Citation: WANG Peng-Fei, FANG Qin, WU Guo-Zhi, WANG Xin. Synthesis, Crystal Structure and Luminescent Property of a Three-Dimensional Framework Zinc Coordination Polymer Constructed from the Benzenemulticarboxylic Acid and N-donor Ligands[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(12): 2521-2527. doi: 10.3969/j.issn.1001-4861.2013.00.387 shu

Synthesis, Crystal Structure and Luminescent Property of a Three-Dimensional Framework Zinc Coordination Polymer Constructed from the Benzenemulticarboxylic Acid and N-donor Ligands

1.
1 Center of Chemical Materials and Engineering Experiment, Department of Materials and Chemical Engineering, Chizhou College, Chizhou, Anhui 247000, China;

Received Date: 7 April 2013
Available Online: 31 May 2013
Fund Project: 国家自然科学基金(No.21101019) (No.21101019)池州学院材料学重点学科(No.2011XK04)资助项目。 (No.2011XK04)

A novel coordination polymer, [Zn₃(BTCA)₂(4,4'-bipy)₂](1) (BTCAH₃=5-bromobenzene-1,2,4-tricarboxylic acid, 4,4'-bipy=4,4'-bipyridine) has been synthesized utilizing Zn(OAc)₂·2H₂O, the rigid 5-bromobenzene-1,2,4-tricarboxylic acid and 4,4'-bipy under the hydrothermal reaction. Compound 1 was characterized by infrared spectroscopy, elemental analysis, thermogravimetric analysis and single crystal X-ray diffraction analysis. In 1, the Zn(Ⅱ) ions are linked through the carboxylate oxygen atoms of the BTCA^3- anions, forming a three-dimensional framework structure with 3-nodal and 4-connected net with Schläfli symbol of (4·7·8⁴)₂(4·7⁴·8)₂(7⁴·8²). The 4,4'-bipy ligand coordinates the Zn(Ⅱ) ions in the framework. In addition, the thermal stability and luminescent properties of Compound 1 were also investigated in this paper. CCDC: 811925.
- metal-organic frameworks;crystal structure;multicarboxylate ligand;luminescent property
1. [1]
  [1] Ma L Q, Abney C, Lin W B. Chem. Soc. Rev., 2009, 38: 1248-1256
2. [2]
  [2] Corma A, Garcí a H, Llabré s Xamena F X. Chem. Rev., 2010, 110:4606-4655
3. [3]
  [3] Hasegawa S, Horike S, Matsuda R, et al. J. Am. Chem. Soc., 2007, 129:2607-2614
4. [4]
  [4] Murray L J, Dinc M, Long J R. Chem. Soc. Rev., 2009, 38: 1294-1314
5. [5]
  [5] Li J R, Kuppler R J, Zhou H C. Chem. Soc. Rev., 2009, 38: 1477-1504
6. [6]
  [6] Dinc M, Long J R. J. Am. Chem. Soc., 2007, 129:11172-11176
7. [7]
  [7] Zhao J A, Mi L W, Hu J Y, et al. J. Am. Chem. Soc., 2008, 130:15222-15223
8. [8]
  [8] Maspoch D, Ruiz-Molina D, Veciana J. Chem. Soc. Rev., 2007, 36:770-818
9. [9]
  [9] Allendorf M D, Bauer C A, Bhakta R K, et al. Chem. Soc. Rev., 2009, 38:1330-1352
10. [10]
  [10] Cui Y J, Yue Y F, Chen B L, et al. Chem. Rev., 2012, 112: 1126-1162
11. [11]
  [11] Kahn O. Molecular Magnetism. New York: VCH Publishers, Inc., 1993.
12. [12]
  [12] Carling C L. Magnetochemistry. Berlin: Springer, 1986.
13. [13]
  [13] Gatteschi D, Sessoli R, Villain J. Molecular Nanomagnets. New York: Oxford University Press, 2006.
14. [14]
  [14] Zang S Q, Dong M M, Hou H W, et al. Cryst. Growth. Des., 2012, 12:1239-1246
15. [15]
  [15] Li C P, Du M. Chem. Commun., 2011, 47:5958-5972
16. [16]
  [16] Yin P X, Zhang J, Yao Y G, et al. CrystEngComm, 2011, 13: 3536-3544
17. [17]
  [17] Chen M, Chen S S, Sun W Y, et al. Cryst. Growth Des., 2011, 11:1901-1912
18. [18]
  [18] Eddaoudi M, O′Keeffe M, Yaghi O M, et al. Science, 2002, 295:469-472
19. [19]
  [19] Song X Z, Song S Y, Zhang H J, et al. Cryst. Growth Des., 2012, 12:253-263
20. [20]
  [20] Eddaoudi M, O′Keeffe M, Yaghi O M, et al. J. Am. Chem. Soc., 2002, 124:376-377
21. [21]
  [21] Zang S Q, Fan Y J, Hou H W, et al. Cryst. Growth Des., 2011, 11:3395-3405
22. [22]
  [22] WANG Peng-Fei (汪鹏飞), WU Guo-Zhi (吴国志), WANG Xin (汪新). Chinese J. Inorg. Chem. (Wuji Huaxue Xuebao), 2012, 28 (3):579-583
23. [23]
  [23] Wang L, Shi Z, Feng S H, et al. Inorg. Chem., 2006, 45: 2474-2478
24. [24]
  [24] Yao J, Meng Q J, Lu C S, et al. CrystEngComm, 2008, 10: 1379-1383
25. [25]
  [25] Ren C, Hou L, Wang Y Y, et al. Dalton Trans., 2011, 40: 793-804
26. [26]
