112, 2.
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-
[1]
[1] Liang X, Pu X, Tian A. Chin. J. Org. Chem., 2011, 31:328-335
-
[2]
[2] HU Yin (胡银), MA Hai-Xia (马海霞), ZHANG Jiao-Qiang (张教强), et al. Chemistry (Huaxue Tongbao), 2010, 73:263 -268
-
[3]
[3] XU Song-Lin (徐松林), LEI Yong-Peng (雷永鹏), YANG Shi-Qing (阳世清), et al. Chin. J. Energ. Mater. (Hanneng Cailiao) 2006, 14:340-342
-
[4]
[4] Marcus H J, Remanick A. J. Org. Chem., 1963, 28:2372-2375
-
[5]
[5] FENG Jin-Ling (冯金玲), ZHANG Jian-Guo (张建国), WANG Kun (王昆), et al. Chem. J. Chinese Universities (Gaodeng Xuexiao Huaxue Xuebao), 2011, 32:1519-1525
-
[6]
[6] Zhang J G, Liang Y H, Feng J L, et al. Z. Anorg. Allg. Chem., 2012, 638, 1212-1218
-
[7]
[7] Sinditskii V P, Egorshev V Y, Rudakov G F, et al. Thermochim. Acta, 2012, 535, 48-57
-
[8]
[8] Huynh M H V, Hiskey M A, Archuleta J G, et al. Angew. Chem. Int. Ed., 2004, 43:5658-5661
-
[9]
[9] Zhou Y, Long X, Shu Y. Chin. J. Chem., 2010, 28:2123-2129
-
[10]
[10] Zeng Z, Hyer W S, Twamley B, et al. Synthesis-Stuttgart, 2008, 11:1775-1782
-
[11]
[11] Wang B Z, Lian P, Liu Q, et al. J. Energ. Mater., 2006, 14: 352-354
-
[12]
[12] Chavez D E, Hiskey M A, Naud D L. Propell. Explos. Pyrot., 2004, 29:209-215
-
[13]
[13] Oxley J C, Smith J L, Chen H. Thermochim. Acta, 2002, 384, 91-99
-
[14]
[14] Oxley J C, Smith J L, Zhang J, et al. Proceedings of the 28th NATAS Annual Conference on Thermal Analysis and Applications. Florida: Orlando, FLa, 2000:287-293
-
[15]
[15] Gao H, Zeng Z, Twamley B, et al. Chem. Eur. J., 2008, 14: 1282-1290
-
[16]
[16] Trohalaki S, Zellmer R J, Pachter R, et al. Toxicol. Sci., 2002, 68:498-507
-
[17]
[17] Hussain S, Mattie D R, Frazier J M. CPIA Publication, 2002, 709:141-153
-
[18]
[18] Chavez D E, Hiskey M A. J. Energ. Mater., 1999, 17:357-377
-
[19]
[19] Sheldrick G M. SHELXS-97, Program for the Solution of Crystal Structure, University of Göttingen, Germany, 1997.
-
[20]
[20] Sheldrick G M. SHELXL-97, Program for the Refining of Crystal Structure, University of Göttingen, Germany, 1997.
-
[21]
[21] Kissinger H E. Anal. Chem., 1957, 29:1702-1706
-
[22]
[22] Ozawa T. Bull. Chem. Soc. Jpn., 1965, 38:1881-1886
-
[23]
[23] Starink M J. Thermochim. Acta, 1996, 288:97-104
-
[24]
[24] Hu Z Q, Liang Y J. Thermochim. Acta, 1988, 123:135-151
-
[25]
[25] Zhang T L, Hu R Z, Xie Y, et al. Thermochim. Acta, 1994, 244:171-176
-
[26]
[26] HU Rong-Zu (胡荣祖), GAO Sheng-Li (高胜利), ZHAO Feng-Qi (赵凤起), et al. Thermal Analysis Kinetics. 2nd Ed. (热分析动力学, 2版), Beijing: Science Press, 2008.
-
[27]
[27] Jaidann M, Roy S, Lussier L S. J. Hazard. Mater., 2010, 176: 165-173
-
[28]
[28] LIU Zi-Tang (刘自铴), LAO Yun-Liang (劳允亮). Initiating Explosive Experimental (起爆药实验). Beijing: Press of Beijing Institute of Technology, 1995.
-
[1]
-
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