  [26] SAINT, Program for Data Extraction and Reduction, Siemens Analytical X-ray Instruments, Madison, WI, 1994-1996.
27. [27]
  [27] Sheldrick G M. SHELXS-97, Program for Crystal Structure Solution, University of Göttingen, Göhttingen, Germany, 1997.
28. [28]
  [28] Sheldrick G M. SHELXL-97, Program for Crystal Structure Refinement, University of Göttingen, Göttingen, Germany, 1997.
29. [29]
  [29] O′Keeffe M, Peskov M A, Yaghi O M, et al. Acc. Chem. Res., 2008, 41:1782-1789
30. [30]
  [30] The Reticuler Chemistry Structure Resource Database can be accessed at http://rcsr.anu.edu.au
31. [31]
  [31] Blatov V A, Shevchenko A P. TOPOS 4.0; Samara State University, Russia, 2008.
32. [32]
  [32] Zheng P Q, Long L S, Zheng L S, et al. Appl. Organometal. Chem., 2003, 17:739-740
33. [33]
  [33] Nakamoto K. Infrared and Raman Spectra of Inorganic and Coordinated Compounds. 5th Ed. New York: Wiley & Sons, 1997.
34. [34]
  [34] Xia H Y, Liu G X, Nishihara S, et al. J. Inorg. Organomet. Polym., 2010, 20:110-117
35. [35]
  [35] Li H H, Shi W, Cheng P, et al. Cryst. Growth Des., 2012, 12:2602-2612
36. [36]
  [36] Liao S Y, Gu W, Yang L Y, et al. Cryst. Growth Des., 2012, 12:3927-3936
37. [37]
  [37] Wu Q G, Esteghamatian M, Xu N X, et al. Chem. Mater., 2000, 12:79-83
38. [38]
  [38] Lee E Y, Jang S Y, Suh M P. J. Am. Chem. Soc., 2005, 127: 6374-6381
39. [39]
  [39] He Y H, Feng Y L, Lan Y Z, et al. Cryst. Growth Des., 2008, 8:3586-3594
40. [40]
  [40] Chen W, Wang J Y, Chen J S, et al. Inorg. Chem., 2003, 42: 944-946
41. [41]
  [41] Wang X L, Chao Q, Wang E B, et al. Inorg. Chem., 2004, 43:1850-1856
42. [42]
  [42] Ji C C, Li Y Z, Zheng H G, et al. Cryst. Growth Des., 2011, 11:480-487
1. [1]
  Xin MA , Ya SUN , Na SUN , Qian KANG , Jiajia ZHANG , Ruitao ZHU , Xiaoli GAO . A Tb₂ complex based on polydentate Schiff base: Crystal structure, fluorescence properties, and biological activity. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1347-1356. doi: 10.11862/CJIC.20230357
2. [2]
  Xiaoling LUO , Pintian ZOU , Xiaoyan WANG , Zheng LIU , Xiangfei KONG , Qun TANG , Sheng WANG . Synthesis, crystal structures, and properties of lanthanide metal-organic frameworks based on 2, 5-dibromoterephthalic acid ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1143-1150. doi: 10.11862/CJIC.20230271
3. [3]
  Zhaoyang WANG , Chun YANG , Yaoyao Song , Na HAN , Xiaomeng LIU , Qinglun WANG . Lanthanide(Ⅲ) complexes derived from 4′-(2-pyridyl)-2, 2′∶6′, 2″-terpyridine: Crystal structures, fluorescent and magnetic properties. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1442-1451. doi: 10.11862/CJIC.20240114
4. [4]
  Jingjing QING , Fan HE , Zhihui LIU , Shuaipeng HOU , Ya LIU , Yifan JIANG , Mengting TAN , Lifang HE , Fuxing ZHANG , Xiaoming ZHU . Synthesis, structure, and anticancer activity of two complexes of dimethylglyoxime organotin. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1301-1308. doi: 10.11862/CJIC.20240003
5. [5]
  Yingchun ZHANG , Yiwei SHI , Ruijie YANG , Xin WANG , Zhiguo SONG , Min WANG . Dual ligands manganese complexes based on benzene sulfonic acid and 2, 2′-bipyridine: Structure and catalytic properties and mechanism in Mannich reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1501-1510. doi: 10.11862/CJIC.20240078
6. [6]
  Haitang WANG , Yanni LING , Xiaqing MA , Yuxin CHEN , Rui ZHANG , Keyi WANG , Ying ZHANG , Wenmin WANG . Construction, crystal structures, and biological activities of two Ln^Ⅲ₃ complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1474-1482. doi: 10.11862/CJIC.20240188
7. [7]
  Xinting XIONG , Zhiqiang XIONG , Panlei XIAO , Xuliang NIE , Xiuying SONG , Xiuguang YI . Synthesis, crystal structures, Hirshfeld surface analysis, and antifungal activity of two complexes Na(Ⅰ)/Cd(Ⅱ) assembled by 5-bromo-2-hydroxybenzoic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1661-1670. doi: 10.11862/CJIC.20240145
8. [8]
  Kaimin WANG , Xiong GU , Na DENG , Hongmei YU , Yanqin YE , Yulu MA . Synthesis, structure, fluorescence properties, and Hirshfeld surface analysis of three Zn(Ⅱ)/Cu(Ⅱ) complexes based on 5-(dimethylamino) isophthalic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1397-1408. doi: 10.11862/CJIC.20240009
9. [9]
  Peiran ZHAO , Yuqian LIU , Cheng HE , Chunying DUAN . A functionalized Eu³⁺ metal-organic framework for selective fluorescent detection of pyrene. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 713-724. doi: 10.11862/CJIC.20230355
10. [10]
  Wenxiu Yang , Jinfeng Zhang , Quanlong Xu , Yun Yang , Lijie Zhang . Bimetallic AuCu Alloy Decorated Covalent Organic Frameworks for Efficient Photocatalytic Hydrogen Production. Acta Physico-Chimica Sinica, 2024, 40(10): 2312014-. doi: 10.3866/PKU.WHXB202312014
11. [11]
  Youlin SI , Shuquan SUN , Junsong YANG , Zijun BIE , Yan CHEN , Li LUO . Synthesis and adsorption properties of Zn(Ⅱ) metal-organic framework based on 3, 3', 5, 5'-tetraimidazolyl biphenyl ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1755-1762. doi: 10.11862/CJIC.20240061
12. [12]
  Tiantian MA , Sumei LI , Chengyu ZHANG , Lu XU , Yiyan BAI , Yunlong FU , Wenjuan JI , Haiying YANG . Methyl-functionalized Cd-based metal-organic framework for highly sensitive electrochemical sensing of dopamine. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 725-735. doi: 10.11862/CJIC.20230351
13. [13]
  Gaofeng WANG , Shuwen SUN , Yanfei ZHAO , Lixin MENG , Bohui WEI . Structural diversity and luminescence properties of three zinc coordination polymers based on bis(4-(1H-imidazol-1-yl)phenyl)methanone. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 849-856. doi: 10.11862/CJIC.20230479
14. [14]
  Lu XU , Chengyu ZHANG , Wenjuan JI , Haiying YANG , Yunlong FU . Zinc metal-organic framework with high-density free carboxyl oxygen functionalized pore walls for targeted electrochemical sensing of paracetamol. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 907-918. doi: 10.11862/CJIC.20230431
15. [15]
  Qiuyang LUO , Xiaoning TANG , Shu XIA , Junnan LIU , Xingfu YANG , Jie LEI . Application of a densely hydrophobic copper metal layer in-situ prepared with organic solvents for protecting zinc anodes. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1243-1253. doi: 10.11862/CJIC.20240110
16. [16]
  Jing SU , Bingrong LI , Yiyan BAI , Wenjuan JI , Haiying YANG , Zhefeng Fan . Highly sensitive electrochemical dopamine sensor based on a highly stable In-based metal-organic framework with amino-enriched pores. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1337-1346. doi: 10.11862/CJIC.20230414
17. [17]
  Huan ZHANG , Jijiang WANG , Guang FAN , Long TANG , Erlin YUE , Chao BAI , Xiao WANG , Yuqi ZHANG . A highly stable cadmium(Ⅱ) metal-organic framework for detecting tetracycline and p-nitrophenol. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 646-654. doi: 10.11862/CJIC.20230291
18. [18]
  Ruikui YAN , Xiaoli CHEN , Miao CAI , Jing REN , Huali CUI , Hua YANG , Jijiang WANG . Design, synthesis, and fluorescence sensing performance of highly sensitive and multi-response lanthanide metal-organic frameworks. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 834-848. doi: 10.11862/CJIC.20230301
19. [19]
  Xiaoxia WANG , Ya'nan GUO , Feng SU , Chun HAN , Long SUN . Synthesis, structure, and electrocatalytic oxygen reduction reaction properties of metal antimony-based chalcogenide clusters. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1201-1208. doi: 10.11862/CJIC.20230478
20. [20]
  Lu LIU , Huijie WANG , Haitong WANG , Ying LI . Crystal structure of a two-dimensional Cd(Ⅱ) complex and its fluorescence recognition of p-nitrophenol, tetracycline, 2, 6-dichloro-4-nitroaniline. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1180-1188. doi: 10.11862/CJIC.20230489

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(267)
HTML views(17)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142